Materials Literature
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Vacuum annealing is a widely used method to increase the electric conductivity of SrTiO3 single crystals. The induced oxygen vacancies act as intrinsic donors and lead to n-type conductivity. Apart from the changed electronic structure, however, also crystal structure modifications arise from this treatment. Hence, el…
Water is known to be an exceptionally poor glass former, which is a significant drawback in the low-temperature storage of food and biomatter. This is one of the characteristic features of water, but its link to the thermodynamic and kinetic anomalies of water remains elusive. Recently, we showed that the glass-formin…
Abstract Closed capped WS2 nanotubes with diameters from 30 to 110 nm are studied by high resolution transmission electron microscopy (HRTEM). The tubes exhibit preferentially a hexagonal stacking order. Atomic resolution images of a 30 nm diameter tube reveal a zigzag chirality. A lattice expansion in c‐axis directio…
Energy eigenvalues and wave functions of hydrogen atoms in hydride LaNi(5)H(7) are calculated. First-principles electronic structure calculations are employed to obtain the three-dimensional potential energy structure of each hydrogen site. These quantum effects are not negligibly small in evaluation of enthalpy of fo…
Based on first-principles approach, the transport properties of single layer armchair h-BNC heterostructures are investigated. The results show that NDR behaviors, whose peak-to-valley ratio reaches ten, and rectifying performance with rectification ratio of up to 21, can be observed while the graphene nanoribbon and…
Polythiophene is chemically synthesized and doped with FeCl 3 for 2.5, 5 and 10 h.For structural investigation all samples have been characterized using different techniques.The results of elemental analysis show that with the increase of doping duration the Fe content increases while the S content decreases.FTIR spec…
Micro- and nanostructures of Ti-γCu (γ = 0, 30, 50, 70, and 100 wt %) intermetallic alloys were produced through a single anodization step. It was found that the original alloy composition influences the final oxide morphology obtained after anodization which presented formation of a microstructure with nanotubes, nan…
Abstract Porous polymer films were generated by biaxial stretching of polypropylene (PP) and high‐density polyethylene (HDPE) filled with various amounts of calcium carbonate particles. The porosity of the films was measured by mercury porosimetry, and the obtained results were related to the processing conditions and…
Several representative ionic liquids (ILs) were synthesized, and [Emim]OAc was chosen as environment-friendly solvent for enzymatic in situ saccharification in view of its biocompatibility with both natural and microcrystalline cellulose, as well as its enzymatic activity. With the microwave pretreatment of natural an…
Resonant Raman spectroscopy has been employed to explore the first- and higher-order phonon spectra of several kinds of II-VI nanocrystals (NCs), with the aim of better understanding of the nature of phonon modes and forming a unified view onto the vibrational spectrum of semiconductor NCs. Particularly, besides the p…
The applications of nanostructures critically depend on their morphologies. Although significant progress has been made in the chemical synthesis of nanostructures with a variety of different morphologies, it is still highly desired to develop an approach that allows one to quickly identify the best set of parameters…
Nanoporous BaTiO3 particles with an average diameter of 27 nm have been synthesized using a soft template based on poloxamer. The pore width has been found to be ∼10 nm. The nanoporous particles have a surface area of 107 m2gm−1. This introduces a large surface area leading to the creation of a large number of oxygen…
Cotton/polyester woven fabrics were functionalized with ZnO thin films or nanoparticles by pulsed laser deposition, using a KrF* excimer laser source. Depending on the number of applied laser pulses, well-separated nanoparticles (for 10 pulses) or compact thin films (for 100 pulses) were deposited. The synthesized nan…
The local crystal structure and phonon modes of Ba[(Fe1/2Nb1/2)1−xTix]O3 solid solutions (x = 0, 0.2, 0.4, 0.6, 0.8, 0.85, 0.9, 0.95) were investigated by Raman spectroscopy in the range of 100–1000 cm− 1 at room temperature. Typical tetragonal structure with C4v symmetry was determined for Ba[(Fe1/2Nb1/2)0.05Ti0.95]O…
This contribution presents an analytical formulation for the electromagnetic response of grids of ferromagnetic microwires, where the electromagnetic fields produced by the structure are found by means of the local field method. In addition, a circuit analogy is introduced for a better understanding of the grid respon…
Thermal aging of hydroxy-terminated polybutadiene/isophorone diisocyanate (HTPB/IPDI)-based polyurethane was studied as a function of NCO/OH ratio (1.0 and 0.85). Samples were aged in air ovens at 50, 60, 65, and 70 ºC for periods of time from 1 to 34 weeks. Changes in chemical (swelling testing and FT-IR spectroscopy…
Abstract Graphene is a truly two‐dimensional (2D) material with exceptional electronic, mechanical, and optical properties. As such, it consists of surface only and can be probed by the well‐developed surface science techniques such as, e.g., scanning tunneling microscopy (STM). This method bridges the gap between the…
The nucleation and growth kinetics of single-wall carbon nanotubes in aligned arrays have been measured using fast pulses of acetylene and in situ optical diagnostics in conjunction with low pressure chemical vapor deposition (CVD). Increasing the acetylene partial pressure is shown to decrease nucleation times by thr…
Diffusion mass transfer in thin chalcogenide films under illumination by a focused Gaussian beam have been studied both experimentally and theoretically. It is demonstrated that depending on the light intensity, waist of the beam, and the film thickness, one can obtain formation of either hillocks or dips in the illum…
Structural, magnetic, and electrical transport properties of $\ensuremath{\delta}$-Mn${}_{x}$Ga${}_{1\ensuremath{-}x}$ epitaxial layers are investigated for alloy compositions in the range of $x=0.49\phantom{\rule{0.16em}{0ex}}...\phantom{\rule{0.16em}{0ex}}0.67$. All samples were grown by molecular beam epitaxy on Ga…