Materials Literature
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Fours for thought: The title compound was prepared by condensation of the preformed unit {Mo2O2S2}2+ as a linker on to the trivacant anion [α-P2W15O5]12−. The self-assembled structure exhibits a modular arrangement (see structure). 31P and 183W NMR spectroscopy revealed that the structure of the supramolecular tetra-u…
This is the first comprehensive study on the kinetic modeling of adiabatic decomposition of di- tert -butyl peroxide (DTBP) and its solvent mixtures. The adiabatic thermal decomposition of DTBP and its solvent mixtures was examined using an accelerating rate calorimeter under varying thermal inertia. The decomposition…
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An ordered hexagonal mesoporous nickel oxide was prepared for the first time using sodium dodecyl sulfate as the surfactant and urea as the hydrolyzing agent. The resulting oxide showed mesoporous structure with pore size ranging from 4 to 7 nm. Calcination at different temperatures was carried out, and the mesoporosi…
[reaction: see text] Regioselectivity of the oxidative coupling of 5,10,15-triarylporphyrin metal complexes with DDQ-Sc(OTf)(3) was dependent on the central metal and meso-aryl substituent. Oxo-quinoidal porphyrin was obtained from Ni(II) porphyrin under the same conditions.
Crystal conversion of beta-chitin to alpha-chitin by aq. NaOH treatment was studied for a highly crystalline beta-chitin sample from diatom spine. The minimum NaOH concentration to cause swelling was between 25% and 30% w/w. The alkali-swollen material was poorly crystalline and was regenerated as alpha-chitin on wash…
This paper describes the preparation of colloidal dispersions of water-insoluble organic materials by a “solvent-shifting” procedure, in which a concentrated solution of an organic solute in a water-miscible organic solvent is dispersed into a large volume of aqueous (nonsolvent) bulk solution containing colloidal sta…
Filling the gaps: A low-temperature solution route was employed to successfully prepare multiwalled TiS2 nanotubes with open-ended tips (see HRTEM image). The as-prepared nanotubes could be intercalated with lithium atoms by treating a solution of the TiS2 nanotubes with nBuLi. The resulting homogeneous intercalated p…
The preparation of poly( N -isopropylacrylamide)-monolayer-protected clusters (PNIPAM-MPC) of gold nanoparticles was carried out in a homogeneous phase using three methods, in which three types of PNIPAM ligands were employed. The first type was comprised of PNIPAMs with narrow molar mass distributions, synthesized by…
Single walled carbon nanotubes (SWNTs) have been coated with silica by the addition of a silica/H 2 SiF 6 solution to a surfactant-stabilized solution of SWNTs. The thickness of the coating is controlled by reaction time, while the coating of individual SWNTs versus small ropes is controlled by the choice of surfactan…
I analyze the Nonlocal Conserved Kardar-Parisi-Zhang (NCKPZ) equation with spatially correlated noise. This equation is also known as the Nonlocal Molecular Beam Epitaxy (NMBE) equation andv was originally suggested to study the effect of the long-range nature of interactions coupled with spatially correlated noise on…
We study the effect of spatial dispersion of crystal modes on optical properties such as the reflectivity $R$. As an example for isotropic media, we investigate the simplest model for phonons in ionic crystals and compare with previous results for highly anisotropic plasmons, which are now understood from a more gener…
We have used a tight-binding model that is fit to first-principles electronic-structure calculations for titanium to calculate quasi-harmonic phonons and the Gibbs free energy of the hexagonal close-packed (hcp) and omega crystal structures. We show that the true zero-temperature ground-state is the omega structure, a…
The complex band structure of an isolated polyethylene chain is calculated within Density Functional Theory (DFT). A plane wave basis and ultrasoft pseudopotentials are used. The results are compared with those obtained via a local basis set. We obtain a gap between the highest occupied molecular orbilar (HOMO) and th…
We report on the first Raman data of Cu substituted La(1-y)Sr(y)Mn(1-x)Cu(x)O3 (0 < x < 0.10 and 0.17 < y < 0.3, accordingly in order to have the same Mn(4+)/[Mn(4+)+Mn(3+)] ratio), collected in the frequency range 100-900 cm-1 and at room temperature, with parallel and crossed polarizations of the incident and scatte…
The T-dependence of magnetic moments in SrB_6 is studied through spin-polarized band calculations for a supercell of Sr_{27}B_{156} containing a B_6 vacancy. The magnetic moment decays rather quickly with T despite the fact that only electronic Fermi-Dirac effects are included. This result and the T-dependence of mome…
No metal jacket required: The surface structures of mesoporous materials were accurately determined by using electron-microscopy techniques—without the need for metal plating. The effectiveness of these techniques was demonstrated with SBA-15 mesoporous silica (see image) and its CMK-5 carbon replica, for which high-r…
Very different electronic properties are found in the hexagonal and lamellar nanocomposite films (see schematic representations) prepared by dilution of a pyrrole-containing surfactant with nonpolymerizable surfactants in a sol–gel-based template polymerization. The hexagonal composite film comprises a thin polypyrrol…
In an effort to make semiconductor nanomaterials with tunable properties, we have deliberately designed and synthesized a family of novel organic-inorganic hybrid nanocomposites based on II-VI semiconductors with structures ranging from one-dimensional (1-D) chain to two-dimensional layer (2-D) to three-dimensional (3…
A recent paper [J. B. Pendry, Phys. Rev. Lett. 85, 3966 (2000)] showed how to construct a superlens that focuses the near-field radiation and, hence, produce an image resolution unlimited by wavelength. The prescription requires lossless materials with a negative refractive index: finite loss cuts off the finer detail…