Materials Literature
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Structural arrangements of nanoplatelets in a polymer matrix play an important role in determining their properties. In the present study, multilayered composite films of poly(vinyl alcohol) (PVA) with Laponite clay are assembled by layer-by-layer (LBL) deposition. The LBL films are found to be hydrated, flexible and…
The magnetic behavior of the pentanuclear complex of formula Mn II (O 2 CCH 3 ) 2 [12-MC Mn III (N)shi -4](DMF) 6, 1, was investigated using magnetization and magnetic susceptibility measurements both in the solid state and in solution. Complex 1 has a nearly planar structure, made of a central Mn II ion surrounded by…
The charge-density-wave phase of TiSe(2) was studied by angle-resolved photoelectron spectroscopy and resistivity measurements investigating the influence of the band gap size and of a varying population of the conduction band. A gradual suppression of the charge-density-wave-induced electronic superstructure is obser…
ZnO nanocrystals of high quality with pure UV-emitting properties were synthesized through a new microfluidic approach based on supercritical fluids and separation of nucleation/growth and functionalization steps (see picture). The as-synthesized ZnO nanocrystals (NCs) show exciton luminescence without classical defec…
We performed a series of density functional theory + U (DFT + U) calculations to explore the energetics of various defects in UO${}_{2}$, i.e., noble gases (He, Ne, Ar, Kr, Xe), Schottky defects, and the interaction between these defects. We found the following: (1) collinear antiferromagnetic UO${}_{2}$ has an energy…
Polyurethanes and polycarbonates are widely used in a variety of applications including engineering, optical devices, and high-performance adhesives and coatings, etc., and are expected to find use also in the biomedical field owing to their biocompatibility and low toxicity. However, these polymers are currently prod…
Dopant-induced phenomena: Doping with sodium ions can stimulate the formation of monodisperse ultrathin La2O2S nanoplates with tunable self-assembled superstructures (see picture) and robust fluorescence in surfactant solutions by creating oxygen vacancies in the host lattice during sulfurization reactions.
Periodic mesoporous organosilica derivatives (PMOs) that bear a high density of Ru and Ir complexes on pore walls were synthesized using a unique two-step approach: 1) synthesis of PMO containing phenylpyridine bridging groups in the pore walls, and 2) post-synthetic formation of metal complexes using the phenylpyridi…
A targeted anticancer prodrug system was fabricated with 180 nm mesoporous silica nanoparticles (MSNs) as carriers. The anticancer drug doxorubicin (DOX) was conjugated to the particles through an acid-sensitive carboxylic hydrazone linker which is cleavable under acidic conditions. Moreover, folic acid (FA) was coval…
Abstract We present a new model for bubbly cavitating flows. Based on volume-averaged equations, a subgrid model is added to account for a bubble, or multiple bubbles, within each computational cell. The model converges to the solution of ensemble-averaged bubbly flow equations for weak oscillations and monodisperse s…
We performed optical annealing experiments at the edges of nanopatterned graphene to study the resultant edge reconstruction. The lithographic patterning direction was orthogonal to a zigzag edge. μ-Raman spectroscopy shows an increase in the polarization contrast of the G band as a function of annealing time. Further…
Due to its demonstrated usefulness in fields such as trace analysis, biodiagnosis, and in vivo study, surface-enhanced Raman scattering (SERS) has received renewed interest in recent years. Development of SERS substrates is of great importance as the SERS intensity and reproducibility depend strongly on the SERS subst…
We investigated transparent conducting aluminium-doped zinc oxide thin films fabricated by atomic layer deposition (ALD). For the thermal ALD, diethylzinc and trimethylaluminium were used as the Zn and Al precursors, respectively. The electrical, structural and optical properties were systematically investigated as fu…
A nanoparticle formulation of docetaxel (DTX) was designed to address the strengths and limitations of current taxane delivery systems: PEGylation, high drug conjugation efficiency (>30 wt %), a slow-release mechanism, and a well-defined and stable nanoparticle identity were identified as critical design parameters. T…
Toxicity effects induced by nanosuspensions of CuO (<50 nm; Sigma-Aldrich) on macrophytic algae cells of Nitellopsis obtusa (96-h median lethal concentration [LC50]), microphytic algae Chlorella (30-min median inhibitory concentration [IC50]), shrimp Thamnocephalus platyurus (24-h LC50), and rotifer Brachionus calycif…
BF(2)-Azadipyrromethene dyes are a promising class of NIR emitter (nonhalogenated) and photosensitizer (halogenated). Spectroscopic studies on a benchmark example of each type, including absorption (one and two photon), time-resolved transient absorption (ps-ms) and fluorescence, are reported. Fast photodynamics revea…
We report x-ray photon correlation spectroscopy (XPCS) and rheometry experiments to study the temporal evolution of gel formation and aging in suspensions of silica nanocolloids possessing a tunable short-range attraction. The colloid volume fractions, φ = 0.20 and 0.43, are below the glass regime at high concentratio…
Emulsions were prepared using poly(N-isopropylacrylamide) microgels as thermoresponsive stabilizers. The latter are well-known for their sensitivity to temperature: they are swollen by water below the so-called volume phase transition temperature (VPTT = 33 °C) and shrink when heated above it. Most of the studies repo…
Nanoparticle Cluster Arrays (NCAs) are a class of electromagnetic materials that comprise chemically defined nanoparticles assembled into clusters of defined size in an extended deterministic arrangement. NCAs are fabricated through integration of chemically synthesized building blocks into predefined patterns using a…
Stereoregular tetraphenylethene derivatives (Z)-o-BCaPTPE and (Z)-o-BTPATPE featured with chiasmatic conformations and aggregation-enhanced emission characteristics are synthesized using a McMurry reaction. Both luminogens exhibit high hole and electron mobilities. Organic light-emitting diodes (OLEDs) using (Z)-o-BCa…