Materials Literature
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Nanowires of different nature have been shown to self-assemble as a function of stress at the contact between two macroscopic metallic leads. Here we demonstrate for gold wires that the balance between various metastable nanowire configurations is influenced by the microstructure of the starting materials and we disco…
First principles calculations of the geometric and electronic structures have been performed for two coverages (0.25 ML and 0.5 ML) of C on Ni(001) to understand the mechanism of the Ni(001) reconstruction induced by carbon adsorption. The calculated structural behavior of the system is in a good agreement with experi…
Isotropic-Nematic and Nematic-Nematic transitions from a homogeneous base state of a suspension of high aspect ratio, rod-like magnetic particles are studied for both Maier-Saupe and the Onsager excluded volume potentials. A combination of classical linear stability and asymptotic analyses provides insight into possib…
The behavior of highly charged short rod-like polyelectrolytes near oppositely charged planar surfaces is investigated by means of Monte Carlo simulations. A detailed microstructural study, including monomer and fluid charge distribution, and chain orientation, is provided. The influence of chain length, substrate's s…
The dissociation of H$_2$ molecules on stretched Au nanowires and its effect on the nanowire conductance are analyzed using a combination of Density Functional (DFT) total energy calculations and non-equilibrium Keldish-Green function methods. Our DFT simulations reproduce the characteristic formation of Au monoatomic…
Various devices and technologies using nanowires and nanoparticles are under intense investigation because of their promise. In these devices, nanowires or nanoparticles are typically in contact with another surface. The contact between a nanowire and a nanoparticle with a substrate forms a constriction of the order o…
Polypyrrole (PPy) nanotubes were readily fabricated through chemical oxidation polymerization in sodium bis(2-ethylhexyl) sulfosuccinate (AOT) reverse (water-in-oil) emulsions. The reverse cylindrical micelle phase was characterized, and the key factors affecting the formation of PPy nanotubes were systematically insp…
A central goal of modern materials physics and nanoscience is control of materials and their interfaces to atomic dimensions. For interfaces between polar and non-polar layers, this goal is thwarted by a polar catastrophe that forces an interfacial reconstruction. In traditional semiconductors this reconstruction is a…
This paper is a study of the behavior of experimentally observed stress-strain force during the fracture of a quantum wire. The magnitude of the force oscillates as a function of time and can be phenomenologically regarded as a sign of discrete-scale invariance. In the theory of discrete-scale invariance, termination…
We investigate theoretically donor-based charge qubit operation driven by external electric fields. The basic physics of the problem is presented by considering a single electron bound to a shallow-donor pair in GaAs: This system is closely related to the homopolar molecular ion H_2^+. In the case of Si, heteropolar c…
Organic semiconducting polymers are currently of broad interest as potential low-cost materials for photovoltaic and light-emitting display applications. I will give an overview of our work in developing a consistent quantum dynamical picture of the excited state dynamics underlying the photo-physics. We will also foc…
Glass is highly sensitive to surface flaws generated by contact. Surface cracks threaten both its mechanical strength and visual aspect. Recent trends in glass functionalisation by grafting or coating lend an even more prominent role to the surface. For these reasons, the glass surface mechanics, which couples surface…
Spins of single donor atoms are attractive candidates for large scale quantum information processing in silicon, since quantum computation can be realized through the manipulation of electron and/or nuclear spins. We here report on two-pulse electron spin echo experiments on phosphorus shallow donors in natural and 28…
Controlled synthesis of hyperbranched CdTe and CdSe semiconductor nanocrystals is presented. The length of the arms and the degree of branching could be controlled independently by varying the amount and kind of organic surfactant. The three-dimensional structure of these nanocrystals has been characterized with TEM t…
Most of the colloidal clusters have been produced from oil-in-water emulsions with identical microspheres dispersed in oil droplets. Here, we present new types of binary colloidal clusters from phase-inverted water-in-oil emulsions using various combinations of two different colloids with several size ratios: monodisp…
Microwave reactor methodologies are unique in their ability to be scaled-up without suffering thermal gradient effects, providing a potentially industrially important improvement in nanocrystal synthetic methodology over convective methods. Synthesis of high-quality, near monodispersity nanoscale InGaP, InP, and CdSe…
The development of technology enables the reduction of material size in science. The use of particle reduction in size from micro to nanoscale not only provides benefits to diverse scientific fields but also poses potential risks to humans and the environment. For the successful application of nanomaterials in bioscie…
Abstract Chelate polymers of azelaoyl bis‐ N ‐phenyl hydroxamic acid with Mn(II), Co(II), Ni(II), and Zn(II) were synthesized for the first time in a dimethylformamide (DMF) medium. These newly synthesized chelate polymers were characterized on the basis of several analytical techniques, namely, elemental analyses, in…
Abstract Polyimide‐ g ‐nylon 6 copolymers were prepared by the polymerization of phenyl 3,5‐diaminobenzoate with several diamines and dianhydrides with a one‐step method. The polyimides containing pendant ester moieties were then used as activators for the anionic polymerization of molten ε‐caprolactam. Nylon 6‐ b ‐po…
Biraite-(Ce), ideally Ce2Fe2+(CO3)(Si2O7), has been found in the Biraia deposit (Irkutsk district, Russia), associated with cordylite-(Ce) and -(La), aragonite, strontianite, Sr,Fe- bearing dolomite, ancylite-(Ce) and -(La), hydroxyl-bastnäsite-(Ce), daqingshanite-(Ce) and -(La), tremolite, winchite, ferriallanite-(C…