Materials Literature
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Alloys play a crucial role in several heterogeneous catalytic processes, and their applications are expected to rise rapidly. This is essentially related to the vast number of configurations and type of surface sites that multi-component materials can afford. It is well established that the chemical composition at the…
We demonstrate a facile and environmentally friendly approach to prepare well-dispersed graphene sheets by γ-ray induced reduction of a graphene oxide (GO) suspension in N,N-dimethyl formamide (DMF) at room temperature. GO is reduced by the electrons generated from the radiolysis of DMF under γ-ray irradiation. The re…
Highly luminescent graphitic carbon quantum dots (GQDs) are synthesized employing reverse micelles as nanoreactors. This method offers size tunability and narrow size distribution without any unpractical size separation process. Also, high quantum yields of maximum 35% at the 360 nm excitation wavelength are achieved.
Highly dispersed Ni nanoparticles have been successfully immobilized by the zeolitic metal-organic framework ZIF-8 via sequential deposition-reduction methods, which show high catalytic activity and long durability for hydrogen generation from hydrolysis of aqueous ammonia borane (NH(3)BH(3)) at room temperature.
Rlyso, a highly selective and sensitive pH sensor, can stain lysosomes with a novel lysosome-locating group, methylcarbitol. Rlyso was successfully used to detect lysosomal pH changes during apoptosis or induced by chloroquine while avoiding the "alkalizing effect" on lysosomes of current lysosomal probes with nitroge…
The actual service life of wind turbine gearboxes is often well below the desired 20 years. One of the prevalent failure modes in gearbox bearing raceways is white structure flaking (WSF) by the formation of butterflies and white etching cracks with associated microstructural change called white etching areas. Despite…
Novel self-healing protective coatings with nanocontainers of corrosion inhibitors open new opportunities for long-term anticorrosion protection of different metallic materials. In this paper a new type of functional nanoreservoir based on silica nanocapsules (SiNC) synthesized and loaded with corrosion inhibitor 2-me…
For the first time, we demonstrated that compressed aerogels made from crosslinked native cellulose nano/micro-fibril cellulose (NFC/MFC) show a fast shape recovery property after being immersed in water. The shape recovery degree in other solvents was also measured by the volume change of compressed aerogels. It was…
Polyoxometalate cluster anions (POMs) control formation and morphology, and serve as protecting ligands, for structurally and compositionally diverse nanostructures. While numerous examples of POM-protected metal(0) nanoparticle syntheses and reactions can now be found in the literature, the use of POMs to prepare nan…
As a fascinating two-dimensional carbon allotrope, graphene has triggered a ‘gold rush’ all over scientific research areas especially since the Nobel Prize for Physics in 2010. To exploit the prominent properties of graphene-based nanomaterials, two important problems are focused in this review: one is the synthesis o…
Simultaneous reduction and surface functionalization of graphene oxide (GO) was realized by simple refluxing of GO with octa-aminophenyl polyhedral oligomeric silsesquioxanes (OapPOSS) without the use of any reducing agents. The presence of OapPOSS made the hydrophilic GO hydrophobic, as evidenced by the good dispersi…
New unsymmetrical diarylethenes were synthesized and their photochromic and fluorescent properties are tailored by Cu(2+) and CN(-) coordinations. A novel molecular logic keypad lock is constructed based on the fluorescence emission changes by the inputs of UV/visible irradiation, Cu(2+) and CN(-).
We report on the preparation of alkylated graphenes on a large scale followed by their dispersion in organic solvents. The alkylated graphenes with variable alkyl chain lengths (Cn = 8, 12, 18) are prepared by coupling of alkylamine with carboxylic groups of graphene oxide (GrO). The FTIR, UV-Visible, and TGA results…
A novel, technically and economically benign procedure to combine vermiculite nanoplatelets with nanocellulose fibre dispersions into functional biohybrid films is presented. Nanocellulose fibres of 20 nm diameters and several micrometers in length are mixed with high aspect ratio exfoliated vermiculite nanoplatelets…
We report a ternary compound CuInTe(2) with diamond-like structure as a promising thermoelectric material in moderate temperature range. Due to the good electrical properties and low thermal conductivity, the zT value of CuInTe(2) reaches 1.18 at 850 K, better than any other un-doped diamond-like material.
The Pechini type polymerizable complex decomposition method is employed to prepare LiTi(2)(PO(4))(3) at 1000 °C in air. High energy ball milling followed by carbon coating by the glucose-method yielded C-coated nano-LiTi(2)(PO(4))(3) (LTP) with a crystallite size of 80(±5) nm. The phase is characterized by X-ray diffr…
Boron nitride (BN) domains are easily formed in the basal plane of graphene due to phase separation. With first-principles calculations, it is demonstrated theoretically that the band gap of graphene can be opened effectively around K (or K') points by introducing small BN domains. It is also found that random doping…
Interpolyelectrolyte complexes (IPECs) are typically formed when two polyelectrolytes of opposite charge are mixed together in solution. We present an overview of different strategies for the preparation of micellar IPECs, i.e., structures where such IPEC domains form the core or the shell of micelles. In addition, ve…
Mesoporous carbons synthesized via a soft-templating approach have attracted much attention due to their easy synthesis and facile control over the derived pore structure. In analogy to soft-templating approaches for mesoporous metal oxides, their synthesis is based on a sequence of forming supramolecular arrangements…
Ni(OH)(2)/MnO(2) core-shell nanowires with a nanoflake surface have been designed and synthesized, and can be applied not only in neutral electrolytes (355 F g(-1), 70.4 wt% MnO(2)) but are also appropriate for alkaline electrolytes (487.4 F g(-1), 35.5 wt% MnO(2)), with high cycling stability due to the synergistic e…