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2006 W.R. Whitney Award Lecture: Application of Advanced Electrochemical Techniques and Concepts to Corrosion Phenomena

M. Keddam2006-12-01CORROSION

In the early 1960s, application of electrochemistry to corrosion was limited to the open-circuit potential measurements, the Stern and Geary methods, and the plot of current-voltage curves with the recently invented potentiostats. These techniques were totally unable to provide a reliable description of the intricate…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilitySmart Materials for Construction

A Graphical Representation of Equivalence Classes of AMP Chain Graphs

Alberto Roverato、Milan Studený2006-12-01OpenAlex

This paper deals with chain graph models under alternative AMP interpretation. A new representative\nof an AMP Markov equivalence class, called the largest deflagged graph, is proposed. The\nrepresentative is based on revealed internal structure of the AMP Markov equivalence class. More\nspecifically, the AMP Markov e…

Parkinson's Disease Mechanisms and TreatmentsAdvanced Software Engineering Methodologiesbiodegradable polymer synthesis and properties

Effect of Pre-covered Oxygen on the Dehydrogenation Reactions over Copper Surface: A Density Functional Theory Study

Shuxia Tao、Gui‐Chang Wang、Xian‐He Bu2006-12-01The Journal of Physical Chemistry B

Dehydrogenation of five species including CH3OH, CH3O, H2COO, NH3, and H2O over clean and oxygen-modified copper surfaces has been investigated by the first-principle density functional calculations within the generalized gradient approximation. The reaction enthalpies and the activation energies have been calculated…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Natural Heat-Sinking Control Method for High-Speed Actuation of the SMA

Chee Siong Loh、Hiroshi Yokoi、Tamio Arai2006-12-01International Journal of Advanced Robotic Systems

This paper describes two methodologies for increasing the actuation speed of the shape memory alloy (SMA) actuator in ambient environment. The first method involves the implementation of a simple, light-weight heat sink, which consists only of a combination of an outer metal tube with the silicone grease, but able to…

Shape Memory Alloy Transformations

Influence of heteroligand complexation on the thermal, photoluminescent, and film-forming properties of some aromatic terbium(III) carboxylates

Oxana Kotova、Svetlana V. Eliseeva、A. A. Volosnikov 等 7 位作者2006-12-01Russian Journal of Coordination Chemistry

With homoligand TbL3 and heteroligand complexes TbL3(Q)n (HL = HSal (salicylic acid) and HPA (2-anilinobenzoic acid); Q = TPPO (triphenylphosphine oxide) and TOPO (tri(n-octyl)phosphine oxide); n = 1 or 2) as examples, it was shown that heteroligand complexation affects not only the thermal and photoluminescent proper…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Three‐Dimensional Observations of Grain Boundary Morphologies in a Cylinder‐Forming Block Copolymer

Hiroshi Jinnai、Kaoru Yasuda、Toshio Nishi2006-12-01Macromolecular Symposia

Abstract The grain boundary morphology of a cylinder‐forming poly(styrene block ‐isoprene) (SI) diblock copolymer was investigated using transmission electron microtomography (TEMT). The three‐dimensional (3D) morphologies of the grain boundaries between the two grains with different orientation angle, α, were investi…

Microstructure and mechanical propertiesAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

Development of Fitting Methods Using Geometric Progression Formulae of Gamma-ray Buildup Factors

Yoshitaka Yoshida2006-12-01Journal of Nuclear Science and Technology

The gamma ray buildup factors are represented by an approximation method to speed up calculation using the point attenuation kernel method. The fitting parameters obtained by the GP formula and Taylor's formula are compiled in ANSI/ANS 6.4.3, available without any limitation. The GP formula featured high accuracy but…

Radiation Shielding Materials AnalysisAdvanced X-ray and CT ImagingX-ray Diffraction in Crystallography

Simple setup to measure electrical properties of polymeric films

R. Hiremath、M.K. Rabinal、B. G. Mulimani2006-12-01Review of Scientific Instruments

A simple method to measure electrical conductivity of conducting organic films has been described. A setup, based on four-probe technique, is specifically designed and fabricated for nondestructive electrical conductivity measurements of freestanding thin films. The current-voltage and temperature dependent characteri…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Synthesis and Characterization of Crystalline Hyperbranched Polysiloxysilane with POSS Groups at the Terminal Position

Makoto Seino、Teruaki Hayakawa、Yoshihito Ishida 等 4 位作者2006-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTSynthesis and Characterization of Crystalline Hyperbranched Polysiloxysilane with POSS Groups at the Terminal PositionMakoto Seino, Teruaki Hayakawa, Yoshihito Ishida, and Masa-aki KakimotoView Author Information Department of Organ…

Dendrimers and Hyperbranched PolymersSynthesis and properties of polymersSilicone and Siloxane Chemistry

Heterogeneous Adsorption Characteristics of Volatile Organic Compounds (VOCs) on MCM‐48

Wang‐Geun Shim、J. W. Lee、Hee Moon2006-12-01Separation Science and Technology

This work focuses on the fundamental studies of heterogeneous adsorption characteristics of mesoporous adsorbent. MCM‐48 was synthesized to investigate the adsorption properties of eight different volatile organic compounds (benzene, cyclohexane, n‐hexane, toluene, methanol, acetone, methyl ethyl ketone (MEK), and tri…

Adsorption and biosorption for pollutant removalZeolite Catalysis and SynthesisMesoporous Materials and Catalysis

Long persistent light emitting diode

Dongdong Jia、D. N. Hunter2006-12-01Journal of Applied Physics

Light emitting diodes (LEDs) coated with Sr2MgSi2O7:Eu2+,Nd3+ (blue), SrAl2O4:Eu2+,Dy3+ (green), SrS:Eu2+,Y3+,Ce3+ (orange), and CaS:Eu2+,Tm3+,Ce3+ (red) long persistent phosphors were prepared. LEDs which have a 450nm blue emission were used as an excitation source for the coated phosphors. Blue (475nm), green (520nm…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsRadiation Detection and Scintillator Technologies

Characterization of an Epoxy Resin Modified with Natural Oil‐Based Reactive Diluents

Piotr Czub2006-12-01Macromolecular Symposia

Abstract Modified natural oils ‐ epoxidized soybean and rapeseed oils were tested as reactive diluents for viscosity regulation of Bisphenol A‐based low‐molecular‐ weight epoxy resin. Satisfactory viscosity reducing ability of epoxidized oils as well as non‐Newtonian rheological behaviour of the resin diluted with mod…

Polymer composites and self-healingEpoxy Resin Curing ProcessesSynthesis and properties of polymers

Structure and photoluminescence properties of evaporated GeOx∕SiO2 multilayers

M. Ardyanian、H. Rinnert、M. Vergnat2006-12-01Journal of Applied Physics

Amorphous GeOx∕SiO2 multilayers were prepared by successive evaporations of GeO2 and SiO2 powders onto substrates maintained at 100°C. The evolution of the structure was investigated by x-ray reflectometry, transmission electron microscopy, infrared-absorption spectrometry and Raman spectrometry for annealing temperat…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Novel Thermoplastic Composites from Commodity Polymers and Man‐Made Cellulose Fibers

Hans‐Peter Fink、Johannes Ganster2006-12-01Macromolecular Symposia

Abstract Summary: A new class of fibre reinforced commodity thermoplastics suited for injection moulding and direct processing applications has been developed using man‐made cellulosic fibres (Rayon tire yarn, Tencel, Viscose, Carbacell) and thermoplastic commodity polymers, such as polypropylene (PP), polyethylene (P…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing Technologies

Characterization of Electrochromic Vanadium Pentoxide Thin Films Prepared By Spray Pyrolysis

作者信息未提供2006-12-01Egyptian journal of solids

Amorphous and crystalline vanadium pentoxide (V2O5) thin films weregrown onto heated glass substrates using spray pyrolysis technique. Aqueoussolution of ammonium meta-vanadat with different concentrations rangingfrom 0.1 to 0.5M was used. X-ray diffraction study of c-V2O5 revealedpolycrystalline films of orthorhombic…

Transition Metal Oxide Nanomaterials

Immobilization of GOD on Electrochemically Synthesized PANI Film by Cross-linking via Glutaraldehyde for Determination of Glucose

P.D. Gaikwad、Dhammanand J. Shirale、V.K. Gade 等 7 位作者2006-12-01International Journal of Electrochemical Science

The Polyaniline-sulfuric acid-glucose oxidase (PANI-H2SO4-GOD) electrode has been investigated in the present work. Platinum electrode was used for the synthesis of Polyaniline-sulfuric acid (PANIH2SO4) film using Potentiometric method with 0.2 M aniline, 1.0 M H2SO4 solution, 1.0 pH and 1 mA/cm2 applied current densi…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Development of Laboratory Procedure for Measuring Friction of HMA Mixtures - Phase I

Timothy W. Vollor、Douglas I Hanson2006-12-01OpenAlex

Pavement friction during wet conditions continues to be a major safety concern for pavement design and maintenance. The skid resistance of pavements is commonly measured using ASTM E 274, Skid Resistance of Paved Surfaces Using a Full-Scale Tire. However, there are no standard test procedures for evaluating the fricti…

Risk and Safety AnalysisEngineering and Material Science ResearchTransportation Safety and Impact Analysis

Phase diagram of the LaFeO3-LaSrFeO4 system

Е. А. Тугова、В. Ф. Попова、И. А. Зверева 等 4 位作者2006-12-01Glass Physics and Chemistry

The phase relationships in the LaFeO 3 -LaSrFeO 4 system at temperatures in the range 1000–2100°C in air are investigated, and the phase diagram of the system is constructed. One perovskite-like compound, namely, La 2 SrFe 2 O 7 , which belongs to the Ruddlesden-Popper phases, is revealed in the system.

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Electrochemical Modification of Graphite Electrodes with Poly(4‐aminophenol)

Sabrina Nunes Vieira、Lucas Franco Ferreira、Diego Leoni Franco 等 7 位作者2006-12-01Macromolecular Symposia

Abstract It was observed the formation of polymeric films derived from 4‐aminophenol on the graphite electrode in aqueous medium (pH 0.5, 8.0 and 12.0). The electrochemical behavior of formed films was studied by voltammetry cyclic and impedance. These analyses indicate that the preparation in acid medium favors the c…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Nonlinear piezoelectric resonance: A theoretically rigorous approach to constant I−V measurements

J. F. Blackburn、Markys G. Cain2006-12-01Journal of Applied Physics

Methods for piezoelectric characterization include the standard resonance test. At higher powers, however, the material’s inherent nonlinearity acts to significantly affect the expected resonance response. High-power resonance methods have previously been developed to describe piezoelectric nonlinearity. In this artic…

Ferroelectric and Piezoelectric MaterialsUltrasonics and Acoustic Wave PropagationAcoustic Wave Resonator Technologies