Materials Literature
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Fluorescence spectroscopy is employed to follow the ion exchange of an emissive dye--a carboxylated perylene imide--on a layered double hydroxide. The exchange of the carboxylate ions starts at the edges of the layered double hydroxide crystals and is followed by diffusion to the basal plane. Such space-resolved obser…
As the role for diagnostic and therapeutic contrast-enhanced imaging increases, review of the epidemiology, mechanisms, risk factors, and pretreatment for radiocontrast-mediated anaphylactoid reactions becomes more and more pertinent. Ongoing research has failed to elucidate the precise mechanisms of both early and la…
Mechanically responsive surfaces that allow to switch reversibly from a hydrophobic to a hydrophilic substrate are reported. The surfaces are constituted of polyelectrolyte multilayers deposited on modified charged silicone sheets. n bilayers of poly(allylamine)-Nafion (PAH-Naf) and m bilayers of poly(allylamine)-poly…
Reproducibly high-yield growth of zigzag fibers and well-faceted nanobelts of SnO2 was achieved via tuning the reactant vapor. The investigation of the morphological evolution via scanning electron microscopy and transmission electron microscopy hints that the formation of the zigzag SnO2 fiber is based on the pregrow…
4H-SiC visible-blind photodetectors specially designed for extreme ultraviolet (EUV) as well as ultraviolet (UV) detection are fabricated and characterised. Spectral quantum efficiency (QE) from 21.5 to 400 nm is determined. The devices have a 2×2 mm active area and less than 1 pA leakage current at low bias. The peak…
Die richtige Lösung für den Spin: Spintransfer und Solvatochromie/Thermochromie zeigt ein rein organisches offenschaliges System, in dem ein neutrales 6-Oxophenalenoxyl-Radikal als Elektronenacceptor direkt mit einer Tetrathiafulvalen-Einheit als Elektronendonor verbunden ist. Ein intramolekularer Elektronentransfer (…
The study of the anion ordered (TMTSF) 2 ClO 4(1 − x ) ReO 4 x solid solution in the limit of a low ReO 4 − substitution level (0 ⩽ x ⩽ 17%) has revealed a new and interesting phase diagram. Superconductivity is drastically suppressed as the effect of ReO 4 − non-magnetic point defects increases following the digamma…
We report the synthesis and characterization of the novel ligand H(5)EPTPA-C(16) ((hydroxymethylhexadecanoyl ester)ethylenepropylenetriaminepentaacetic acid). This ligand was designed to chelate the Gd(III) ion in a kinetically and thermodynamically stable way while ensuring an increased water exchange rate (kappa(ex)…
The reaction of 1,1-diphenylhydrazine with Ti(NMe2)2Cl2 produced the monomeric terminal titanium hydrazido(2-) species Ti(NNPh2)Cl2(HNMe2)2 (1) in near-quantitative yield. The reaction of Ti(NMe2)2Cl2 with the less sterically demanding ligand precursors 1,1-dimethylhydrazine or N-aminopiperidine gave the dimeric mu-et…
We show that near-spherical micrometer-sized colloidal particles at an interface of two fluids experience inter-particle forces merely as a consequence of their shape-induced capillary interaction. The interaction is strong even if the deviations from sphericity are on the nm-scale, and can hardly be avoided in experi…
The dynamics of colloidal star—linear homopolymer mixtures is investigated by photon correlation spectroscopy. In dilute star solutions, osmotic forces due to the added polymers lead initially to a shrinkage of the stars and eventually, at higher polymer concentrations, to stable star clusters. Furthermore, concentrat…
The oxidation of linolenic acid (LNA) and soy lecithin was studied by differential scanning calorimetry (DSC) with linear programmed heating rates (non-isothermal mode). The interpretation of the shape of DSC curves is discussed, and it has been concluded that temperatures of the extrapolated start of heat release are…
A bis(Zn(II)-porphyrin) tweezer host with anthracene components as apex and side-arms has been synthesized. Mono- (pyridine) and bidentate (4,4'-bipyridine) guests were used as models for single and double axial coordination inside the cavity, respectively. A series of dipyridylporphyrin guests with different substitu…
Covalent fixation of a chiral helical structure which is created in a self-assembling system by a chiral-amplification method based on the sergeants/soldiers principle is reported. Disk-shaped triazine triamides self-assembled to form columnar-type helical aggregates through pi-stacking interactions among the central…
[Reaction: see text]. Fluorogenic calix[4]arenes (1 and 2) bearing a pendent ethyleneamine on their triazacrown rings, respectively, were synthesized in the cone conformation. Compared with 4, free 1 and 2 display a relatively weak emission, reflecting that a PET process from the pendent amine group (-CH2CH2NH2) to th…
The hydrothermally stable and long-range ordered Ce-MCM-48 and Fe-MCM-48 were conveniently synthesized at 393 K for 24 h by directly adding fluoride ions to the initial gel without posttreatment and pH adjustment. The Ce-MCM-48 with a Si/Ce of 200 and 100, which were prepared by directly adding fluoride ions, could st…
Four new inorganic-organic hybrid coordination polymers in which 1D or 2D manganese(II) azido inorganic motifs are interlinked into higher-dimensional networks have been synthesized by use of a series of bis(pyridyl)-type organic bridging ligands (linkers) with different side groups and/or different coordination orien…
Mesoporous silica thin films were shown to be an appropriate matrix for immobilization of discrete electroactive moieties, yielding uniform transparent thin film electrodes with defined texture and enhanced electrochemical activity. The mesoporous silica films prepared on conducting FTO-coated glass substrate were pos…
We study the capillary forces acting on sub-millimeter particles (0.02-0.6 mm) trapped at a liquid-liquid interface due to gravity-induced interface deformations. An analytical procedure is developed to solve the linearized capillary (Young-Laplace) equation and calculate the forces for an arbitrary number of particle…
Comprehensive studies for a periodic array of gold nanorod pairs demonstrate its unique optical properties, including a negative refractive index in the optical range.