Materials Literature
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We have synthesized Sr${}_{6}$Co${}_{5}$O${}_{15}$, a quasi-one-dimensional oxide, measured its magnetic properties, and calculated its electronic structure by ab initio techniques. We have found strong evidence for its electronic and magnetic behavior not to follow the trend of its structural series. The magnetic cou…
Fabrication of high-performance nanocomposites requires that the nanoscale fillers be dispersed uniformly and form a continuous network throughout the matrix. Direct infiltration of porous CNT sponges consisting of a three-dimensional nanotube scaffold may provide a possible solution to this challenge. Here, we fabric…
Vascular grafts are devices intended to replace compromised arteries in the body and grafts made of polyethylene terephthalate (PET) fabric have been used mainly for synthetic grafting procedures involving medium to large diameter vascular grafts. Though porosity of the graft permits tissue in-growth, it would lead to…
Abstract Nanocrystalline ceria (CeO 2 ) is known for its ionic conductivity and oxygen storage properties, which depend on the presence of oxygen ion vacancies. The vacancies cause several important changes in CeO 2 involving microstrain, electronic structure, magnetic properties, etc. In this article, we focus our at…
Poly(propylene sulfide) nanoparticles (<150 nm) have been synthesized by an anionic, ring-opening emulsion polymerization. Upon exposure to parts per million (ppm) levels of oxidizing agent (NaOCl), hydrophobic polysulfide particles are oxidized to hydrophilic polysulfoxides and polysulfones. Utilizing this mechanism,…
We present frequency tunable metamaterial designs at terahertz (THz) frequencies using broadside coupled split-ring resonator (BC-SRR) arrays. Frequency tuning, arising from changes in near-field coupling, is obtained by in-plane displacement of the two SRR layers. For electrical excitation, the resonance frequency co…
Abstract Benzotriazole (BTAH) is well known as an effective corrosion inhibitor for Cu because of its ability to make a coordination polymer film on the surface that provides a barrier to Cu oxidation. BTA − film formation was investigated on single‐crystal and polycrystalline Cu surfaces with shell‐isolated nanoparti…
Carbon nanotubes (CNTs) cause perturbations in immune systems and limit the application of CNTs in biomedicine. Here we demonstrate that a surface chemistry modification on multiwalled CNTs (MWCNTs) reduces their immune perturbations in mice and in macrophages. The modified MWCNTs change their preferred binding patter…
Superconductivity in the iron pnictides and chalcogenides arises at the border of antiferromagnetism, which raises the question of the role of quantum criticality. In this topical review, we describe the theoretical work that led to the prediction of a magnetic quantum critical point arising out of a competition betwe…
Pressure dependence of thermal conductivity provides a critical test of the validity of the model of the minimum thermal conductivity for describing heat transport by molecular vibrations of an amorphous polymer. We measure the pressure dependence of the thermal conductivity \ensuremath{\Lambda}($P$) of poly(methyl me…
A single nitrogen-vacancy (NV) center is used to sense individual, as well as small ensembles of, electron spins placed outside the diamond lattice. Applying double electron–electron resonance techniques, we were able to observe Rabi nutations of these external spins as well as the coupling strength between the extern…
Recent advances in the synthesis of multicomponent nanocrystals have enabled the design of nanocrystal molecules with unique photophysical behavior and functionality. Here we demonstrate a highly luminescent nanocrystal molecule, the CdSe/CdS core/shell tetrapod, which is designed to have weak vibronic coupling betwee…
We have found that a water-soluble alkaline-digested form of eggshell membrane (ASESM) can provide an extracellular matrix (ECM) environment for human dermal fibroblast cells (HDF) in vitro. Avian eggshell membrane (ESM) has a fibrous-meshwork structure and has long been utilized as a Chinese medicine for recovery fro…
We present an investigation into the influence of nanocrystal size on the reactivity of silicon nanocrystals (Si-NCs) in near-UV photochemical hydrosilylation. The size-dependent reactivity of Si-NCs with photoluminescence (PL) in the visible and near-infrared regions was evaluated using PL and Fourier-transform infra…
We report the unique layer-by-layer (LbL) assembly behavior of pH-sensitive star-shaped polyelectrolytes with both linear and exponential growth modes controlled by star architecture and assembly conditions. Cationic poly[2-(dimethylamino)ethyl methacrylate] and anionic poly(acrylic acid) stars were synthesized via "c…
Two new mid-infrared transparency compounds, centric Ba(2)BiGaS(5) (1) and acentric Ba(2)BiInS(5) (2), were synthesized from a high-temperature solid-state reaction in evacuated closed silica tubes. Their crystal structures were determined by a single crystal X-ray diffraction method at 293 K. The results of crystal s…
Several different approaches have been proposed to calculate the zero-field splitting tensor with density functional methods. In this work, our own derivation is presented in some detail, to allow a theoretical analysis and a comparison with other methods [M. R. Pederson and S. N. Khanna, Phys. Rev. B 60, 9566 (1999);…
The important source of interface conductivity in LaAlO${}_{3}$/SrTiO${}_{3}$ heterostructures, the Ti 3$d$ carriers, is probed with resonant inelastic x-ray scattering at the Ti 2${p}_{3/2}$ edge of epitaxially grown superlattices. We reveal unambiguously the generation of both localized and delocalized Ti 3$d$ carri…
The transfer of electrons between a solid surface and adsorbed atomic or molecular species is fundamental in natural and synthetic processes, being at the heart of most catalytic reactions and many sensors. In special cases, metallic conduction can be induced at the surface of, for example, Si-terminated SiC1, or mixe…
The estimator proposed recently by Delmas and Jourdain for waste-recycling Monte Carlo achieves variance reduction optimally with respect to a control variate that is evaluated directly using the simulation data. Here, the performance of this estimator is assessed numerically for free energy calculations in generic bi…