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New π-Complexation Adsorbents for Propane−Propylene Separation

Carlos A. Grande、J.D.P. Araújo、Simone Cavenati 等 6 位作者2004-05-26Langmuir

New adsorbents were prepared and tested for the separation of propane-propylene mixtures by adsorption. The ordered mesoporous material SBA-15 was used as the starting material for silver-ion deposition for pi-complexation with propylene. Two different loadings of silver were evaluated. Adsorption equilibrium and kine…

Mesoporous Materials and CatalysisCatalytic Processes in Materials ScienceZeolite Catalysis and Synthesis

Mobility and In Situ Aggregation of Charged Microparticles at Oil−Water Interfaces

Sowmitri Tarimala、Srinivas R. Ranabothu、Jeremy P. Vernetti 等 4 位作者2004-05-26Langmuir

Particle mobility, aggregate structure, and the mechanism of aggregate growth at the two-dimensional level have been of long-standing interest. Here, we use solid-stabilized emulsions as a model system to investigate the mobility of charged microparticles at poly(dimethylsiloxane) (oil)-water interfaces using confocal…

Enhanced Oil Recovery TechniquesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Preparation and Thermal Stability of Gold Nanoparticles in Silk-Templated Porous Filaments of Titania and Zirconia

Junhui He、Toyoki Kunitake2004-05-26Chemistry of Materials

Porous metal-oxide filaments were readily fabricated using hydrophobic silk as template via the surface sol−gel process, followed by removal of the organic components. Such biotemplated porous matrixes were employed as nanoreactors for in situ synthesis of gold nanoparticles by NaBH 4 reduction of the incorporated gol…

Pickering emulsions and particle stabilizationGold and Silver Nanoparticles Synthesis and ApplicationsNanoporous metals and alloys

Effect of Monomers on the Basal Spacing of Sodium Montmorillonite and the Structures of Polymer−Clay Nanocomposites

Yeong Suk Choi、Hyeong Taek Ham、In Jae Chung2004-05-26Chemistry of Materials

The basal spacings of sodium montmorillonite (MMT) dispersed in various solvents and monomers were measured via X-ray diffraction. Some liquids with strong hydrogen-bonding groups (δ h ) showed little suspended MMT, but liquids with moderate or poor hydrogen-bonding groups precipitated MMT completely, this indicates t…

Surfactants and Colloidal SystemsPolymer Nanocomposites and PropertiesHydrogels: synthesis, properties, applications

H2OandO2molecules in amorphousSiO2:Defect formation and annihilation mechanisms

Tamas Bakos、Sergey N. Rashkeev、Sokrates T. Pantelides2004-05-26Physical Review B

Interstitial water and oxygen molecules are ubiquitous impurities and participate in various defect formation processes in thermally grown ${\mathrm{SiO}}_{2}$ films and synthetic silica glass. Using results of first-principles calculations we report the types of defects (including different possible charge states) th…

Glass properties and applicationsSemiconductor materials and devicesLuminescence Properties of Advanced Materials

Selective deposition of a gadolinium(III) cluster in a hole opening of single-wall carbon nanohorn

Ayako Hashimoto、Hideki Yorimitsu、Kumiko Ajima 等 9 位作者2004-05-26Proceedings of the National Academy of Sciences

Selective synthesis of particles of angstrom to nanometer size consisting of one to many metal atoms is instrumental in various applications, but it has been hampered by the tendency of the metal atom to form large clusters. We found, as studied by the state-of-the-art electron microscopic technique, a strategy to pro…

Fullerene Chemistry and ApplicationsCarbon Nanotubes in CompositesGraphene research and applications

Polymer Size and Concentration Effects on the Size of Gold Nanoparticles Capped by Polymeric Thiols

Robert G. Shimmin、Andrew B. Schoch、Paul V. Braun2004-05-26Langmuir

Gold nanoparticles stabilized by thiol-terminated poly(ethylene glycol) monomethyl ethers with molecular weights ranging from 350 to 2000 have been prepared at thiol-to-gold molar ratios ranging from 3:1 to 1:8. Particle size distributions have been constructed for these particles from transmission electron microscopy…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials for catalytic reactionsNanocluster Synthesis and Applications

How Scale Inhibitors Work: Mechanisms of Selected Barium Sulphate Scale inhibitors Across a Wide Temperature Range

K. S. Sorbie、N. Laing2004-05-26OpenAlex

Abstract Scale inhibitors (SI) have been applied very successfully over many years in oilfields to prevent the formation of mineral scale. Both barium sulphate and calcium carbonate scales may be prevented using inhibitors, although in this work we will focus on the more difficult barite inhibition problem. A number o…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation Techniques

Novel One-Step Route for Synthesizing CdS/Polystyrene Nanocomposite Hollow Spheres

Dazhen Wu、Xuewu Ge、Zhicheng Zhang 等 5 位作者2004-05-26Langmuir

CdS/polystyrene nanocomposite hollow spheres with diameters between 240 and 500 nm were synthesized under ambient conditions by a novel microemulsion method in which the polymerization of styrene and the formation of CdS nanoparticles were initiated by gamma-irradiation. The product was characterized by transmission e…

Quantum Dots Synthesis And PropertiesPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Observation of Buried Phosphorus Dopants near Clean Si(100)-(2x1) with Scanning Tunneling Microscopy

Geoffrey W. Brown、Holger Grube、Marilyn E. Hawley2004-05-26arXiv

We have used scanning tunneling microscopy to identify individual phosphorus dopant atoms near the clean silicon (100)-(2x1) reconstructed surface. The charge-induced band bending signature associated with the dopants shows up as an enhancement in both filled and empty states and is consistent with the appearance of n…

Materials Science

Different steady states for spin currents in noncollinear multilayers

Peter M Levy、Jianwei Zhang2004-05-26arXiv

We find there are at least two different steady states for transport across noncollinear magnetic multilayers. In the conventional one there is a discontinuity in the spin current across the interfaces which has been identified as the source of current induced magnetic reversal; in the one advocated herein the spin to…

Mesoscale and Nanoscale PhysicsMaterials Science

Identification of transverse spin currents in noncollinear magnetic structures

Jianwei Zhang、Peter M Levy、Shufeng Zhang 等 4 位作者2004-05-26arXiv

We show that the transverse components of spin current in a ferromagnet is linked to an off diagonal spin component of the transmission matrix at interfaces;it has little to do with the mismatch of band structures between dissimilar metals. When we take account of this component,not considered in prior analyses, we fi…

Materials ScienceMesoscale and Nanoscale Physics

The steady state in noncollinear magnetic multilayers

Jianwei Zhang、Peter M Levy2004-05-26arXiv

There are at least two different putative steady state solutions for current across noncollinear magnetic multilayers; one has a discontinuity in the spin current at the interface the other is continuous. We compare the resistance of the two and find the solution with the continuous spin currents is lower. By using th…

Materials ScienceMesoscale and Nanoscale Physics

Current induced spin flip scattering at interfaces in noncollinear magnetic multilayers

Peter M Levy、Jianwei Zhang2004-05-26arXiv

We show that when one drives a charge current across noncollinear magnetic layers the two electron Coulomb scattering creates a spin flip potential at interfaces. This scattering is found when the interface potential is updated due to the spin accumulation attendant to charge flow, and it contributes in linear respons…

Materials ScienceMesoscale and Nanoscale Physics

Self-consistent local GW method: Application to 3d and 4d metals

K. D. Belashchenko、V. P. Antropov、N. E. Zein2004-05-26arXiv

Using the recently developed version of the GW method employing the one-site approximation and self-consistent quasiparticle basis set we calculated the electronic structure of 3d and 4d transition metals at experimental atomic volumes. The results are compared with traditional local density approach and with experime…

Strongly Correlated ElectronsMaterials Science

Comment on 'Pulsed field studies of the magnetization reversal in molecular nanomagnets'

W. Wernsdorfer、N. E. Chakov、G. Christou2004-05-26arXiv

In a recent paper, cond-mat/0404041, J. Vanacken et al. reported experimental studies of crystals of Mn12-ac molecular nanomagnets in pulsed magnetic fields with sweep rates up to 4000 T/s. Steps in the magnetization curve were observed. The data were explained by collective dipolar relaxation. We give here an alterna…

Materials ScienceMesoscale and Nanoscale Physics

Dissolution of Pristine Single Walled Carbon Nanotubes in Superacids by Direct Protonation

Sivarajan Ramesh、Lars M. Ericson、Virginia A. Davis 等 10 位作者2004-05-26OpenAlex

Strong tube−tube van der Waal attractions that hinder the dissolution of single walled carbon nanotubes (SWNTs) as individuals have been overcome by the direct protonation of the tubes by superacids. The pristine nanotubes disperse as individuals in 100% H 2 SO 4, oleum, trifluromethanesulfonic acid, and chlorosulfoni…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsGraphene research and applications

Large-Scale Synthesis of Six-Nanometer-Wide ZnO Nanobelts

Xudong Wang、Yong Ding、Christopher J. Summers 等 4 位作者2004-05-26OpenAlex

Using a thin film of metallic tin as catalyst, ultrasmall single-crystalline zinc oxide nanobelts have been synthesized in large quantity using a simple solid−vapor technique. The nanobelts have an average width of 5.5 nm and a narrow size distribution of ±1.5 nm. The nanobelts grew along the [0001] direction, with (2…

Quantum Dots Synthesis And PropertiesZnO doping and propertiesNanowire Synthesis and Applications

Ultrathin Poly( N -isopropylacrylamide) Grafted Layer on Polystyrene Surfaces for Cell Adhesion/Detachment Control

Yoshikatsu Akiyama、Akihiko Kikuchi、Masayuki Yamato 等 4 位作者2004-05-26OpenAlex

We investigated physicochemical properties of two types of poly(N-isopropylacrylamide) (PIPAAm)-grafted tissue culture polystyrene (TCPS) surfaces, to elucidate the influential factors for thermally regulated cell adhesion and detachment to PIPAAm-grafted surfaces. The two types of PIPAAm-grafted surfaces were prepare…

Tissue Engineering and Regenerative MedicineElectrospun Nanofibers in Biomedical Applications3D Printing in Biomedical Research

An Oxidized Porous Silicon (OPS) Microlens Implemented on Thick OPS Membrane for a Silicon-Based Optoelectronic-Multichip Module (OE-MCM)

Man-Lyun Ha、Joo‐Hyung Kim、S.-K. Yeo 等 4 位作者2004-05-25IEEE Photonics Technology Letters

Using the silicon bulk micromachining and selectively oxidized porous silicon (SOPS) technology, a silicon dioxide microlens was implemented on thick oxidized porous silicon (OPS) membrane. Because the surface of microlens was the interface of OPS-Si, the surface roughness of lens was directly affected by the anodizat…

Nanowire Synthesis and ApplicationsSilicon Nanostructures and PhotoluminescenceSemiconductor materials and devices