Materials Literature
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Nanometer‐sized crystallites of Y‐type strontium hexaferrite, Sr 2 Ni 2 Fe 12 O 22 and its Mn‐ and Cr‐doped derivatives have been synthesized by the sol–gel method. Y‐type phase formation was achieved at a considerably lower temperature of 950°C than is required in the traditional solid‐state method (1200°C). The effe…
Ionothermal synthesis was applied to the formation of polyoxometalates (POMs) and two new compounds [EMIM](8)Na(9)[WFe(9)(micro(3)-O)(3)(micro(2)-OH)(6)O(4)H(2)O(SiW(9)O(34))(3)].7H(2)O (, [EMIM](8)Na(9)[].7H(2)O, EMIM = 1-ethyl-3-methylimidazolium) and [EMIM](4)[SiMo(12)O(40)].12H(2)O (), have been successfully produ…
We investigated fundamental parameters such as the Curie temperature, biaxial elastic modulus, and thermal expansion coefficient of (K,Na)NbO 3 (KNN) films on Pt/Ti/SiO 2 /Si substrates. From the temperature dependence of the dielectric constant of the KNN films, their Curie temperature was approximately 360 °C; this…
High-quality epitaxial ZnO thin films were grown by an ultrasonic spray-assisted mist chemical vapor deposition (CVD) on a-plane sapphire substrates with ZnO buffer layers. The ZnO thin films were grown with c -axis orientation without notable rotational domains. Surface morphologies and electrical properties were mar…
p -type conduction in hexagonal boron nitride (hBN) films was achieved by beryllium implantation and subsequent rapid thermal annealing treatment. The dependence of phase composition and electrical properties of hBN films on the implantation fluence and annealing was studied. A maximum resistivity reduction by six ord…
Our earlier studies have shown the in vitro and in vivo targeting of a generation 5 (G5) dendrimer-based multifunctional conjugate that contained folic acid (FA) as the targeting agent and methotrexate (MTX) as the chemotherapeutic drug. To clinically apply the synthesized G5-FA-MTX nanotherapeutic, it is important th…
Spin-crossover (SCO) compounds are a sort of bistable material whose electronic and magnetic properties can be tuned by external physical stimuli, such as heat, light, and pressure. The title SCO compound [Fe(pmea)(NCS)(2)] (1; pmea = bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine) undergoes spin transition in such a…
Polycrystalline La2NiMnO6 compounds were fabricated at different temperatures and their magnetic properties were investigated. Although the antiferromagnetic antisite disorder degree changes a little, the antiferromagnetic coupling intensity increases with increasing synthesized temperature. When La2NiMnO6 sample was…
The patterning of conducting polymer PEDOT:PSS, an excellent organic electrode material, with high resolution (50 nm, middle part of figure) on both rigid and flexible substrates by AFM nanoscratching (left part of figure) is demonstrated. The high density electrode array (108 elements cm−2) and small area electrode p…
A pair of mer-octahedral lanthanide chalcogenolate coordination complexes [(THF)(3)Ln(EC(6)F(5))(3) (Ln = Er, E = Se; Ln = Yb, E = S)] have been isolated and structurally characterized. Both compounds show geometry-dependent bond lengths, with the Ln-E bonds trans to the neutral donor tetrahydrofuran (THF) significant…
Resonant ultrasound spectroscopy has been used to characterize elastic softening and anelastic dissipation processes associated with the Pm3m <--> R3c transition in single crystal and ceramic samples of LaAlO(3). Softening of the cubic structure ahead of the transition point is not accompanied by an increase in dissip…
The presence of the (Gly-Xaa-Yaa)(n) open reading frames in different bacteria predicts the existence of an expanded family of collagen-like proteins. To further explore the triple-helix motif and stabilization mechanisms in the absence of hydroxyproline (Hyp), predicted novel collagen-like proteins from Gram-positive…
Abstract Zinc oxide (ZnO) pencil‐head‐like (PHL) microprisms were synthesized by a hydrothermal route using a zinc (Zn) plate as a source and substrate. The structural analysis confirmed the formation of ZnO with hexagonal wurtzite phase on the hexagonal Zn substrate and the growth of the ZnO microparticles along the…
Nanocarriers with multilayer core-shell architecture were prepared by coating a superparamagnetic Fe(3)O(4) core with a triblock copolymer. The first block of the copolymer formed the biocompatible outermost shell of the nanocarrier. The second block that contains amino groups and hydrophobic moiety formed the inner s…
In this Communication we report a single step reductive polymerization of ProDOT derivatives which is compatible with functional side chains and is amenable for scale-up.
We fabricated light-emitting hybrid p-n junction devices using low temperature deposited ZnO and organic films, in which the ZnO and the organic films served as the n- and p-type component, respectively. The devices have a rectification factor as high as ∼103 and a current density greater than 2 A/cm2. Electroluminesc…
The first stable structure of silver(I) cluster cations [Ag(8)(mu(4)-H){Se(2)P(OR)(2)}(6)](+) [R = (i)Pr, 1; Et, 2] containing Ag(I)-hydride bridges (Ag-mu-H-Ag) in T symmetry was reported. The clusters having an interstitial hydride were composed of an octanuclear silver core in tetracapped tetrahedral geometry, whic…
The impact of drying on the ultrastructure of fresh wood was studied by deuterium exchange coupled with FT-IR analysis. This fundamental investigation demonstrated that water removal leads to irreversible alterations of the wood structure, namely, supramolecular rearrangements between wood polymers. The deuteration of…
The spectroscopic characteristics of Er3+-doped lead phosphate glasses have been investigated, and Judd?Ofelt analysis was used to evaluate the effect of increasing the Er3+ content on the glass matrices. The intensity-dependent Judd?Ofelt parameters, ?(4) and ?(6), remained constant while ?(2) decreased. The concentr…
Silver nanocrystals (Ag NCs) hold promising antibiotic and antiviral properties in biological systems. The biodistribution of silvernanostructures injected into animals in vivo is currently unknown, remaining as a fundamental issue for potential therapeutic applications. Here, we injected Ag NCs capped with bovine ser…