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Release of Photoactivatable Drugs from Plasmonic Nanoparticles for Targeted Cancer Therapy

Yun-Ling Luo、Yi-Syun Shiao、Yu‐Fen Huang2011-09-26ACS Nano

Chemotherapy is an important modality in cancer treatment. The major challenges of recent works are to improve drug loading, increase selectivity to target cells, and control the precise release of drugs. In the present study, we devised a smart drug carrier, an aptamer/hairpin DNA-gold nanoparticle (apt/hp-Au NP) con…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesRNA Interference and Gene Delivery

Graphene Transistor Arrays for Recording Action Potentials from Electrogenic Cells

Lucas H. Hess、M. Jansen、Vanessa Maybeck 等 9 位作者2011-09-26Advanced Materials

Arrays of graphene solution-gated field-effect transistors are fabricated for the detection of electrical activity of electrogenic cells. Cardiomyocyte-like cells are cultured on the transistor arrays and their action potentials are detected by the underlying transistors. The analysis of the recorded cell signals and…

Graphene research and applicationsAdvanced Memory and Neural ComputingNeuroscience and Neural Engineering

Biomedical potential of silver nanoparticles synthesized from calli cells of Citrullus colocynthis (L.) Schrad

K. Satyavani、Gurudeeban Selvaraj、T. Ramanathan 等 4 位作者2011-09-26Journal of Nanobiotechnology

BACKGROUND: An increasingly common application is the use of silver nanoparticles for antimicrobial coatings, wound dressings, and biomedical devices. In this present investigation, we report, biomedical potential of silver nanopaticles synthesized from calli extract of Citrullus colocynthis on Human epidermoid larynx…

Nanoparticles: synthesis and applicationsAdvances in Cucurbitaceae ResearchChemotherapy-induced organ toxicity mitigation

Hierarchically Assembled ZnO Nanocrystallites for High‐Efficiency Dye‐Sensitized Solar Cells

Nafiseh Memarian、Isabella Concina、Antonio Braga 等 6 位作者2011-09-26Angewandte Chemie International Edition

Spray pyrolysis is effective in the formation of a nanoengineered photoanode. An unprecedented photoconversion efficiency of 7.5 % for ZnO-based dye-sensitized cells was achieved on a photoelectrode consisting of polydispersed ZnO aggregates of nanocrystallites over a compact ZnO buffer layer at a firing temperature o…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesZnO doping and properties

Amorphous TiO2 Nanotube Anode for Rechargeable Sodium Ion Batteries

Hui Xiong、Michael Slater、Mahalingam Balasubramanian 等 5 位作者2011-09-26The Journal of Physical Chemistry Letters

Sodium ion batteries are an attractive alternative to lithium ion batteries that alleviate problems with lithium availability and cost. Despite several studies of cathode materials for sodium ion batteries involving layered oxide materials, there are few low-voltage metal oxide anodes capable of operating sodium ion r…

Advancements in Battery MaterialsGraphene research and applicationsAdvanced Battery Materials and Technologies

Near-Complete Suppression of Surface Recombination in Solar Photoelectrolysis by “Co-Pi” Catalyst-Modified W:BiVO4

Diane K. Zhong、Sujung Choi、Daniel R. Gamelin2011-09-26Journal of the American Chemical Society

The influence of an earth-abundant water oxidation electrocatalyst (Co-Pi) on solar water oxidation by W:BiVO(4) has been studied using photoelectrochemical (PEC) techniques. Modification of W:BiVO(4) photoanode surfaces with Co-Pi has yielded a very large (∼440 mV) cathodic shift in the onset potential for sustained…

Advanced Photocatalysis TechniquesIron oxide chemistry and applicationsCopper-based nanomaterials and applications

Tunable and absolute electromagnetic vacuum in two-dimensional photonic-band-gap Based on multiferroic materials

Kai Chen、Wei Jia、Yanbin Chen 等 14 位作者2011-09-26Applied Physics Letters

When multiferroic terbium manganite (TbMnO3) crystal cylinders are periodically arranged in a square lattice, the resulting two-dimensional (2D) system exhibits photonic band gaps (PBGs). The absolute PBG originating from the Mie resonance is modulated from closed to open by applying an external static magnetic field,…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsMultiferroics and related materials

Fabrication and analysis of transmission gratings produced by the indirect laser etching technique

Bálint Kiss、Cs. Vass、P Heck 等 5 位作者2011-09-26Journal of Physics D Applied Physics

The diffraction efficiency of gratings etched into fused silica was measured and modelled. 950, 2120 and 3710 nm period gratings were fabricated with the use of two-beam interferometric laser-induced backside wet etching (TWIN-LIBWE). The spatial distribution of the modulation depth (MD), determined from AFM measureme…

Advanced Surface Polishing TechniquesOptical Coatings and GratingsSurface Roughness and Optical Measurements

A novel redox-active calix[4]arene-tetrathiafulvalene dyad

Bang‐Tun Zhao、Xiaomin Zhu、Qiming Peng 等 6 位作者2011-09-26Open Chemistry

Abstract A novel redox-active calix[4]arene-TTF 5 was prepared by the reaction of p-tert-butylcalix[4]arene 4 with the tosylated TTF 3 in the presence of cesium fluoride. The structure of the dyad 5 was identified by X-ray diffraction analysis, and the preliminary electrochemical properties of 5 were investigated by c…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryOrganic and Molecular Conductors Research

Molecular Dynamics of Linear and Crosslinked Polyester Urethanes Studied by Dielectric Spectroscopy

Ștefan Oprea、Valentina Musteaţa、Violeta Otilia Potolinca2011-09-26Journal of Elastomers & Plastics

The molecular dynamics of crosslinked polyurethanes have been studied by dielectric spectroscopy and compared with the dynamics of linear polyurethanes. Two local relaxations, γ and β, and a primary relaxation, α, were observed for all the samples, appearing in relation with the increase in temperature. The conductivi…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsPolymer composites and self-healing

Mechanochemically Assisted Extraction

O.I. Lomovsky、Igor Lomovsky2011-09-26Contemporary food engineering

Diffusion processes are among the most important technical operations in various industries, especially chemical, pharmaceutical, and food production. In the diffusion model, it is assumed that viscous forces and permeability barriers within the microstructure of the biological material prevent coherent velocity ªow o…

Analytical chemistry methods developmentExtraction and Separation ProcessesCrystallization and Solubility Studies

Electromagnetic near-field interactions of a dipolar emitter with metal and metamaterial nanoslabs

Timo Hakkarainen、Tero Setälä、Ari T. Friberg2011-09-26Physical Review A

We investigate the emission properties of a polarizable point dipole placed within a subwavelength distance from a silver or a slightly absorbing, negative-index metamaterial nanoslab. Using electromagnetic theory we show that in the immediate vicinity of the slab the dipole-slab interaction prevents the dipole from r…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

Relieving frustration: The case of antiferromagnetic Mn 3 molecular triangles

Junjie Liu、Changhyun Koo、Asma Amjad 等 8 位作者2011-09-26Physical Review B

Recently, various triangular [Mn${}^{\mathrm{III}}$]${}_{3}$ molecules have been extensively studied due to the fact that one can modulate the magnitude and the sign of the inter-ion exchange, thereby giving rise to very simple clusters that constitute some of the cleanest and best examples of so-called single-molecul…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Quantification of Quantum Dot Concentration Using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS)

Sarah L. Sewell、Melinda M Higgins、Charleson S. Bell 等 4 位作者2011-09-26Journal of Biomedical Nanotechnology

As quantum dot (QD) bioconjugates are increasingly being used for biomedical in vitro and in vivo studies, validated methods for the quantitative determination of QD concentration are of considerable potential value. In this work, we have assessed inductively coupled plasma mass spectrometry (ICP-MS) as a method for t…

Quantum Dots Synthesis And PropertiesIon-surface interactions and analysis

Atomistic mechanisms of moisture-induced fracture at copper-silica interfaces

Dandapani Vijayshankar、Hong Zhu、Saurabh Garg 等 7 位作者2011-09-26Applied Physics Letters

Tailoring the chemo-mechanical properties of metal-dielectric interfaces is crucial for many applications including nanodevice wiring, packaging, composites, and catalysis. Here, we combine moisture-induced fracture tests, electron spectroscopy, and density functional theory calculations to reveal fracture toughness p…

Advanced ceramic materials synthesisCorrosion Behavior and InhibitionCopper Interconnects and Reliability

Photoluminescence due to inelastic exciton-exciton scattering in ZnMgO-alloy thin film

C. H. Chia、J. N. Chen、Y. M. Hu2011-09-26Applied Physics Letters

We studied the photoluminescence of ZnMgO thin film, grown by the radiofrequency sputtering method, as a function of excitation intensity and temperature. As the excitation intensity increases, a nonlinear emission band caused by the radiative recombination of the inelastic exciton-exciton scattering was detected at l…

ZnO doping and propertiesPerovskite Materials and ApplicationsGa2O3 and related materials

Degradation Due to Neutron Embrittlement of Nuclear Vessel Steels: A Critical Review about the Current Experimental and Analytical Techniques to Characterise the Material, with Particular Emphasis on Alternative Methodologies

Diego Ferreño、I. Gorrochategui、Federico Gutierrez-Sol2011-09-26InTech eBooks

The pressure vessel constitutes the most important structural component in a nuclear reactor from the point of view of its safety. The core of the reactor, that is, the nuclear fuel, is accommodated inside the vessel. This material is composed of fissile nuclides that undergo chain nuclear reactions of an exothermic n…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Synthesis, crystal structures, and photophysical properties of dibromo-2-(2′-pyridyl)imidazole and its corresponding boron–fluorine complex

Miaofu Mao、Ronghua Zhang、Shuzhang Xiao 等 4 位作者2011-09-26Journal of Coordination Chemistry

2-(2′-Pyridyl)imidazole L1 and its corresponding boron–fluorine complex, 1, were synthesized and their crystal structures correlated with their photophysical properties. L1 forms a rigid supramolecular network through hydrogen bonds and halogen bond in the single crystal, which induces amplified spontaneous emission i…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsOrganoboron and organosilicon chemistry

Role of structural disorder in ferromagnetism of chromium-doped indium oxide

C. Y. Hsu2011-09-26Journal of Physics D Applied Physics

Structurally defective and highly crystallized chromium (Cr)-doped indium oxide samples are fabricated by rf sputtering. Both samples with 4% Cr doping show a very weak saturation magnetization of ∼0.05μ B /Cr. The magnetization of the structurally defective Cr-doped films as low as 2.8% is significantly enhanced to ∼…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Fluorescent and Paramagnetic Chitosan Nanoparticles that Exhibit High Magnetic Resonance Relaxivity: Synthesis, Characterization and In Vitro Studies

Padmavathy Tallury、Swadeshmukul Santra、Parvesh Sharma 等 10 位作者2011-09-26Journal of Biomedical Nanotechnology

We report water-in-oil (W/O) microemulsion synthesis of fluorescently bright and paramagnetically strong bimodal chitosan nanoparticles (BCNPs). The W/O microemulsion system provides a confined environment for producing monodispersed BCNPs. Average particle size as estimated by the Transmission Electron Microscopy was…

Surfactants and Colloidal SystemsPhotochemistry and Electron Transfer StudiesLanthanide and Transition Metal Complexes