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Photoluminescence property of ZnO–SiO2composites synthesized by sol–gel method

Haiping He、Yu‐Xia Wang、Youming Zou2003-11-20Journal of Physics D Applied Physics

The room temperature photoluminescence property of ZnO particles embedded in sol–gel silica was investigated. Three ZnO emissions at about 3.25 eV (ultraviolet (UV)), 2.8 eV (blue), and 2.45 eV (green) were observed. The blue and green emissions were ascribed to interstitial zinc and oxygen vacancy defects in ZnO. At…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

High-pressure micro-discharges in etching and deposition applications

R. Mohan Sankaran、Konstantinos P. Giapis2003-11-20Journal of Physics D Applied Physics

High-pressure micro-discharges are promising sources of light, ions, and radicals and offer some advantages in materials processing applications as compared to other more conventional discharges. We review here results from etching experiments using stencil masks where the discharge is formed only in the pattern cutou…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Comparison of Physicochemical, Binding, and Antibacterial Properties of Chitosans Prepared without and with Deproteinization Process

Hong Kyoon No、Shin Ho Lee、Na Young Park 等 4 位作者2003-11-20Journal of Agricultural and Food Chemistry

Physicochemical, binding, and antibacterial properties of chitosans prepared without and with deproteinization (DP) process (5, 10, 15, and 30 min at 15 psi/121 degrees C) were compared. Chitosan from DP 0 min had comparable nitrogen content, lower degree of deacetylation and solubility, but higher molecular weight an…

Nanocomposite Films for Food PackagingPineapple and bromelain studiesAgricultural and Environmental Management

Infrared Study of the Stability and Folding Kinetics of a 15-Residue β-Hairpin

Yao Xu、Rolando Oyola、Feng Gai2003-11-20Journal of the American Chemical Society

The thermal stability and folding kinetics of a 15-residue beta-hairpin (SESYINPDGTWTVTE) have been studied by using infrared (IR) spectroscopy coupled with laser-induced temperature-jump (T-jump) technique for rapid folding-unfolding initiation. An alternative method based on analyzing IR difference spectra was also…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Preparation and characterization of PET/silica nanocomposites

Wentao Liu、Xingyou Tian、Ping Cui 等 6 位作者2003-11-20Journal of Applied Polymer Science

Abstract Poly(ethylene terephthalate) (PET)/silica nanocomposites were fabricated by direct polymerizing PET monomer dispersed with organic modified silica nanoparticles. The characteristics and properties of these nanocomposites were investigated by the transmission electron microscopy, differential scanning calorime…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Ferroquadrupole ordering andΓ5rattling motion in the clathrate compoundCe3Pd20Ge6

Yuichi Nemoto、Takashi Yamaguchi、Takenobu Horino 等 9 位作者2003-11-20Physical review. B, Condensed matter

Lattice effects in a cerium based clathrate compound ${\mathrm{Ce}}_{3}{\mathrm{Pd}}_{20}{\mathrm{Ge}}_{6}$ with a cubic ${\mathrm{Cr}}_{23}{\mathrm{C}}_{6}$-type structure have been investigated by ultrasonic and thermal expansion measurements. Elastic softenings of ${(C}_{11}\ensuremath{-}{C}_{12})/2$ and ${C}_{44}$…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Structure and Photophysical Properties of Porphyrin-Modified Metal Nanoclusters with Different Chain Lengths

Hiroshi Imahori、Yukiyasu Kashiwagi、Yoshiyuki Endo 等 9 位作者2003-11-20Langmuir

Three-dimensional porphyrin-monolayer-protected gold clusters with different chain lengths (MPCs) have been prepared to examine the structure and photophysical properties, in comparison with self-assembled monolayers (SAMs) of the porphyrins on a flat gold surface. The three-dimensional porphyrin MPCs exhibit electroc…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Microplasma devices fabricated in silicon, ceramic, and metal/polymer structures: arrays, emitters and photodetectors

J. G. Eden、S-J Park、N.P. Ostrom 等 14 位作者2003-11-20Journal of Physics D Applied Physics

Microplasma devices fabricated in silicon, ceramic, and metal/polymer structures: arrays, emitters and photodetectors, J G Eden, S-J Park, N P Ostrom, S T McCain, C J Wagner, B A Vojak, J Chen, C Liu, P von Allmen, F Zenhausern, D J Sadler, C Jensen, D L Wilcox, J J Ewing

Luminescence Properties of Advanced MaterialsPlasma Applications and DiagnosticsSilicon Nanostructures and Photoluminescence

Synthesis, Characterization, and Properties of Polyelectrolyte Block Copolymer Brushes Prepared by Atom Transfer Radical Polymerization and Their Use in the Synthesis of Metal Nanoparticles

Stephen G. Boyes、Bülent Akgün、William J. Brittain 等 4 位作者2003-11-20Macromolecules

Diblock copolymer polyelectrolyte brushes of either polystyrene (PS) or poly(methyl acrylate) (PMA) and poly(acrylic acid) (PAA) were synthesized using sequential monomer addition from a tethered 2-bromoisobutyrate initiator. Si/SiO 2 //PS- b -poly( tert -butyl acrylate) (P( t -BA)) and Si/SiO 2 //PMA- b -P(t-BA) were…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Living artificial heart valve alternatives: a review

Thomas C. Flanagan、Abhay Pandit2003-11-20European Cells and Materials

Conventional replacement therapies for heart valve disease are associated with significant drawbacks. The field of tissue engineering has emerged as an exciting alternative in the search for improved heart valve replacement structures. One of the principles behind this concept is the transplantation of living elements…

Cardiac Valve Diseases and TreatmentsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Effect of organo‐phosphorus and nano‐clay materials on the thermal and fire performance of epoxy resins

Manwar Hussain、Russell J. Varley、Z. Mathys 等 5 位作者2003-11-20Journal of Applied Polymer Science

Abstract The results of flame retardance and thermal stability of a reactively modified organo‐phosphorus diglycidylether of bisphenol‐A and an organo‐phosphorus tetraglycidyl diaminodiphenylmethane are reported here. The organo‐phosphorus epoxy resins were synthesized by the reaction of 9,10‐dihydro‐9‐oxa‐10‐phosphap…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesSynthesis and properties of polymers

Coalescence of Particle-Laden Fluid Interfaces

Edward J. Stancik、Mehrnaz Kouhkan、Gerald G. Fuller2003-11-20Langmuir

Colloidal particles are capable of stabilizing emulsions and, thus, slowing or preventing their complete breakdown into phase-separated systems. Direct observations of the dynamics of such particles on both water and oil droplets are reported as two colloid-laden interfaces are brought into contact with each other. As…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Spin- and charge-polarized states in nanographene ribbons with zigzag edges

Atsushi Yamashiro、Yukihiro Shimoi、Kikuo Harigaya 等 4 位作者2003-11-20Physical review. B, Condensed matter

Effects of the nearest-neighbor Coulomb interaction on nanographene ribbons with zigzag edges are investigated using the extended Hubbard model within the unrestricted Hartree-Fock approximation. The nearest Coulomb interaction stabilizes an electronic state with the opposite electric charges separated and localized a…

Graphene research and applications2D Materials and ApplicationsTopological Materials and Phenomena

A new colloidal model system to study long-range interactions quantitatively in real space

C. Patrick Royall、Mirjam E. Leunissen、Alfons van Blaaderen2003-11-20Journal of Physics Condensed Matter

We present quantitative three-dimensional real space measurements by confocal microscopy on fluorescently labelled and sterically stabilized dispersions of polymethylmethacrylate spheres dispersed in index and density-matched solvent mixtures with a relative dielectric constant 5<ε r <10 . In this new model system Deb…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsElectrostatics and Colloid Interactions

Implicit Purification for Temperature-Dependent Density Matrices

Anders M. N. Niklasson2003-11-20arXiv

An implicit purification scheme is proposed for calculation of the temperature-dependent, grand canonical single-particle density matrix, given as a Fermi operator expansion in terms of the Hamiltonian. The computational complexity is shown to scale with the logarithm of the polynomial order of the expansion, or equiv…

Materials Science

Suppression of the Magnetic Phase Transition in Manganites Close to the Metal-Insulator Crossover

F. Rivadulla、J. Rivas、J. B. Goodenough2003-11-20arXiv

We report the suppression of the magnetic phase transition in La1-xCaxMnO3 close to the localized-to-itinerant electronic transition, i.e. at x = 0.2 and x = 0.5. A new crossover temperature Tf can be defined for these compositions instead of TC. Unlike in common continuous magnetic phase transition the susceptibility…

Materials ScienceStrongly Correlated Electrons

Andrade, Omori and Time-to-failure Laws from Thermal Noise in Material Rupture

A. Saichev、D. Sornette2003-11-20arXiv

Using the simplest possible ingredients of a rupture model with thermal fluctuations, we provide an analytical theory of three ubiquitous empirical observations obtained in creep (constant applied stress) experiments: the initial Andrade-like and Omori-like $1/t$ decay of the rate of deformation and of fiber ruptures…

Materials Science

Current-induced transverse spin wave instability in a thin nanomagnet

M. L. Polianski、P. W. Brouwer2003-11-20arXiv

We show that an unpolarized electric current incident perpendicular to the plane of a thin ferromagnet can excite a spin-wave instability transverse to the current direction if source and drain contacts are not symmetric. The instability, which is driven by the current-induced ``spin-transfer torque'', exists for one…

Mesoscale and Nanoscale PhysicsMaterials Science

Magnetization of ultrathin (Ga,Mn)As layers

R. Mathieu、B. S. Sørensen、J. Sadowski 等 9 位作者2003-11-20Physical review. B, Condensed matter

Kerr rotation and superconducting quantum interference device magnetometry measurements were performed on ultrathin $({\mathrm{Ga}}_{0.95}{\mathrm{Mn}}_{0.05})\mathrm{As}$ layers. The thinner layers (below 250 \AA{}) exhibit magnetic properties different than those of thicker ones, associated with different microstruc…

Physics of Superconductivity and MagnetismZnO doping and propertiesMagnetic and transport properties of perovskites and related materials

A Paramagnetic CEST Agent for Imaging Glucose by MRI

Shanrong Zhang、R. Trokowski、A. Dean Sherry2003-11-20Journal of the American Chemical Society

The europium(III) complex of a DOTA-tetraamide ligand (DOTA = 1,4,7,10-tetraazacyclododecane-N,N',N' ',N' ''-tetraacetic acids) containing two phenyl boronate pendent arms binds glucose reversibly with an association constant of 383 M-1 at pH 7. Glucose binding results in slowing of water exchange between a single Eu(…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies