Materials Literature
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Large-area (>1 cm 2 ), vertically aligned ZnGa 2 O 4, Mn 2+ -doped ZnGa 2 O 4 (ZnGa 2 O 4:Mn 2+ ) and Cr 3+ -doped ZnGa 2 O 4 (ZnGa 2 O 4:Cr 3+ ) nanowire arrays were synthesized by a two-step thermal evaporation method using ZnO nanowire arrays as the templates followed by reaction with Ga and/or dopant (Mn or Cr) va…
This letter reports the magnetic shape memory effect in a polycrystalline Ni45.2Mn36.7In13Co5.1 alloy having the martensitic transformation around 310 K. An application of magnetic field shifts the transformation to lower temperatures by 6.7 K/T. Originating from the magnetically induced martensite-austenite transform…
The synthesis and electrochemical characterization of ferrocene functional polymethacrylate brushes on indium tin oxide (ITO) electrodes using surface-initiated atom transfer radical polymerization (SI-ATRP) is reported. SI-ATRP of ferrocene-containing methacrylate (FcMA) monomers from a phosphonic acid initiator-modi…
Transfer of photoexcited charge from PbS nanocrystals to ligand molecules is investigated in different solvents. We find that the charge transfer rate increases dramatically with solvent dielectric constant. This trend is accounted for by a modified Marcus theory that incorporates only static dielectric effects. The c…
Analytical models of proton transverse relaxation rate enhancement by magnetic nanoparticles were tested by making measurements on model experimental systems in a field of 1.4 T. Proton relaxivities were measured for five aqueous suspensions of iron oxide (maghemite) nanoparticles with nominal mean particle sizes of 6…
Low temperature growth of epitaxial graphene on SiC is facilitated by carbon evaporation under ultrahigh vacuum (UHV) conditions. By counteracting the need for complete Si depletion as in the conventional sublimation method, monolayer graphene evolves at significantly lower temperatures by depositing additional carbon…
Fully epitaxial Co2MnSi (CMS)/MgO/CMS magnetic tunnel junctions (MTJs) with various values of Mn composition α in Co2MnαSi electrodes were fabricated and the influence of α on the tunnel magnetoresistance (TMR) characteristics of these MTJs was investigated. MTJs with Mn-rich CMS electrodes showed TMR ratios, up to 11…
Refractive-index-matched indium–tin-oxide (ITO) electrode for thin-film transistor liquid crystal displays is presented to reduce optical losses caused by Fresnel reflections. Simulations show a 24% improvement in optical transmittance when the conventional dense ITO is replaced with the refractive-index-matched ITO i…
Eu 2 + , Dy3+, and Er3+ ions codoped SrAl2O4 phosphors with near infrared (NIR) (at 1530 nm) long-persistent phosphorescence were synthesized by a combustion method. The NIR phosphorescence emission was realized through a persistent energy transfer process from Eu2+ ions to Er3+ ions. Optimal Er3+ concentration for th…
There are no treatments for reversing or halting cataract, a disease of the structural proteins in the eye lens, that has associations with other age-related degenerative conditions such as Alzheimer's disease. The incidence of cataract and associated conditions is increasing as the average age of the population rises…
⟨ 001 ⟩ -oriented (K0.5Na0.5)(Nb0.97Sb0.03)O3 (KNNS) ceramics with a narrow orientation distribution (full width at half maximum=7.0°) were produced by templated grain growth using NaNbO3 templates. Excellent electromechanical properties were obtained from −70 °C to the polymorphic phase transition (PPT) at 160 °C. Te…
Diarylethenes are photosensitive π-conjugated molecules whose application to various molecular devices is expected. The molecular and electronic structures of diarylethenes are switchable upon photoirradiation with their reversible structural isomerization. Site-specific electron transport phenomena through a diarylet…
Abstract Thermoregulated phase‐transfer catalysis for the transfer hydrogenation of 2‐octanone in 2‐propanol/H 2 O biphasic media was achieved with ruthenium‐bearing microgel‐core star polymers with amphiphilic, thermosensitive poly(ethylene glycol) (PEG) arms [Ru(II)‐PEG star], which were directly prepared by the rut…
Abstract Well‐defined macromolecular brushes with poly( N ‐isopropyl acrylamide) (PNIPAM) side chains on random copolymer backbones were synthesized by “grafting from” approach based on click chemistry and reversible addition‐fragmentation chain transfer (RAFT) polymerization. To prepare macromolecular brushes, two li…
Hydrogen bonding to anions drives the helical folding of an indolocarbazole oligomer, thus resulting in an internal cavity with six NHs and two OHs for binding sulfate with high selectivity.
We present in this Letter a free-energy approach to the dynamics of a fluid near a nanostructured surface. The model accounts both for the static phase equilibrium in the vicinity of the surface (wetting angles, Cassie-Wenzel transition) and the dynamical properties like liquid slippage at the boundary. This method br…
In this paper, Pt nanoparticles with good shapes of nanocubes and nano-octahedra and well-controlled sizes in the range 5-7 and 8-12 nm, respectively, have been successfully synthesized. The modified polyol method by adding silver nitrate and varying the molar ratio of the solutions of silver nitrate and H(2)PtCl(6) h…
Using the full-potential linearized augmented plane wave method, we study the magnetism and electronic structures of Mg-doped SnO2 system. We find that the Sn23MgO48 supercell with an isolated Mg atom produces a total magnetic moment of 2.00μB and introduces spin-polarized 2p states in the band gap. The origin of the…
We demonstrate dispersion and exfoliation of nanotubes in two new solvents for nanotubes, cyclohexyl-pyrrolidone (CHP) and 1-benzyl-2-pyrrolidinone (NBenP). Both solvents are structural analogues of the well-known nanotube solvent N -methyl-pyrrolidone. Each solvent can disperse nanotubes at high concentrations, up to…
We applied matrix-assisted laser desorption/ionization (MALDI) for mass analysis of Au clusters stabilized by poly(vinyl-pyrrolidone) (PVP) and discovered a series of magic numbers for Au cluster size: 35 +/- 1, 43 +/- 1, 58 +/- 1, 70 +/- 3, 107 +/- 4, 130 +/- 1, and 150 +/- 2. Magic numbers smaller than approximately…