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Characterization of supramolecular polymers

Yiliu Liu、Zhiqiang Wang、Xi Zhang2012-01-01Chemical Society Reviews

Supramolecular polymers are made of monomers that are held together by noncovalent interactions. This is the reason for the wide range of novel properties, such as reversibility and responses to stimuli, exhibited by supramolecular polymers. A range of supramolecular polymerization methods have been developed leading…

Supramolecular Chemistry and ComplexesSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Hierarchically Porous Ni-Co Oxide for High Reversibility Asymmetric Full-Cell Supercapacitors

Chunhua Tang、Zhe Tang、Hao Gong2012-01-01Journal of The Electrochemical Society

Hierarchically porous Ni-Co oxide powder is successfully synthesized by a facile chemical bath deposition method. The structure and composition of Ni-Co oxide are confirmed by transmission electron microscopy and energy dispersive X-ray analysis. Scanning electron microscopy characterization indicates that the Ni-Co o…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

A “skeleton/skin” strategy for preparing ultrathin free-standing single-walled carbon nanotube/polyaniline films for high performance supercapacitor electrodes

Zhiqiang Niu、Pingshan Luan、Qi Shao 等 11 位作者2012-01-01Energy & Environmental Science

One of the most critical aspects in the preparation of single-walled carbon nanotubes (SWCNTs)/conducting polymer hybrid electrodes is to improve the energy density without seriously deteriorating their high power capability. Here, we report a “skeleton/skin” strategy for the preparation of free-standing, thin and fle…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Graphene oxide-iron oxide and reduced graphene oxide-iron oxide hybrid materials for the removal of organic and inorganic pollutants

Xin Yang、Changlun Chen、Jiaxing Li 等 6 位作者2012-01-01RSC Advances

Graphene oxide (GO) and reduced graphene oxide (RGO) were both decorated with iron oxide nanoparticles and were characterized by scanning and transmission electron microscopy, powder X-ray diffraction, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The adsorption of Pb(II), 1-naphthol,…

Adsorption and biosorption for pollutant removalGraphene research and applicationsGraphene and Nanomaterials Applications

Multivalent H-bonds for self-healing hydrogels

Jiaxi Cui、Aránzazu del Campo2012-01-01Chemical Communications

UPy is used as a reversible and dynamic crosslinker to prepare hydrogels that are injectable and undergo rapid self-healing in response to damage.

Hydrogels: synthesis, properties, applicationsPolymer composites and self-healingSupramolecular Self-Assembly in Materials

Two-dimensional crystals-based heterostructures: materials with tailored properties

Kostya S. Novoselov、A. H. Castro Neto2012-01-01Physica Scripta

Graphene is just one example of a large class of two-dimensional crystals. These crystals can either be extracted from layered three-dimensional materials or grown artificially by several different methods. Furthermore, they present physical properties that are unique because of the low dimensionality and their specia…

Graphene research and applications2D Materials and ApplicationsElectronic and Structural Properties of Oxides

Morphology evolution of urchin-like NiCo2O4 nanostructures and their applications as psuedocapacitors and photoelectrochemical cells

Qiufan Wang、斌 刘、Xianfu Wang 等 7 位作者2012-01-01Journal of Materials Chemistry

Urchin-like NiCo2O4 nanostructures were synthesized on a large scale via a simple hydrothermal method free of any template and catalyst. As-synthesized NiCo2O4 urchins have uniform diameters of 5 μm with numerous small nanorods radially grown from the center. Typical nanorods have diameters of 100–200 nm and lengths o…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationTransition Metal Oxide Nanomaterials

Carbon quantum dots/Cu2O composites with protruding nanostructures and their highly efficient (near) infrared photocatalytic behavior

Haitao Li、Ruihua Liu、Yang Liu 等 9 位作者2012-01-01Journal of Materials Chemistry

Carbon quantum dots (CQDs)/Cu2O composite with protruding nanostructures on the surface is prepared by facile one-step ultrasonic treatment. We demonstrate for the first time that this photocatalytic system could harness the (near) infrared light to enhance the photocatalytic activity based on the collective effect of…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

Unidirectional water-penetration composite fibrous film via electrospinning

Jing Wu、Nü Wang、Li Wang 等 6 位作者2012-01-01Soft Matter

An interesting “water diode” film is fabricated by a facile electrospinning technique. The fibrous film is a composite of hydrophobic polyurethane (PU) and hydrophilic crosslinked poly (vinyl alcohol) (c-PVA) fibrous layers. By taking advantages of the hydrophobic–hydrophilic wettability difference, water can penetrat…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Bimetallic catalysts for hydrogen generation

Zhehao Wei、Junming Sun、Yan Li 等 5 位作者2012-01-01Chemical Society Reviews

Research interest in bimetallic catalysts is mainly due to their tunable chemical/physical properties by a number of parameters like composition and morphostructure. In catalysis, numerous bimetallic catalysts have been shown to exhibit unique properties which are distinct from those of their monometallic counterparts…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Layer-by-layer assembly for rapid fabrication of thick polymeric films

Yang Li、Xu Wang、Junqi Sun2012-01-01Chemical Society Reviews

In the past two decades, layer-by-layer (LbL) assembly has been proven to be a convenient and versatile method to fabricate functional films. However, using traditional dipping LbL assembly to fabricate micrometer-thick films is time consuming. Compared with ultrathin films, micrometer-thick films prepared by LbL asse…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

Solution behaviors and self-assembly of polyoxometalates as models of macroions and amphiphilic polyoxometalate–organic hybrids as novel surfactants

Panchao Yin、Dong Li、Tianbo Liu2012-01-01Chemical Society Reviews

Large, hydrophilic polyoxoanions with high solubility in water and/or other polar solvents demonstrate unique solution behavior by self-assembling into single layer, hollow, spherical "blackberry" structures, which is obviously different from small, simple ions. These macroions cannot be treated as insoluble colloidal…

Molecular Sensors and Ion DetectionPolyoxometalates: Synthesis and ApplicationsSupramolecular Self-Assembly in Materials

Dodecyl sulfate-induced fast faradic process in nickel cobalt oxide–reduced graphite oxide composite material and its application for asymmetric supercapacitor device

Xu Wang、Wan Shuang Liu、Xuehong Lu 等 4 位作者2012-01-01Journal of Materials Chemistry

In this contribution, we report a facile preparation method of nickel cobalt oxide–reduced graphite oxide (NiCo2O4–rGO) composite material. A fast Faradic process has been realized by sodium dodecyl sulfate (SDS)-induced ultrasmall NiCo2O4 nanocrystals on rGO. As a result, this composite material gives a high specific…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Photo-induced water–oil separation based on switchable superhydrophobicity–superhydrophilicity and underwater superoleophobicity of the aligned ZnO nanorod array-coated mesh films

Dongliang Tian、Ximu Zhang、Yu Tian 等 7 位作者2012-01-01Journal of Materials Chemistry

Stimulus-responsive surface wettability, especially photoresponsive surface wettability, has been intensively studied. Meanwhile, multifunctional surfaces, especially for the treatment of oil contaminated water, have aroused worldwide attention. Recently, pH-responsive surfaces with controllable oil–water separation h…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrohydrodynamics and Fluid Dynamics

Synthesis and characterization of electrospun polyvinyl alcohol nanofibrous scaffolds modified by blending with chitosan for neural tissue engineering

Masoud Mozafari、Fathollah Moztarzadeh、Jalali 等 8 位作者2012-01-01International Journal of Nanomedicine

Among several attempts to integrate tissue engineering concepts into strategies to repair different parts of the human body, neuronal repair stands as a challenging area due to the complexity of the structure and function of the nervous system and the low efficiency of conventional repair approaches. Herein, electrosp…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Silicon-containing polymer-derived ceramic nanocomposites (PDC-NCs): preparative approaches and properties

Emanuel Ionescu、Hans‐Joachim Kleebe、Ralf Riedel2012-01-01Chemical Society Reviews

Composites consist by definition of at least two materials (Gibbsian phases) with rather different properties. They exhibit a heterogeneous microstructure and possess improved properties with respect to their components. Furthermore, the design of their microstructure allows for tailoring their overall properties. In…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsAdvanced materials and composites

Surface strontium enrichment on highly active perovskites for oxygen electrocatalysis in solid oxide fuel cells

Ethan J. Crumlin、Eva Mutoro、Zhi Liu 等 10 位作者2012-01-01Energy & Environmental Science

Perovskite oxides have high catalytic activities for oxygen electrocatalysis competitive to platinum at elevated temperatures. However, little is known about the oxide surface chemistry that influences the activity near ambient oxygen partial pressures, which hampers the design of highly active catalysts for many clea…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of Oxides

A high thermoelectric figure of merit ZT > 1 in Ba heavily doped BiCuSeO oxyselenides

J. Li、Jiehe Sui、Yanling Pei 等 9 位作者2012-01-01Energy & Environmental Science

A high ZT value of ∼1.1 at 923 K in the BiCuSeO system is achieved via heavily doping with Ba and refining grain sizes (200–400 nm), which is higher than any thermoelectric oxide. Excellent thermal and chemical stabilities up to 923 K and high thermoelectric performance confirm that the BiCuSeO system is promising for…

Advanced Thermoelectric Materials and DevicesGas Sensing Nanomaterials and SensorsChalcogenide Semiconductor Thin Films

Magnetic nanoparticles for the manipulation of proteins and cells

Yue Pan、Xuewen Du、Fan Zhao 等 4 位作者2012-01-01Chemical Society Reviews

In the rapidly developing areas of nanobiotechnology, magnetic nanoparticles (MNPs) are one type of the most well-established nanomaterials because of their biocompatibility and the potential applications as alternative contrast enhancing agents for magnetic resonance imaging (MRI). While the development of MNPs as al…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesCharacterization and Applications of Magnetic Nanoparticles

Facile synthesis of highly emissive carbon dots from pyrolysis of glycerol; gram scale production of carbon dots/mSiO2 for cell imaging and drug release

Chih-Wei Lai、Yi‐Hsuan Hsiao、Yung‐Kang Peng 等 4 位作者2012-01-01Journal of Materials Chemistry

We report on a facile method to synthesize carbon dots (CDs) using glycerol solvent as a single precursor via a pyrolysis process free from catalysts. This method is extremely simple and economical, and provides a feasible route for mass production of highly emissive CDs. For rationalization, a mechanism incorporating…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsGraphene and Nanomaterials Applications