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Evolution of Spectral Function in a Doped Mott Insulator: Surface vs Bulk Contributions

Kalobaran Maiti、Priya Mahadevan、D. D. Sarma1998-03-30Physical Review Letters

We study the evolution of the spectral function with progressive hole doping in a Mott insulator, ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}{\mathrm{VO}}_{3}$ with $x\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}0.0--0.5$. The spectral features indicate a bulk-to-surface metal-insulator transition in this…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Corrosion and Its Control by Coatings

Gordon P. Bierwagen1998-03-30ACS symposium series

Corrosion protection of metallic substrates has long been one of the key roles performed by organic coatings. Such coatings remain one of the most cost-effective means of providing practical protection from corrosion to easily corrodible metallic (and sometimes non-metallic) structures and objects. This choice of a co…

Corrosion Behavior and InhibitionConcrete Corrosion and Durability

Dephasing Rate in Dielectric Glasses at Ultralow Temperatures

Alexander L. Burin、Yu. Kagan、L. A. Maksimov 等 4 位作者1998-03-30Physical Review Letters

A novel mechanism for dephasing in dielectric glasses is considered. The mechanism is due to the delocalized collective excitations arising in the ensemble of the interacting two-level systems. The spectral diffusion induced by these excitations gives rise to the phonon-independent transverse relaxation. The mechanism…

Liquid Crystal Research AdvancementsGlass properties and applicationsPhase-change materials and chalcogenides

Organic Coatings for Corrosion Control

Gordon P. Bierwagen1998-03-30ACS symposium series

Corrosion protection of metallic substrates has long been one of the key roles performed by organic coatings. Such coatings remain one of the most cost-effective means of providing practical protection from corrosion to easily corrodible metallic (and sometimes non-metallic) structures and objects. This choice of a co…

Corrosion Behavior and InhibitionConcrete Corrosion and Durability

Anisotropic magnetoresistance of thin La0.7Ca0.3MnO3films

M. Ziese、S. Sena1998-03-30Journal of Physics Condensed Matter

The low-field magnetoresistance of films deposited on different substrates has been measured. Whereas post-annealed films on and exhibit a clear anisotropic magnetoresistance (AMR), the low-field magnetoresistance of as-deposited films on and Si is dominated by grain-boundary magnetoresistance. At low temperatures the…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Lattice parameter in Si1−yCy epilayers: Deviation from Vegard’s rule

M. Berti、D. De Salvador、A. V. Drigo 等 8 位作者1998-03-30Applied Physics Letters

The precise C content of a series of Si1−yCy epilayer samples (0<y<0.012) was determined by resonant backscattering experiments using a He+4 ion beam at 5.72 MeV. This beam energy is more suitable for the determination of the C content than the previously used 4.265 MeV. From the correlation of these inv…

Silicon Carbide Semiconductor TechnologiesMetal and Thin Film MechanicsDiamond and Carbon-based Materials Research

Dielectric tunability of barium strontium titanate/silicone-rubber composite

J.W. Liou、Sien Chi1998-03-30Journal of Physics Condensed Matter

The dielectric tunability, which is defined as the percentage change of the permittivity under DC biasing, is over 30% for polycrystalline barium strontium titanate (BST) under a field of at around the Curie peak. Various volume fractions (18%, 40%, 52%, and 64%) of BST powder are mixed with silicone rubber to obtain…

Ferroelectric and Piezoelectric MaterialsDielectric materials and actuatorsMicrowave Dielectric Ceramics Synthesis

Mechanics of Aircraft Structures

C. T. Sun1998-03-30OpenAlex

Characteristics of Aircraft Structures and Materials. Introduction to Elasticity. Torsion. Bending and Flexural Shear. Flexural Shear Flow in Thin--Walled Sections. Failure Criteria for Isotropic Materials. Elastic Buckling. Analysis of Composite Laminates. Index.

Material Properties and Applications

The metal - insulator transition and ferromagnetism in the electron-doped layered manganites (x= 0, 0.3, 0.5)

Pratap Raychaudhuri、Chiranjib Mitra、Arun Paramekanti 等 6 位作者1998-03-30Journal of Physics Condensed Matter

Bulk samples of , with x = 0, 0.3, 0.5, with layered perovskite structure have been synthesized and investigated as regards their electrical, electronic and magnetic properties. It is found that has tetragonal structure and is a metallic ferromagnet with a magnetic transition temperature of 170 K. This compound shows…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Combustion and fire retardance of poly(2,6-dimethyl-1,4-phenylene ether)-high-impact polystyrene blends. II. Chemical aspects

A. Boscolo Boscoletto、Mattia Checchin、L. Milan 等 7 位作者1998-03-28Journal of Applied Polymer Science

The chemical reactions occurring during the intumescent process taking place in the combustion of the poly(2,6-dimethyl–1,4-phenylene ether)–high-impact polystyrene blends (PPE–HIPS) are studied in detail through the chemical characterization of the burnt and original material by infrared, pyrolysis–gas chromatography…

Fire dynamics and safety researchFlame retardant materials and propertiesCombustion and Detonation Processes

Study on the thermal degradation of epoxidized natural rubber

Sidong Li、Ying Chen、Jiang Zhou 等 6 位作者1998-03-28Journal of Applied Polymer Science

The thermal degradation and thermooxidative degradation of epoxidized natural rubber (ENR) were studied by thermogravimetry (TG). In the thermal degradation of ENR, the initial temperature of weight loss T0 = 1.20B + 348, the temperature of maximum weight loss rate Tp = 1.07B + 392, and the final temperature of weight…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSynthesis and properties of polymers

Luminescence of Zinc Tetraphenylporphyrin in Ethylene Glycol-in-Oil Microemulsions

Pilar López‐Cornejo、Sı́lvia M. B. Costa1998-03-28Langmuir

Photophysical properties of zinc-tetraphenylporphyrin (ZnTPP) were studied in n -heptane/AOT/ethylene glycol and isooctane/AOT/ethylene glycol microemulsions. Results of steady state and transient fluorescence techniques show the existence of different spectroscopic ZnTPP species located at different environments of t…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPhotochemistry and Electron Transfer Studies

Preparation of Ultrafine Titanium Dioxide Particles Using Hydrolysis and Condensation Reactions in the Inner Aqueous Phase of Reversed Micelles: Effect of Alcohol Addition

Hideki Sakai、Hajime Kawahara、Masuo Shimazaki 等 4 位作者1998-03-28Langmuir

An attempt was made to prepare ultrafine titanium dioxide (TiO 2 ) particles in the nanometer range by making use of the hydrolysis and condensation reactions of tetraisopropylorthotitanate (TTIP) in the inner aqueous phase of Aerosol OT reversed micelles formed in cyclohexane. Addition of linear alcohols (C 2 to C 6…

TiO2 Photocatalysis and Solar CellsCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Polymerizable Lyotropic Liquid Crystals Containing Transition-Metal and Lanthanide Ions: Architectural Control and Introduction of New Properties into Nanostructured Polymers

Hai Deng、Douglas L. Gin、Ryan C. Smith1998-03-28Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTPolymerizable Lyotropic Liquid Crystals Containing Transition-Metal and Lanthanide Ions: Architectural Control and Introduction of New Properties into Nanostructured PolymersHai Deng, Douglas L. Gin, and Ryan C. SmithView Author Information Department of Chemistry, Uni…

Liquid Crystal Research AdvancementsAdvanced Polymer Synthesis and CharacterizationSurfactants and Colloidal Systems

A New Synthesis of Tetrathiooxalate and Its Conversion to C3S52- and C4S62-

Jonathan G. Breitzer、Jun-Hong Chou、Thomas B. Rauchfuss1998-03-28Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTA New Synthesis of Tetrathiooxalate and Its Conversion to C3S52- and C4S62-Jonathan G. Breitzer, Jun-Hong Chou, and Thomas B. RauchfussView Author Information School of Chemical Sciences and the Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Cha…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Dehydrochlorination behavior of flexible PVC pellets in NaOH solutions at elevated temperature

Shun Myung Shin、Toshiaki Yoshioka、A. Okuwaki1998-03-28Journal of Applied Polymer Science

Flexible PVC pellets were treated at 150–250°C in 0–7M NaOH solutions for 0–12 h. The degree of dehydrochlorination of flexible PVC pellets increased with increasing reaction temperature and was about 100% at 250°C over 5 h. A porous char, 2–16 μm in pore size, was produced. The dehydrochlorination of PVC in the flexi…

Polymer Science and PVC

π-Dimers of Prototype High-Spin Polaronic Oligomers

John A. E. H. van Haare、Marc van Boxtel、René A. J. Janssen1998-03-28Chemistry of Materials

Novel well-defined oligomers consisting of two dopable π-conjugated segments, 2,2‘-bipyrrole or 2,2‘-bithiophene, linked via 1,3-phenylene and end-capped with phenyl groups have been synthesized using palladium-catalyzed cross-coupling reactions. The molecules are considered as prototypical examples for polaronic ferr…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and Properties of Aromatic Compounds

Effect of X-rays on poly(vinylidene fluoride) in X-ray photoelectron spectroscopy

Mariana D. Duca、Carmina L. Plosceanu、Tatiana Pop1998-03-28Journal of Applied Polymer Science

The polymer poly(vinylidene fluoride) (PVDF) was irradiated with X-rays produced by a nonmonochromatic (MgKα) source and the structural and electronic PVDF surface modifications were studied by X-ray photoelectron spectroscopy (XPS). Changes in the shape and intensity of the C1s and F1s lines show that a PVDF degradat…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesSilicone and Siloxane Chemistry

Silicon and Zinc Coordination to Peripheral Catechol Sites of (2,3,9,10,16,17,23,24-Octahydroxyphthalocyaninato)nickel(II). Phthalocyanine Coordination Chemistry at the Edge

Michael Ruf、Andrew M. Lawrence、B.C. Noll 等 4 位作者1998-03-27Inorganic Chemistry

(2,3,9,10,16,17,23,24-Octahydroxyphthalocyaninato)nickel(II) (NiPc(OH) 8 ) has been prepared by demethylation of (octamethoxyphthalocyaninato)nickel(II). Silylation of peripheral oxygen atoms using dimethyl- tert -butylsilyl chloride gave NiPc(OSi( t -Bu)Me 2 ) 8 as a convenient precursor to NiPc(OH) 8 with high solub…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

The Quantum-Classical Metal

David G. Clarke、Steven Strong、P. M. Chaikin 等 4 位作者1998-03-27Science

In a normal Fermi liquid, Landau's theory precludes the loss of single-fermion quantum coherence in the low-energy, low-temperature limit. For highly anisotropic, strongly correlated metals, there is no proof that this remains the case, and quantum coherence for transport in some directions may be lost intrinsically.…

Quantum and electron transport phenomenaMagnetism in coordination complexesOrganic and Molecular Conductors Research