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Insights into the Self-Assembly Mechanism of the Modular Polyoxometalate “Keggin-Net” Family of Framework Materials and Their Electronic Properties

Johannes Thiel、Pedro I. Molina、Mark D. Symes 等 4 位作者2011-12-16Crystal Growth & Design

The mechanism for the syntheses of inorganic framework materials based solely on polyoxometalate Keggin clusters has been examined and their electronic properties have been investigated. The assembly of the modular network compounds with the molecular formula (C 4 H 10 NO) n [W 72 M 12 O 268 X 7 ] (with the heteroatom…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

Plasma-Enhanced Copolymerization of Amino Acid and Synthetic Monomers

Kyle Anderson、Seth L. Young、Hao Jiang 等 7 位作者2011-12-16Langmuir

In this paper we report the use of plasma-enhanced chemical vapor deposition (PECVD) for the simultaneous deposition and copolymerization of an amino acid with other organic and inorganic monomers. We investigate the fundamental effects of plasma-enhanced copolymerization on different material chemistries in stable ul…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

Redox-switchable devices based on functionalized graphene nanoribbons

Daniele Selli、Matteo Baldoni、Antonio Sgamellotti 等 4 位作者2011-12-16Nanoscale

The possibility of tuning the electronic properties of graphene by tailoring the morphology at the nanoscale or by chemical functionalization opens interesting perspectives towards the realization of devices for nanoelectronics. Indeed, the integration of the intrinsic high carrier mobilities of graphene with function…

Advancements in Battery MaterialsGraphene research and applicationsMolecular Junctions and Nanostructures

Ontogenetic and interspecific valve shape variation in the Pinnatae group of the genusSurirellaand the description ofS. lacrimulasp. nov.

Jonathan David English、Marina Potapova2011-12-16Diatom Research

The morphology and ontogenetic allometric trends of several taxa in the Pinnatae group of Surirella were studied using traditional morphometrics, landmark-based shape analysis, and light and electron microscopy. We investigated separately two groups of species: the first consisted of S. brebissonii Krammer & Lange-Ber…

Geology and Paleoclimatology ResearchDiatoms and Algae ResearchMorphological variations and asymmetry

DFT Study of the Electronic Properties of LaOCl Surfaces

Steeve Chrétien、Horia Metiu2011-12-16The Journal of Physical Chemistry C

We use density functional theory to study the properties of low index flat faces (i.e., not having steps) of lanthanum oxychloride LaOCl. We calculate the surface energies and the energies to make oxygen and chlorine vacancies on the surface by producing 1 / 2 O 2 or 1 / 2 Cl 2 in the gas phase. We find that the elect…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

A computational and experimental investigation of the mechanical properties of single ZnTe nanowires

Keivan Davami、Bohayra Mortazavi、Hessam Ghassemi 等 7 位作者2011-12-16Nanoscale

One-dimensional nanostructures such as ZnTe, CdTe, Bi(2)Te(3) and others have attracted much attention in recent years for their potential in thermoelectric devices among other applications. A better understanding of their mechanical properties is important for the design of devices. A combined experimental and comput…

Advanced Thermoelectric Materials and DevicesNanowire Synthesis and ApplicationsThermal properties of materials

Review: The chirality and bionic studies of polyoxometalates: the synthetic strategy and structural chemistry

Weilin Chen、Huaqiao Tan、Enbo Wang2011-12-16Journal of Coordination Chemistry

Chiral polyoxometalates (POMs) have been a hot topic because of their potential applications in the fields of stereoselective catalysis, bio-simulation, sensing, nonlinear materials, and medicine. In view of the extensive work on chiral POMs, four parts are included in this review to give a broad overview on recent de…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

A facile method to prepare zirconia electrospun fibers with different morphologies and their novel composites based on cyanate ester resin

Dake Qin、Aijuan Gu、Guozheng Liang 等 4 位作者2011-12-16RSC Advances

Using zirconium propoxide as the precursor, a new method combining the advantages of electrospinning and sol–gel approaches is set up to facilely fabricate zirconia (ZrO2) nanofibers with controllable chemical and morphological structures in batch size on a standard electrospinning equipment. Interestingly, zirconia (…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Fabrication and thermoelectric properties of Yb-doped ZrNiSn half-Heusler alloys

Xiaohua Liu、Jian He、Hanhui Xie 等 5 位作者2011-12-16International Journal of Smart and Nano Materials

Half-Heusler (HH) alloys constitute an important class of materials that exhibit promising potential in high-temperature thermoelectric (TE) power generation. In this work, we synthesized Zr1−x Yb x NiSn (x = 0, 0.01, 0.02, 0.04, 0.06 and 0.10) HH alloys using a time-efficient levitation melting and spark plasma sinte…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsHeusler alloys: electronic and magnetic properties

Tensile properties degradation of GFRP composites containing nanoclay in three different environments

Honggang Zhu、Christopher K.Y. Leung、Jang‐Kyo Kim 等 4 位作者2011-12-16Journal of Composite Materials

Glass fiber-reinforced polymer (GFRP) composite with neat epoxy matrix and GFRP nanocomposite with epoxy–organoclay nanocomposite matrix were prepared. Their tensile properties degradation at elevated temperatures and in alkaline as well as freeze–thaw cycling environments was studied by performing the uniaxial tensio…

Structural Behavior of Reinforced ConcretePolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Bamboo fibre processing: insights into hemicellulase and cellulase substrate accessibility

Jiajia Fu、Gibson S. Nyanhongo、Carla Silva 等 8 位作者2011-12-16Biocatalysis and Biotransformation

A biological approach for degumming bamboo substrates has been assessed. The ability of various commercially available enzymes, including cellulase, xylanase, pectinase and mannanase, to hydrolyze bamboo powders was investigated. In addition, a commercial cellulase preparation was applied onto bamboo fibre bundles obt…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesBamboo properties and applications

Giant enhancement of the second harmonic generation efficiency in poled multilayered silica glass structures

Ksenia Yadav、Claire L. Callender、Christopher W. Smelser 等 7 位作者2011-12-16Optics Express

Multilayered thin-film doped silica structures are experimentally demonstrated as an effective tool to enhance the second-order nonlinear properties induced in thermally poled glass devices. A 204-fold improvement is obtained in the second harmonic generated (SHG) in a poled structure with a 3 μm-thick multilayered st…

Glass properties and applicationsPhotonic Crystals and ApplicationsPhotorefractive and Nonlinear Optics

Controlledin situgrowth of tunable plasmonic self-assembled nanoparticle arrays

Ruggero Verre、K. Fleischer、J. F. McGilp 等 7 位作者2011-12-16Nanotechnology

Self-assembled silver nanoparticle (NP) arrays were produced by deposition at glancing angles on transparent stepped Al2O3 templates. The evolution of the plasmonic resonances has been monitored using reflection anisotropy spectroscopy (RAS) during growth. It is demonstrated that the morphology of the array can be tai…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Quantitative Characterization of Individual Microdroplets using Surface-Enhanced Resonance Raman Scattering Spectroscopy

Christopher D. Syme、Chiara Martino、Rama Yusvana 等 5 位作者2011-12-16Analytical Chemistry

Surface-enhanced resonance Raman scattering (SERRS) spectroscopy is a highly sensitive optical technique capable of detecting multiple analytes rapidly and simultaneously. There is significant interest in SERRS detection in micro- and nanotechnologies, as it can be used to detect extremely low analyte concentrations i…

Gold and Silver Nanoparticles Synthesis and ApplicationsMicrofluidic and Capillary Electrophoresis ApplicationsInnovative Microfluidic and Catalytic Techniques Innovation

Study of in vitro degradation of biodegradable polymer based thin films and tissue engineering scaffolds

Naznin Sultana2011-12-16AFRICAN JOURNAL OF BIOTECHNOLOGY

This paper reports the in vitro degradation of three-dimensional, highly porous tissue engineering scaffolds and non-porous thin films based on poly (L-lactide) (PLLA) biopolymers. The tissue engineering scaffolds were produced through the emulsion freezing/freeze-drying technique. The nonporous thin films were produc…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing Technologies

Synthesis of Star-Shaped Macromolecular Schiff Base Complexes Having Melamine Cores and Their Magnetic and Thermal Behaviors

Şaban Uysal、Ziya Erdem Koç、Şeyma Çelikbilek 等 4 位作者2011-12-16Synthetic Communications

We aim to study magnetic and thermal behaviors of some melamine cored macromolecular Schiff base complexes. In this context, tripodal ligands were synthesized by reacting melamine with 4-carboxybenzaldehyde or 4-hydroxybenzaldehyde. Then, 16 new trinuclear Fe(III), Cr(III), Mn(III), and Al(III) complexes were synthesi…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistrySynthesis and Characterization of Heterocyclic Compounds

Gold Nanospacers Greatly Enhance the Capacitance of Electrochemically Reduced Graphene

Lucia Buglione、Alessandra Bonanni、Adriano Ambrosi 等 4 位作者2011-12-16ChemPlusChem

Abstract Graphene has great potential in electrochemical storage applications for supercapacitors owing to its high conductivity, large surface area, and the economical feasibility in producing it. The main issue that faces graphene nanomaterials in this application is that they tend to restack, thus decreasing the ac…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Super-large dendrites composed of trigonal PbO 2 nanoplates with enhanced performances for electrochemical devices

Liang‐Xin Ding、Fu-Lin Zheng、Jianwei Wang 等 6 位作者2011-12-16Chemical Communications

Correction for 'Super-large dendrites composed of trigonal PbO2 nanoplates with enhanced performances for electrochemical devices' by Liang-Xin Ding et al., Chem. Commun., 2012, 1275-1277, DOI: 10.1039/C2CC15271A.

Quantum Dots Synthesis And PropertiesAdvanced Thermoelectric Materials and DevicesTransition Metal Oxide Nanomaterials

Synergistic antibacterial effects of nano zinc oxide combined with silver nanocrystales

Alireza Jafari2011-12-16African Journal of Microbiology Research

Antibacterial nanocrystals have attracted great interests in recent years. In fact, with the emergence and increase of microbial organisms resistant to multiple antibiotics, many researchers have tried to develop new antibiotics. The aim of this research is to compare antibacterial activity of mono-metallic with compo…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsNanotechnology research and applications