A new stereocontrolled approach to KDO containing disaccharides
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A.c. conductivity in binary V2O5-P2O5 glasses
The a.c. conductivity of binary V2O5-P2O5 glasses containing 40, 50, 60 and 70mol% V2O5 has been measured at temperatures between 100 and 423 K, and for frequencies up to 100 MHz. The results are interpreted in terms of Long's polaron hopping model. The polaron parameters calculated from the above model appear reasona…
Processing of composites with titanate coupling agents—a review
Abstract It is proposed that titanium‐derived coupling agents react with free protons at the inorganic interface to form organic monomolecular layers on the inorganic surface, which causes inorganic/organic phase compatibilization resulting in new composite property, catalysis, adhesion, and rheology performance stand…
Absorption Bands of Electrochemically-Colored Films of WO3, MoO3 and MocW1-cO3
Optical absorption bands of electrochemically-colored films of amorphous WO 3 , MoO 3 and Mo c W 1- c O 3 were investigated. The peak photon energy of the bands depends not only on the amount of injected charges but also on the Mo content. In the WO 3 films, the absorption band originates from the intervalence trasfer…
Auxospore formation and development inNeidium(Bacillariophyta)
Neidium affine is allogamous and exhibits a form of physiological anisogamy in which the behaviour but not the morphology of the two gametes produced by each gametangium differ: one gamete is active, the other passive. The active gamete moves across to the other gametangium via a narrow fusion canal to effect fertiliz…
VALVE MORPHOGENESIS IN THE PENNATE DIATOM ACHNANTHES COARCTATA
ABSTRACT Mitosis and valve morphogenesis in the pennate diatom Achnanthes coarctata (Bréb. in W. Sm.) Grun. are described. After cytokinesis, both daughter nuclei and their microtubule centers (MCs) are found near one side of the cell. Each new tubular silica deposition vesicle (SDV) arises centrally, forming a single…
Heterogeneous nucleation of poly(ethylene terephthalate)
Abstract The effect of various metal salts as nucleating additives for poly(ethylene terephthalate) (PET) has been investigated. In the case of sodium benzoate and probably for all other effective nucleating additives, the nucleation process can be divided into a “heterogeneous particle nucleation” performed by the un…
Mechanism of Iron Oxide Dissolution—A Review of Recent Literature
Recent literature concerning the dissolution of iron oxide and removal of iron oxide from metal surfaces is reviewed. Studies of electrochemical phenomena and reaction kinetics are discussed. Rate expressions based on this work are critically examined, and mechanisms for the dissolution of free iron oxide and iron oxi…
Some Considerations About Bond Indices in Non-orthogonal Bases and the MO Calculation of Valence and Oxidation Number
In order to guarantee the desired invariance properties of bond indices, we show the importance of expliciting the tensor character of the matrices concerned, so as to deal with a contraction in the tensor sense between a covariant index and a contravariant one. A straightforward definition of oxidation numbers is pro…
Alloy cluster beams: nickel/chromium and nickel/aluminum
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAlloy cluster beams: nickel/chromium and nickel/aluminumE. A. Rohlfing, D. M. Cox, R. Petkovic-Luton, and A. KaldorCite this: J. Phys. Chem. 1984, 88, 25, 6227–6231Publication Date (Print):December 1, 1984Publication History Published online1 May 2002Published inissue 1 Dece…
Effects of Exchangeable Cation Composition on the Thermal Expansion/Contraction of Clinoptilolite
Abstract To understand and predict the effects of a thermal pulse induced by a radioactive waste repository on clinoptilolite-bearing rocks, the lattice parameters of 6 natural and 3 cation-exchanged (Ca, K, Na) clinoptilolites were studied as a function of temperature. The samples were examined at room temperature, u…
Effect of Thiosulfate on Crevice Corrosion of Stainless Steels
Crevice corrosion studies were conducted on AISI 304, AISI 316L, and UHB 904L stainless steels using Teflon/metal crevices exposed to aqueous solutions of 1M NaCl and 1M NaCl + 0.01 M Na2S2O3. Tests were conducted at 22 C, except for some additional tests at 55 C on the more crevice resistant 904L. Crevice potentials…
Screening of hydrodynamic interactions in dense polymer solutions: a phenomenological theory and neutron-scattering investigations
We present a study on single-chain relaxation of linear polymers covering the full concentration range from dilute solution to the melt. Assuming incomplete screening of the hydrodynamic interaction between different segments of a chain, we introduce a phenomenological theory of chain dynamics in semidilute and concen…
Proton NMR study of diffusion in continuous, nonstoichiometric metal-hydrogen systems:HfV2HxandZrV2Hx
The proton spin-relaxation times ${T}_{1}$ and ${T}_{2}$ in the continuous, nonstoichiometric, single-phase hydrides $\mathrm{Zr}{\mathrm{V}}_{2}{\mathrm{H}}_{x}$ and $\mathrm{Hf}{\mathrm{V}}_{2}{\mathrm{H}}_{x}$ ($0.25\ensuremath{\le}x\ensuremath{\le}4.2$) were measured in the temperature range $100 \mathrm{K}\ensure…
Iron(III)-catalyzed oxygenation of catechols. Structure of (nitrilotriacetato)(3,5-di-tert-butylcatecholato)ferrate(III) dianion
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIron(III)-catalyzed oxygenation of catechols. Structure of (nitrilotriacetato)(3,5-di-tert-butylcatecholato)ferrate(III) dianionL. S. White, P. V. Nilsson, L. H. Pignolet, and L. Que Jr.Cite this: J. Am. Chem. Soc. 1984, 106, 26, 8312–8313Publication Date (Print):December 1,…
The inelastic mean free path of electrons in some semiconductor compounds and metals
Abstract The elastic backscattering probability P e of electrons is proportional to the product of the inelastic mean free path (IMFP), effective backscattering cross section (σ eff ), and atomic density ( N ). Thus, experimental evaluation of P e , e.g. from the elastic peak intensity measurements, enables the determ…
Productive Lifespan of Bull Progeny Groups: Failure Time Analysis
For genetic parameters herd lives of 587,013 Holstein cows recorded in Dairy Herd Improvement were analyzed by paternal half-sister analysis and Cox regression models. Length of life was duration in days between birth and failure or censoring. Failure was defined in two ways; first was death or sale for beef as determ…
A XANES investigation of the bonding of divalent lead in solids
XANES (X-ray absorption near-edge structure) spectra of divalent lead compounds have been studied at both the Pb LIII and LI edges using synchrotron x rays from CHESS (Cornell High Energy Synchrotron Source). The combined LIII and LI near-edge spectral features strongly support a sp3d2 hybridization scheme in covalent…
An experimental study of hypervalent molecular clusters by neutralized ion beam spectroscopy: ammonium-ammonia (NH4(NH3)n) and deuterated ammonium-ammonia (ND4(ND3)n)
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn experimental study of hypervalent molecular clusters by neutralized ion beam spectroscopy: ammonium-ammonia (NH4(NH3)n) and deuterated ammonium-ammonia (ND4(ND3)n)Gregory I. Gellene and Richard F. PorterCite this: J. Phys. Chem. 1984, 88, 26, 6680–6684Publication Date (Pr…
Time-resolved light scattering studies on the kinetics of phase separation and phase dissolution of polymer blends. 2. Phase separation of ternary mixtures of polymer A, polymer B, and solvent
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTime-resolved light scattering studies on the kinetics of phase separation and phase dissolution of polymer blends. 2. Phase separation of ternary mixtures of polymer A, polymer B, and solventTakeji Hashimoto, Kouji Sasaki, and Hiromichi KawaiCite this: Macromolecules 1984,…