Materials Literature
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The interaction of hydrogen with a chemical vapor deposition (CVD) deposited polycrystalline film on Si(100), cleaned by heating to 1500 K, has been examined. No adsorption is observed unless prior activation with a hot filament is carried out. However atomic H thereby created is found to adsorb with a high sticking p…
Abstract The mercury perrhenates with the empirical formulas HgReO 4 and Hg 2 ReO 5 were prepared by annealing powdered mixtures of mercury(II)oxide and mercury(II)metaperrhenate Hg(ReO 4 ) 2 in sealed silica tubes. Their crystal structures were determined from single‐crystal X‐ray data. HgReO 4 crystallizes dimeric w…
The optical absorption, luminescence, luminescence excitation, and luminescence decay kinetics of a dopant with a 3${\mathit{d}}^{3}$ shell (most probably ${\mathrm{Cr}}^{3+}$) and ${\mathrm{V}}^{3+}$ ions in natural ${\mathrm{Ca}}_{2}$${\mathrm{Al}}_{3}$${\mathrm{Si}}_{3}$${\mathrm{O}}_{12}$(OH) zoisite crystal have…
We attempt to establish the mathematical expression of the current and the magnetic field in a metallized capacitor. The expression of the impedance of this capacitor is also presented. The distribution of the current is discussed through the variation of the capacitor impedance and compared to experimental ones. Ther…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMetalorganic Chemical Vapor Deposition of Lead TitanateWarren C. Hendricks, Seshu B. Desu, and Chien H. PengCite this: Chem. Mater. 1994, 6, 11, 1955–1960Publication Date (Print):November 1, 1994Publication History Published online1 May 2002Published inissue 1 November 1994h…
The morphology, systematics and ecology of a new centric diatom, Cyclotella pseudocomensis nov. sp., are presented. The morphological variation and ultrastructure from initial to the smallest cells are described as revealed by light and scanning electron microscopy. This new species is characterized by the transverse…
ABSTRACT Polypropylene and polyethylene terephthalate films were immersed in pure triglycerides or fatty acids for a range of times. They were analyzed for the amount sorbed to determine the relative importance of fat chemical configuration and cohesive energy density (CED) on sorption order and amount. Structure affe…
In this paper, the author describes how effects related to dislocation mobility can be incorporated in the instability criterion in a straightforward manner and used to analyze the strain-rate dependence of (Tc). He begins with a simple example and studies the dynamics of a group of dislocations in the vicinity of a c…
Abstract Kinetics of manganese(III) oxidation of L‐arginine has been studied in the presence of pyrophosphate and acetate ions in acidic media at 328 K and 323 K, respectively. The nature of the oxidizing species formed in manganese(III) solutions was determined by spectrophotometric and redox potential measurements.…
In the present paper we address the question of whether localized failure due to elastoplastic bifurcation can be captured within the fixed‐mesh approach. To this end, the theoretical framework of localization analysis of elastoplastic solids is revisited, and examples of weak discontinuities are presented for an elas…
Author: Kang, C. S. et al.; Genre: Journal Article; Issued: 1994; Title: SYNTHESIS AND PROPERTIES OF AROMATIC MAIN-CHAIN POLYESTERS HAVING<br/> DISPERSE RED-1 NONLINEAR-OPTICAL CHROMOPHORES IN THE SIDE-CHAIN
Abstract The kinetics of the H 2 O 2 decomposition by Cu(II)‐, Co(II)‐, and Fe(III)‐amine complexes supported on the surface of silica‐alumina (25% Al 2 O 3 ) catalyst have been investigated. The decomposition process proceeded with first‐order kinetics for the substrate concentration. With copper complexes, in partic…
Disruptions in tokamak reactors are considered a limiting factor to successful operation and a reliable design. The behavior of plasma-facing components during a disruption is critical to the overall integrity of the reactor. Erosion of plasma facing-material (PFM) surfaces due to thermal energy dump during the disrup…
Abstract The six donor‐acceptor spiro compounds spiro[1,3‐dioxolane‐2,2′‐indan]‐1′,3′‐dione ( 8 ), spiro[indan‐2,2′‐[1,3]oxathiolane]‐1,3‐dione ( 9 ), spiro[1,3‐dithiolane‐2,2′‐indan]‐1′,3′‐dione ( 10 ), spiro[1,3‐benzodioxole‐2,2′‐indan]‐1′,3′‐dione ( 11 ), 5‐methylspiro[1,3‐benzodithiole‐2,2′‐indan]‐1′,3′‐dione ( 12…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermal expansion and temperature dependence of elastic moduli of aromatic polyamidesDaniel J. Lacks and Gregory C. RutledgeCite this: Macromolecules 1994, 27, 24, 7197–7204Publication Date (Print):November 1, 1994Publication History Published online1 May 2002Published iniss…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation of Forsterite by Pyrolysis of a Xerogel: The Effect of WaterDong Gon Park, James C. Duchamp, T. Michael Duncan, and James M. BurlitchCite this: Chem. Mater. 1994, 6, 11, 1990–1995Publication Date (Print):November 1, 1994Publication History Published online1 May 2…
Abstract A chain complex, [Mo2{O2CC(CH3)3}4 bpy]n (bpy = 4,4′-bipyridine), was prepared by the reaction of molybdenum(II) pivalate (Mo2{O2CC(CH3)3}4) and bpy. An X-ray crystal analysis showed that the chain structure is formed by alternating Mo2{O2CC(CH3)3}4 and bpy.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDegradation Kinetics of Polyaniline Base and Sulfonated PolyanilineTsung-Chieh Tsai, D. Alan Tree, and Martin S. HighCite this: Ind. Eng. Chem. Res. 1994, 33, 11, 2600–2606Publication Date (Print):November 1, 1994Publication History Published online1 May 2002Published inissu…
Abstract Die bisher unbekannte Kristallstruktur von β‐Cu 3 SbS 3 bei Zimmertemperatur wurde anhand eines verzwillingten Kristalls ermittelt. Die Verbindung kristallisiert monoklin, RG P2 1 /c (Nr. 14) mit a = 7,808(1), b = 10,233(2) und c = 13,268(2) Å, β = 90,31(1)°, V = 1 060,1(2) Å 3 , Z = 8. Eine Extended‐Hückel‐R…
Abstract A peak‐to‐background method was implemented for standardless electron microprobe analysis of bulk samples and particles. First, a study on the choice of the beam entry point was performed; the region of the particle closest to the detector proved to be the most convenient. Then, a very simple algorithm, which…