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High-rate capacitive performance of graphene aerogel with a superhigh C/O molar ratio

Xiaozhong Wu、Jin Zhou、Wei Xing 等 9 位作者2012-01-01Journal of Materials Chemistry

Graphene aerogel (GA) is successfully prepared through hydrogen reduction of graphene oxide aerogel (GOA) which is self-assembled from graphene oxide solution and subsequently dried by a supercritical CO2 method. The morphology, structure and surface property evolution in the preparation of GA are investigated intensi…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Submicrometer-sized NiO octahedra: facile one-pot solid synthesis, formation mechanism, and chemical conversion into Ni octahedra with excellent microwave-absorbing properties

Guoxiu Tong、Qian Hu、Wenhua Wu 等 6 位作者2012-01-01Journal of Materials Chemistry

A facile template-free and one-pot thermal decomposition approach was used for the mass preparation of submicrometer-sized NiO octahedra. Ni octahedra with tailored crystallization and texture characteristics are easily achieved through H2-annealing of NiO octahedra at various temperatures. The good morphology retenti…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsMagnesium Oxide Properties and Applications

Tetraphenylethenyl-modified perylene bisimide: aggregation-induced red emission, electrochemical properties and ordered microstructures

Qiuli Zhao、Shuang Zhang、Yi Liu 等 10 位作者2012-01-01Journal of Materials Chemistry

Perylene bisimides (PBIs) are one class of the most explored organic fluorescent materials due to their high fluorescence quantum efficiency, electron transport behaviour, and ready to form well-tailored supramolecular structures. However, they suffer from heavy aggregation-caused quenching (ACQ) effect which has grea…

Organic Electronics and PhotovoltaicsLuminescence and Fluorescent MaterialsPolydiacetylene-based materials and applications

Solubility improvements in aromatic polyimides by macromolecular engineering

Anindita Ghosh、Suman Sen、Susanta Banerjee 等 4 位作者2012-01-01RSC Advances

Polyimides are proved to be an important class of polymers due to their outstanding set of physical and chemical properties. However, this class of polymers suffers from poor processability, which limits their scope of application. This review article deals with approaches that have been undertaken by different resear…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersTribology and Wear Analysis

Overcoming Mutual Blockage Between Neighboring Dipole Antennas Using a Low-Profile Patterned Metasurface

Alessio Monti、Jason Soric、Andrea Alù 等 6 位作者2012-01-01IEEE Antennas and Wireless Propagation Letters

In this letter, we investigate the possibility of using the mantle cloaking approach to reduce mutual blockage effects between two electrically close antennas. In particular, we consider the case of two dipoles resonating at different, close frequencies and separated by an electrically short distance ( λ0/10 at 3 GHz)…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Novel polymer nanocomposites from bioinspired green aqueous functionalization of BNNTs

Vijay Kumar Thakur、Jian Yan、Meng‐Fang Lin 等 8 位作者2012-01-01Polymer Chemistry

Boron nitride nanotubes (BNNTs) are excellent nanofillers to enhance the mechanical and thermal properties of polymer nanocomposites. Despite the rapid progress in the effective syntheses of BNNTs, the ease of processability and solubility are major roadblocks for their widespread applications. The present work report…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Multifaceted Roles of Tunneling Nanotubes in Intercellular Communication

Ludovica Marzo、Karine Gousset、Chiara Zurzolo2012-01-01Frontiers in Physiology

Cell-to-cell communication and exchange of materials are vital processes in multicellular organisms during cell development, cell repair, and cell survival. In neuronal and immunological cells, intercellular transmission between neighboring cells occurs via different complex junctions or synapses. Recently, long dista…

RNA and protein synthesis mechanismsCellular transport and secretionSupramolecular Self-Assembly in Materials

Design and properties of supramolecular polymer gels

Atsushi Noro、Mikihiro Hayashi、Yushu Matsushita2012-01-01Soft Matter

Supramolecular polymer gels are precisely designed physical gels brought together by reversible secondary interactions to form three dimensional networks of melt macromolecules. Generally, they differ from supramolecular gels because they are comprised of polymers instead of low molecular weight compounds. Recently, m…

Hydrogels: synthesis, properties, applicationsSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials

Junction studies on electrochemically fabricated p–n Cu2O homojunction solar cells for efficiency enhancement

Colleen M. McShane、Kyoung‐Shin Choi2012-01-01Physical Chemistry Chemical Physics

p-n Cu(2)O homojunction solar cells were electrochemically fabricated by consecutively depositing an n-Cu(2)O layer on a p-Cu(2)O layer. In order to better understand the Fermi levels of the electrochemically grown polycrystalline p- and n-Cu(2)O layers and maximize the overall cell performance, the back and front con…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Nanocrystalline CaYAlO4:Tb3+/Eu3+ as promising phosphors for full-color field emission displays

Dongling Geng、Guogang Li、Mengmeng Shang 等 7 位作者2012-01-01Dalton Transactions

Eu(3+) and/or Tb(3+)-doped CaYAlO(4) phosphor samples were synthesized by Pechini-type sol-gel method. X-Ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), photoluminescence (PL) and cathodoluminescence (CL) spectra were used to characterize the samples. For CaYAlO(4):Tb(3+), it is shown that…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesLuminescence and Fluorescent Materials

Continuous mechanical exfoliation of graphene sheets via three-roll mill

Jinfeng Chen、Miao Duan、Guohua Chen2012-01-01Journal of Materials Chemistry

In this work, single and few-layer graphene sheets have been successfully peeled from natural graphite through continuous mechanical exfoliation by a three-roll mill machine with a polymer adhesive. The inspiration takes root in the “Scotch tape” method. Characterizations show that the thickness of the resultant graph…

Graphene research and applicationsMolecular Junctions and NanostructuresGraphene and Nanomaterials Applications

Non-covalently modified graphene sheets by imidazolium ionic liquids for multifunctional polymer nanocomposites

Yingkui Yang、Chengen He、Rengui Peng 等 8 位作者2012-01-01Journal of Materials Chemistry

Chemical reduction of graphite oxide (GO) to produce graphene nanosheets often results in irreversible agglomeration and precipitation. Herein, stable well-dispersed graphene sheets in solvents were obtained by simultaneous functionalization and reduction of GO under alkaline conditions, in the presence of sodium boro…

Graphene research and applicationsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

A DNA-templated fluorescent silver nanocluster with enhanced stability

Jaswinder Sharma、Reginaldo C. Rocha、M. Lisa Phipps 等 9 位作者2012-01-01Nanoscale

We report the discovery of a DNA sequence that templates a highly stable fluorescent silver nanocluster. In contrast to other DNA templated silver nanoclusters that have a relatively short shelf-life, the fluorescent species templated in this new DNA sequence retains significant fluorescence for at least a year. Moreo…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

An efficient route to a porous NiO/reduced graphene oxide hybrid film with highly improved electrochromic properties

Guofa Cai、J.P. Tu、Jun Zhang 等 7 位作者2012-01-01Nanoscale

A porous NiO/RGO hybrid film is prepared by the combination of electrophoretic deposition and chemical-bath deposition. The porous hybrid film exhibits a noticeable electrochromism with reversible color changes from transparent to dark brown, and shows high coloration efficiency (76 cm(2) C(-1)), fast switching speed…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsCopper-based nanomaterials and applications

Molecular early main group metal hydrides: synthetic challenge, structures and applications

Sjoerd Harder2012-01-01Chemical Communications

Within the general area of early main group metal chemistry, the controlled synthesis of well-defined metal hydride complexes is a rapidly developing research field. As group 1 and 2 metal complexes are generally highly dynamic and lattice energies for their [MH](∞) and [MH(2)](∞) salts are high, the synthesis of well…

Hydrogen Storage and MaterialsAsymmetric Hydrogenation and CatalysisAmmonia Synthesis and Nitrogen Reduction

Fire retardancy and morphology of layered double hydroxide nanocomposites: a review

Zvonimir Matusinović、Charles A. Wilkie2012-01-01Journal of Materials Chemistry

One of the methods to reduce the flammability of polymeric materials is the incorporation of layered double hydroxides (LDHs) into the polymer matrix. Dispersing LDH into the polymer matrix results in the formation of nanocomposites with significantly improved thermal and fire retardant properties. In this review the…

Flame retardant materials and propertiesLayered Double Hydroxides Synthesis and ApplicationsSynthesis and properties of polymers

Hierarchically structured porous aluminum surfaces for high-efficient removal of condensed water

Min He、Xin Zhou、Xiping Zeng 等 11 位作者2012-01-01Soft Matter

Hierarchically structured porous aluminum surfaces for the high efficient removal of condensed water microdroplets are prepared via simply immersing aluminum sheets in hot water followed by modification with a low surface energy chemical. A correlation between the work of adhesion with the self-removal of condensed wa…

Surface Modification and SuperhydrophobicityAerogels and thermal insulationElectrohydrodynamics and Fluid Dynamics

Diphosphates and diphosphonates in polyoxometalate chemistry

Abhishek Banerjee、Bassem S. Bassil、Gerd‐Volker Röschenthaler 等 4 位作者2012-01-01Chemical Society Reviews

In the wide area of polyoxometalate (POM) chemistry, diphosphate/diphosphonate-based POMs represent a more recent area of study. However, in this short time it has emerged to become very dynamic, as shown by the wide variety of compounds reported. Ever since the discovery of the first polyoxotungstate framework constr…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Polyaniline–MnO2 coaxial nanofiber with hierarchical structure for high-performance supercapacitors

Hao Jiang、Jan Ma、Chunzhong Li2012-01-01Journal of Materials Chemistry

We demonstrated the facile loading of ultrafine and loosened K-birnessite MnO2 floccules on the surface of polyaniline (PANI) nanofibers by simply soaking the polyaniline nanofibers in a KMnO4 aqueous solution for electrochemical energy storage applications. The as-prepared PANI–MnO2 coaxial nanofibers with optimal co…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications