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The Structure of the Thioredoxin–Triosephosphate Isomerase Complex Provides Insights into the Reversible Glutathione-Mediated Regulation of Triosephosphate Isomerase

Shahul Hameed M. S.、Siddhartha P. Sarma2011-11-29Biochemistry

Protein-protein interactions are crucial for many biological functions. The redox interactome encompasses numerous weak transient interactions in which thioredoxin plays a central role. Proteomic studies have shown that thioredoxin binds to numerous proteins belonging to various cellular processes, including energy me…

Endoplasmic Reticulum Stress and DiseaseEnzyme Structure and FunctionRedox biology and oxidative stress

Characterization of the Materials Synthesized by High Pressure-High Temperature Treatment of a Polymer Derived t-BC2N Ceramic

Wallace Matizamhuka、Iakovos Sigalas、Mathias Herrmann 等 8 位作者2011-11-29Materials

Bulk B-C-N materials were synthesized under static high thermobaric conditions (20 GPa and 2,000 °C) in a multianvil apparatus from a polymer derived t-BC1.97N ceramic. The bulk samples were characterised using X-ray synchrotron radiation and analytical transmission electron microscopy in combination with electron ene…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Lattice dynamics and anomalous softening in the YbFe 4 Sb 12 skutterudite

A. Möchel、I. Sergueev、Hans‐Christian Wille 等 11 位作者2011-11-29Physical Review B

The lattice dynamics of the filled skutterudite YbFe${}_{4}$Sb${}_{12}$ was studied by resonant ultrasound spectroscopy and an anomalous softening in the temperature dependence of the elastic constants at $\ensuremath{\sim}$50 K was observed. This anomaly can not be explained by the dynamics of the filler, in contrast…

High-pressure geophysics and materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Dielectric relaxation and rheological properties of single-walled carbon nanotubes reinforced poly(3-octylthiophene-2,5-diyl)

M. Abu‐Abdeen、Ayman S Ayesh、Abdullah Aljaafari2011-11-29Journal of Thermoplastic Composite Materials

Polymer nanocomposites consisting of single-walled carbon nanotubes (SWCNTs) and poly(3-octylthiophene-2,5-diyl) (P3OT) were prepared at different SWCNT loadings to investigate the influence of SWCNT content on the structure, dielectric and rheological properties of P3OT host. The dielectric parameters and dielectric…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsDielectric materials and actuators

Spiral magnetic structure in spin- 52 frustrated trimerized chains in SrMn 3 P 4 O 14

Masashi Hase、Vladimir Pomjakushin、L. Keller 等 10 位作者2011-11-29Physical Review B

We study a spin-5/2 antiferromagnetic trimerized chain substance SrMn${}_{3}$P${}_{4}$O${}_{14}$ using neutron powder diffraction experiments. The coplanar spiral magnetic structure appears below ${T}_{\mathrm{N}1}=2.2(1)$ K. Values of several magnetic structure parameters change rapidly at ${T}_{\mathrm{N}2}=1.75(5)$…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Permanent fixation of β‐cyclodextrin on cotton surface—An assessment between innovative and established approaches

Piyush Agrawal、M.M.C.G. Warmoeskerken2011-11-29Journal of Applied Polymer Science

Abstract Attachment of β‐cyclodextrin (β‐CD) molecules on cotton textile provides hosting cavities that can include a large variety of guest molecules for specific functionality. Five different new and existing techniques were evaluated for connecting β‐CD and its derivatives to cotton surface. A comparison has been m…

Skin Protection and AgingDyeing and Modifying Textile FibersPhotochromic and Fluorescence Chemistry

Improvement of Collagen Hydrogel Scaffolds Properties by the Addition of Konjac Glucomannan

Raquel Farias Weska、Matteo Achilli、Marisa Masumi Beppu 等 4 位作者2011-11-29Advanced materials research

Collagen gels have been investigated for a number of applications in tissue engineering because of their excellent biological properties. However, their limited mechanical behavior represents a major bottleneck for clinical use, especially for vascular tissue engineering. The targeting of their mechanical properties m…

Electrospun Nanofibers in Biomedical ApplicationsCollagen: Extraction and CharacterizationPolysaccharides Composition and Applications

Solubility and diffusivity of cyclohexane in high density polyethylene

Justin L. Rausch、Taylor C. Schulz、Ronald P. Danner2011-11-29Journal of Applied Polymer Science

Abstract The diffusivity and solubility of cyclohexane in a high density polyethylene, HDPE, were studied using a gravimetric, quartz‐spring, sorption balance. Solvent concentrations up to a weight fraction of 0.15 over a temperature range of 90 to 160°C were measured. Diffusion coefficients in the range of 10−6 to 10…

Phase Equilibria and ThermodynamicsPolymer Foaming and CompositesAdsorption, diffusion, and thermodynamic properties of materials

Mixed state of a π -striped superconductor

Mirsaeed Zelli、Catherine Kallin、A. J. Berlinsky2011-11-29Physical Review B

A model of an antiphase modulated $d$-wave superconductor has been proposed to describe the decoupling between Cu-O planes in $1/8$ doped La${}_{2\ensuremath{-}x}$Ba${}_{x}$CuO${}_{4}$. Unlike a uniform $d$-wave superconductor, this model exhibits an extended Fermi surface. Within Bogoliubov--de Gennes theory, we stud…

Physics of Superconductivity and MagnetismOrganic and Molecular Conductors ResearchIron-based superconductors research

Climate dependent diatom production is preserved in biogenic Si isotope signatures

Xiaole Sun、Per Andersson、Christoph Humborg 等 7 位作者2011-11-29Biogeosciences

Abstract. The aim of this study was to reconstruct diatom production in the subarctic northern tip of the Baltic Sea, Bothnian Bay, based on down-core analysis of Si isotopes in biogenic silica (BSi). Dating of the sediment showed that the samples covered the period 1820 to 2000. The sediment core record can be divide…

Geology and Paleoclimatology ResearchMarine and coastal ecosystemsDiatoms and Algae Research

Durable polytetrafluoroethylene composites in harsh environments: Tribology and corrosion investigation

Liwen Mu、Jian Chen、Yijun Shi 等 7 位作者2011-11-29Journal of Applied Polymer Science

Abstract The tribological properties and mass loss of polytetrafluoroethylene (PTFE) composites filled with carbon fiber (CF) or potassium titanate whisker (PTW) after the immersion in 30% sulfuric acid solution for 5 or 15 days were studied under different temperatures (25, 50, and 75°C). Results show that PTW/PTFE c…

Polymer Nanocomposites and PropertiesTribology and Wear AnalysisPolymer Nanocomposite Synthesis and Irradiation

Supramolecular Structures of Inclusion Complexes of C70 and Cyclic Porphyrin Dimers

Hirofumi Nobukuni、Takuya Kamimura、Hidemitsu Uno 等 6 位作者2011-11-29Bulletin of the Chemical Society of Japan

Abstract Cyclic nickel and free-base porphyrin dimers (Ni2-CPDPy and H4-CPDPy) include fullerene C70 both in solution and in the crystals. Based on the 13C NMR spectra in solution, the included C70 molecule inside the cavity of Ni2-CPDPy shows both end-on and side-on orientations, whereas the C70 molecule within H4-CP…

Carbon Nanotubes in CompositesPorphyrin and Phthalocyanine ChemistryFullerene Chemistry and Applications

Mechanism‐Oriented Redesign of an Isomaltulose Synthase to an Isomelezitose Synthase by Site‐Directed Mutagenesis

Julian Görl、Malte Timm、Jürgen Seibel2011-11-29ChemBioChem

An isomelezitose synthase was redesigned out of the sucrose isomerase from Protaminobacter rubrum for the synthesis of isomelezitose (6-O(F)-glucosylsucrose), a potential nutraceutical. The variants F297A, F297P, R333K, F321A_F319A and E428D catalyze the formation of isomelezitose in up to 70 % yield.

Enzyme Structure and FunctionEnzyme Production and CharacterizationPolyamine Metabolism and Applications

Long-range steady-state density profiles induced by localized drive

Tridib Sadhu、Satya N. Majumdar、David Mukamel2011-11-29Physical Review E

We show that the presence of a localized drive in an otherwise diffusive system results in steady-state density and current profiles that decay algebraically to their global average value, away from the drive in two or higher dimensions. An analogy to an electrostatic problem is established, whereby the density profil…

Material Dynamics and PropertiesTheoretical and Computational PhysicsAdvanced Thermodynamics and Statistical Mechanics

Spirostanol Saponins Derivated from the Seeds ofTrigonella foenum-graecumbyβ-Glucosidase Hydrolysis and Their Inhibitory Effects on Rat Platelet Aggregation

Xu Pang、Yue Cong、Heshui Yu 等 13 位作者2011-11-29Planta Medica

Nine spirostanol saponins (1-9) and seven mixtures of 25 R and 25 S spirostanol saponin isomers (10-16) were obtained from the seeds of Trigonella foenum-graecum after enzymatic hydrolysis of the furostanol saponin fraction by β-glucosidase. Their structures were determined by NMR and MS spectroscopy. Among them, 1- 4…

Natural product bioactivities and synthesisPhytochemical Studies and BioactivitiesPhytochemistry and Bioactive Compounds

Optical technique for the in situ study of orientation and structure changes accompanied the plastic deformation of polycrystalline specimens of aluminum

E.E. Badiyan、A.G. Tonkopryad、О. В. Шеховцов 等 5 位作者2011-11-29Inorganic Materials

An optical technique for in situ color orientation mapping of the surface of a ductile Al polycrystal is suggested. It is based on the effect of anisotropic scattering of white light by quasiperiodic etching relief depending on the crystallographic grain orientation. The technique includes recording of digital color o…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesMetallurgy and Material Forming

Morphological, infrared, and ionic conductivity studies of poly(ethylene oxide)–49% poly(methyl methacrylate) grafted natural rubber–lithium perchlorate salt based solid polymer electrolytes

Azizan Ahmad、M. Y. A. Rahman、Mohd Sukor Su’ait2011-11-29Journal of Applied Polymer Science

Abstract The potential of poly(ethylene oxide) (PEO) and 49% poly(methyl methacrylate) grafted natural rubber (MG49) as a polymer host in solid polymer electrolytes (SPE) was explored for electrochemical applications. PEO–MG49 SPEs with various weight percentages of lithium perchlorate salt (LiClO4) was prepared with…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesConducting polymers and applications

Self‐catalyzed, vertically aligned GaN rod‐structures by metal‐organic vapor phase epitaxy

Christian Tessarek、Silke Christiansen2011-11-29Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics

Abstract This paper will discuss the influence of parameters such as temperature, V/III ratio, atmosphere and pressure on the vertical growth of GaN rod‐structures on sapphire by metal‐organic vapor phase epitaxy. For all growth experiments a simple two step method is applied consisting of a nitridation step on the sa…

GaN-based semiconductor devices and materialsSemiconductor materials and devicesGa2O3 and related materials

Determination of Carrier Lifetime in Bulk-Heterojunction Solar Cells by Continuous-Wave Photoinduced Absorption Spectroscopy

Takashi Kobayashi、Yosuke Terada、Takashi Nagase 等 4 位作者2011-11-29Applied Physics Express

Continuous-wave photoinduced absorption spectroscopy is applied to a bulk-heterojunction solar cell based on a blend of polymer and fullerene for the determination of carrier lifetime. This technique has several advantages with respect to conventional methods: (1) mobile and trapped carriers can be clearly distinguish…

Organic Electronics and PhotovoltaicsSilicon and Solar Cell TechnologiesConducting polymers and applications

Indium incorporation in InGaN/GaN quantum wells grown on m ‐plane GaN substrate and c ‐plane sapphire

Kun‐Yu Lai、T. Paskova、Virginia D. Wheeler 等 9 位作者2011-11-29physica status solidi (a)

Abstract InGaN/GaN quantum wells (QWs) grown at identical conditions on m ‐plane GaN and c ‐plane sapphire substrates were characterized by several techniques, aiming to clarify the reason for different emission wavelengths often observed in similar LED structures with m ‐ and c ‐plane surface orientations. Cathodolum…

Semiconductor Quantum Structures and DevicesZnO doping and propertiesGaN-based semiconductor devices and materials