Materials Literature
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In this study, a spin- and gradient-echo echo-planar imaging (SAGE EPI) MRI pulse sequence is presented that allows simultaneous measurements of gradient-echo and spin-echo dynamic susceptibility-contrast perfusion-weighted imaging data. Following signal excitation, five readout trains were acquired using spin- and gr…
The effects of the dye-adsorption solvent on the performances of the dye-sensitized solar cells (DSSCs) based on black dye have been investigated. The highest conversion efficiency (10.6 %) was obtained in the cases for which 1-PrOH and the mixed solvent of EtOH and tBuOH (3:1 v/v) were employed as dye-adsorption solv…
Four new compounds, [Cd(5-aip)(bpy)]·1.5DMA (1), [Cu(5-aip)(bpy)]·1.3DMA (2), [Co(5-aip)(bpy)]·1.6DMA (3), and [Cd(5-aip)(bpy)(0.5)(H(2)O)]·1.3DMA (4), based on 5-aminoisophthalic acid and 4,4'-bipyridine, have been synthesized by the solvothermal method and structurally determined using single crystal X-ray diffracti…
Disk-shaped metal nanoparticles on high-index substrates can support resonant surface plasmon polariton (SPP) modes at the interface between the particle and the substrate. We demonstrate that this new conceptual model of nanoparticle scattering allows clear predictive abilities, beyond the dipole model. As would be e…
Abstract Transmembranrezeptoren ermöglichen die Kommunikation zwischen Zellen und ihrer Umgebung. Die Stimuli, die diese Rezeptoren aktivieren, treten in Form von Änderungen der Ligandenkonzentration (z. B. Hormone oder Neurotransmitter), der Temperatur, des Drucks (z. B. Schallwellen oder Berührungen), des Transmembr…
Two K([2.2.2]crypt) salts of lanthanide-doped semimetal clusters were prepared, both of which contain at the same time two types of ternary intermetalloid anions, [Ln@Sn(7)Bi(7)](4-) and [Ln@Sn(4)Bi(9)](4-), in 0.70:0.30 (Ln = La) or 0.39:0.61 (Ln = Ce) ratios. The cluster shells represent nondeltahedral, fullerane-ty…
Metal-organic framework nanotubes (MOFNTs) are achieved by a strategy in which MOF nanorods formed initially act as a self-sacrificing template for the formation of the final MOFNTs. The fluorescent MOFNTs obtained exhibit high sensitivity, significant selectivity, and a fast response rate for the reversible vapor-pha…
We measure the mechanical resonances of an as-grown suspended carbon nanotube, detected via electrical mixing in the device. A sequence of modes extending to 39 GHz is observed with a quality factor of 35,000 in the highest mode. This unprecedentedly high combination corresponds to a thermal excited state probability…
Membrane proteins in their native cellular membranes are accessible by dynamic nuclear polarization magic angle spinning solid-state NMR spectroscopy without the need of purification and reconstitution (see picture). Dynamic nuclear polarization is essential to achieve the required gain in sensitivity to observe the m…
4-bromoanisole is used as a very versatile processing additive to control the phase separation and phase purity of organic photovoltaic devices. Polymer-polymer blends based on P3HT as donor and a wide range of acceptor materials (F8TBT, PCDTBT,…︁) are investigated. The additive promotes the aggregation of P3HT which…
Copper/silica nanocomposite catalysts prove efficient for the direct hydrocyclization of biomass-derived levulinic acid to cyclic 2-methyltetrahydrofuran in the vapor phase, at moderate hydrogen pressures. A nickel-promoted copper/silica catalyst with a high copper loading (72 wt %) is particularly effective for the d…
The weighted histogram analysis method (WHAM) has become the standard technique for the analysis of umbrella sampling simulations. In this article, we address the challenges (1) of obtaining fast and accurate solutions of the coupled nonlinear WHAM equations, (2) of quantifying the statistical errors of the resulting…
A family of π-extended platinum(II) porphyrins has been synthesized and incorporated into solution processed polymer light emitting diodes (PLEDs) and vapor deposited multilayer organic light emitting diodes (OLEDs), giving rise to devices with peak emission ranging from 771 to 1005 nm. The longest wavelength emitter,…
Due to their favourable combination of high ionic conductivity and stability versus elemental lithium, garnet-related lithium ion conductors Li7La3Zr2O12 have raised strong interest for both all-solid-state batteries and as protective layers for anode materials. Here we study the correlation between structure and ion…
The photophysics and morphology of thin films of N,N-bis(2,6-diisopropylphenyl)perylene-3,4:9,10-bis(dicarboximide) (1) and the 1,7-diphenyl (2) and 1,7-bis(3,5-di-tert-butylphenyl) (3) derivatives blended with 6,13-bis(triisopropylsilylethynyl)pentacene (TIPS-Pn) were studied for their potential use as photoactive la…
Tubular nanocomposites of silver nanoparticles (AgNPs)/silica nanotubes (SNTs) with the nearly uniform diameters of 250–350 nm were successfully fabricated by combining the single capillary electrospinning technique (for SNTs as the supports) and an in situreduction approach (for AgNPs). The highly dispersed AgNPs ass…
Organic photovoltaic cells based on small molecules show high performance in bulk heterojunction solar cells. Using the simple solution spinning process, DERHD7T/PC61 BM-based solar cell exhibits a power conversion efficiency of up to 6.10%.
Rapid improvements in organic solar cell efficiency have brought these devices into the spotlight as a potential source of abundant electricity. Despite much empirical progress, fundamental understanding is still lacking. Due to the required three-dimentional nanoscale morphology, determining structure–performance rel…
Transmembrane receptors allow a cell to communicate with its environment in response to a variety of input signals. These can be changes in the concentration of ligands (e.g. hormones or neurotransmitters), temperature, pressure (e.g. acoustic waves or touch), transmembrane potential, or light intensity. Many importan…
A novel porous nanoarchitecture composed of 2D graphene–SnS2 (G–SnS2) units is developed via a two-step approach in this work. The special structure endows the high-rate transportation of electrolyte ions and electrons throughout the electrode matrix, resulting in remarkable electrochemical performance when it was use…