Materials Literature
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Abstract The impact behaviors of nanoclay filled nylon 6 (nano‐nylon 6) or nylon 6 blended with poly(acrylonitrile‐butadiene‐styrene) terpolymers (ABS) were investigated here using polybutadiene grafted maleic anhydride (PB‐ g ‐MA) as a compatibilizer to enhance interphase interaction. It is found that impact strength…
We present the optical conductivity and Raman spectra of θ-(BEDT-TTF) 2 CsZn(SCN) 4 . The vibrational and vibronic bands in the 1200–1600 cm -1 region was assigned with the aid of the 13 C-substituted compound. The nearly uniform charge distribution was found in a whole temperature range from 300 to 6 K. However, the…
An in situ cell designed for synchrotron X-ray diffraction during electrochemical cycling of battery materials is presented. The cell operates in transmission mode and can be oscillated with the dedicated sample holder to improve powder statistics. It allows fast data acquisition, provides hermetic sealing and high-qu…
When methyl 4,6-O-(p-nitrobenzylidene)-alpha-D-glucopyranoside (p-NO(2)Glu) was dissolved in water, p-NO(2)Glu molecules self-assembled to form a fiber (elemental fiber), and as a result, the solution became a partially transparent gel. When an equal (or more) amount of DNA was added to the gel, a white and crystallin…
The reaction of [Mn(CH2tBu)2(tmeda)] (1) and a silica partially dehydroxylated at 700 degrees C (SiO(2/700)) yields a single surface species [([triple bond]SiO)Mn(CH2tBu)(tmeda)] (2a; tmeda = tetramethylethylendiamine), while a mixture of 2a and [([triple bond]SiO)2Mn(tmeda)] (2b) is obtained by using SiO(2/200), SiO(…
Analytic expressions are presented for calculating translations of high-order three-dimensional expansions of orthonormal real spherical harmonic and Gaussian-type or exponential-type radial basis functions. When used with real spherical harmonic rotation matrices, the resulting translation matrices provide a fully an…
Characteristic temperatures and structural relaxation times for different classes of glass-forming polymer liquids are computed using a revised entropy theory of glass formation that permits the chain backbone and the side groups to have different rigidities. The theory is applied to glass formation at constant pressu…
Linear homo- and co-polycarbonates have been prepared from the sugar-based diols 2,3,4-tri- O -methyl- l -arabinitol and 2,3,4-tri- O -methylxylitol. Statistical co-polycarbonates were obtained from molar feed ratios of sugar:bisphenol A of 1:1 and 2:1. The polycarbonates were stable up to ∼280 °C with maximum decompo…
We present a time-dependent quantum-chemical analysis on merocyanine aggregates to understand the insight of the intermolecular interactions and to find the relationship between structural and collective nonlinear optical properties. The first hyperpolarizabilities are evaluated for monomer and aggregates of a series…
The structure and magnetic properties of magnetite (Fe3O4) nanoparticles synthesized by a solvothermal processing route are investigated. The nanoparticles are grown from the single organometallic precursor Fe(III) acetylacetonate in trioctylamine (TOA) solvent at 260°C, with and without the addition of heptanoic acid…
Phonon scattering in carbon nanotube field-effect transistors (CNTFETs) is treated using the nonequilibrium Green’s function formalism with the self-consistent Born approximation. The treatment simultaneously captures the essential physics of phonon scattering and important quantum effects. For a one-dimensional chann…
Although poly(tetrafluoroethylene) (PTFE) is an unusually ductile polymer, it undergoes an abrupt ductile-brittle transition at modest impact velocities. No previous explanation for this behavior has been found after an extensive literature search. In this paper, we examine the role of a pressure-induced phase transit…
Nuclear magnetic resonance spectroscopy was used to study polycrystalline $\ensuremath{\beta}$-spodumene $(\ensuremath{\beta}\text{\ensuremath{-}}\mathrm{Li}\mathrm{Al}{\mathrm{Si}}_{2}{\mathrm{O}}_{6})$ as well as glassy specimens with the same chemical composition. $^{7}\mathrm{Li}$ spin-lattice relaxation measureme…
Abstract Boehmite [AlOOH] nanoneedles, nanorods, and nanotubes were successfully synthesized by a facile sol‐hydrothermal method without using any surfactant. Calcination of the corresponding boehmite nanostructures at 700 °C gave the corresponding γ‐Al 2 O 3 nanoneedles, nanorods, and nanotubes. The resulting product…
A novel Se/C nanocomposite with core-shell structures has been prepared through a facile one-pot microwave-induced hydrothermal process. The new material consists of a trigonal-Se (t-Se) core and an amorphous-C (a-C) shell. The Se/C composite can be converted to hollow carbon capsules by thermal treatment. These produ…
beta-Halogenated dioxoruthenium(VI) porphyrin complexes [Ru(VI)(F(28)-tpp)O(2)] [F(28)-tpp=2,3,7,8,12,13, 17,18-octafluoro-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato(2-)] and [Ru(VI)(beta-Br(8)-tmp)O(2)] [beta-Br(8)-tmp=2,3,7,8,12,13,17,18-octabromo-5,10,15,20- tetrakis(2,4,6-trimethylphenyl)porphyrinato(2-)]…
This DOI is not currently attached to any metadata records. DOIs can’t actually ever be deleted (they’re persistent), but sometimes our members create DOIs in error. We do have a process to approximate deletion which we follow only in rare cases where the DOI has been genuinely created in error, and most crucially, if…
The corrosion inhibition of zinc in hydrochloric acid by extract of Nypa Fruticans Wurmb was studied using weight loss techniques. Maximum inhibition efficiency (and surface coverage) was obtained at an optimum concentration. However increase in temperature decreased the inhibition efficiency at the temperature range…
The shape coefficient of a curve, which is defined as the ratio of its full width at half-maximum intensity to integral width, is a measure of variation in shape. From the definitions of the pseudo-Voigt, Pearson VII and Voigt functions used in X-ray diffractometry, three shape-converting formulae are deduced. Numeric…
The Rietveld method of crystal structure refinement was an important breakthrough, allowing crystal structural information to be obtained from powder diffraction data. One remaining challenge is to collect Rietveld-quality data for polycrystalline minerals in situ , using laboratory-based micro X-ray diffraction (µXRD…