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A functional monomer to synthesize sulfonated poly(ether ether ketone) with sulfonic acid group in the pendant side chain

P. Krishnan、Suresh G. Advani、Ajay K. Prasad2011-09-09Journal of Applied Polymer Science

Abstract A functional monomer which enables the synthesis of sulfonated poly(ether ether ketone) (SPEEK) polymer with the sulfonic acid group in the pendant side chain has been successfully developed. 1, 3‐propane sultone was used as the model compound to introduce the side chain moiety in the monomer. The above sulfo…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsSynthesis and properties of polymers

Banana fiber-reinforced polypropylene nanocomposites: Effect of fiber treatment on mechanical, thermal, and dynamic-mechanical properties

Manoranjan Biswal、Smita Mohanty、Sanjay K. Nayak2011-09-09Journal of Thermoplastic Composite Materials

Banana fiber-reinforced nanocomposites were fabricated by melt mixing in a twin-screw extruder followed by compression molding in this study. Maleic anhydride polypropylene copolymer (MA-g-PP) was used as a compatibilizer to increase the compatibility between the PP matrix, clay, and banana fiber to enhance exfoliatio…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesPolymer Nanocomposite Synthesis and Irradiation

Single mode phonon energy transmission in functionalized carbon nanotubes

Jonghoon Lee、Vikas Varshney、Ajit K. Roy 等 4 位作者2011-09-09The Journal of Chemical Physics

Although the carbon nanotube (CNT) features superior thermal properties in its pristine form, the chemical functionalization often required for many applications of CNT inevitably degrades the structural integrity and affects the transport of energy carriers. In this article, the effect of the side wall functionalizat…

Carbon Nanotubes in CompositesThermal properties of materialsMechanical and Optical Resonators

Spherulitic Growth Rate of Blends of Polyhydroxybutyrate (PHB) with Oligomeric Atactic PHB-diol

Safaa H. El‐Taweel、B. Stoll2011-09-09Journal of Macromolecular Science Part B

Spherulitic growth rates of blends of polyhydroxybutyrate (PHB) with oligomers of atactic R,S-PHB-OH (Mn = 610, 910, and 2670 g/mol), as well as atactic R,S-PHB (Mn = 30 000 g/mol), were investigated by polarized light optical microscopy in the range from 50°C to 110°C. The temperature of maximum growth rate of PHB sp…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

High Pressure and High Temperature Generation Using Sintered Diamond Anvils

Wataru Utsumi、Takehiko Yagi、Kurt Leinenweber 等 5 位作者2011-09-09Geophysical monograph

Large size sintered diamond anvils were used in the multi-anvil apparatus in order to raise the attainable pressure. Pressure generation up to 18 GPa in the DIA apparatus (truncation 3 mm), up to 30 GPa in a Drickamer anvil cell (anvil top 3 mmϕ), and more than 23 GPa in a 6–8 two stage system (truncation 2 mm) were a…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Isotropic properties of the photonic band gap in quasicrystals with low-index contrast

T. Priya Rose、Emiliano Di Gennaro、Giancarlo Abbate 等 4 位作者2011-09-09Physical Review B

We report on the formation and development of the photonic band gap in two-dimensional 8-, 10-, and 12-fold symmetry quasicrystalline lattices of low-index contrast. Finite-size structures made of dielectric cylindrical rods were studied and measured in the microwave region, and their properties were compared with a c…

Photonic Crystals and ApplicationsOptical Coatings and GratingsDiatoms and Algae Research

Defect Mechanisms for the Solid State Reduction of Olivine

J. N. Boland、A. Duba2011-09-09Geophysical monograph

The development of the microstructures in experimentally reduced single crystals of San Carlos olivine (Fo92) has been studied by optical and electron microscopy. At 1400°C in a reducing atmosphere of nearly pure CO, reduction proceeds by propagation of a reaction zone from the surface to the center of the crystals. T…

Metal Extraction and BioleachingCrystallization and Solubility StudiesMineral Processing and Grinding

Raman Spectroscopy of High Pressure MgSiO3Phases Synthesized in a CO2Laser Heated Diamond Anvil Cell: Perovskite and Clinopyroxene

A. Chopelas、R. Boehler2011-09-09Geophysical monograph

Both MgSiO3 clinopyroxene and perovskite were synthesized in the diamond anvil cell from single crystal MgSiO3 orthoenstatite embedded in argon at 165 and 232 kbar, respectively, using the 10.6 μm radiation of a CO2 laser for heating. Raman spectra of MgSiO3 orthorhombic perovskite phase were exceptionally sharp, whic…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsCrystal Structures and Properties

Polycrystals of High-Pressure Phases of Mantle Minerals: Hot-Pressing and Characterization of Physical Properties

Gabriel D. Gwanmesia、Robert C. Liebermann2011-09-09Geophysical monograph

A large volume 2000-ton uniaxial split-sphere apparatus (USSA-2000) has been adapted to fabricate polycrystals of mantle minerals. By improving the gasket support and using NaCl as the pressure medium, a 14/7.5 MgO cell assembly with a telescopic graphite furnace to provide a low temperature gradient (<15°C/mm) and a…

Geological and Geochemical AnalysisAdvanced ceramic materials synthesisHigh-pressure geophysics and materials

Raman spectroscopy and lattice dynamics of MgSiO3-perovskite at high pressure

Russell J. Hemley、R. E. Cohen、Amir Yeganeh‐Haeri 等 6 位作者2011-09-09Geophysical monograph

Vibrational Raman spectra have been obtained for 50 to 100 μm single crystals of MgSiO3 perovskite in situ at high pressure. Seven bands were tracked as a function of pressure to 26 GPa using a diamond-anvil high-pressure cell with rare-gas pressure-transmitting media. The frequency shifts with pressure are positive,…

Ferroelectric and Piezoelectric MaterialsHigh-pressure geophysics and materialsCrystal Structures and Properties

Anisotropy in the Rheology of Hydrolytically Weakened Synthetic Quartz Crystals

M. F. Linker、S. H. Kirby2011-09-09Geophysical monograph

This chapter contains sections titled: Experimental Details Experimental Results Anisotropy in the Steady State Rheology of Synthetic Quartz Summary and Conclusions Appendices: Interpretation of the Creep Curves

Granular flow and fluidized bedsComposite Material MechanicsCrystallization and Solubility Studies

Post-Operational Treatment of Residual Na Coolant in EBR-II Using Carbonation

Raphael Steven、Jean-Paul Collin2011-09-09InTech eBooks

The Experimental Breeder Reactor Two (EBR-II) was an unmoderated, heterogeneous, sodium-cooled fast breeder reactor operated by Argonne National Laboratory -West, now part of the Idaho National Laboratory in southeastern Idaho, USA. It was a pool-type reactor. The reactor core, sodium fluid pumps, and intermediate hea…

Graphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Graft Polyrotaxanes: A New Class of Graft Copolymers with Mobile Graft Chains

Yasuhiro Kohsaka、Yasuhito Koyama、Toshikazu Takata2011-09-09Angewandte Chemie

Die Synthese und Struktur gepfropfter Polyrotaxane, einer neuen Copolymerklasse mit mobilen Seitenketten, wird beschrieben. Poly(tetrahydrofuran)-Ketten wurden an die Achse des Pseudo[2]rotaxans angebracht, um das entsprechende gepfropfte Polyrotaxan zu erhalten (siehe Bild). N-Acetylierung der Ammoniumgruppen führt z…

Advanced Polymer Synthesis and CharacterizationSupramolecular Chemistry and ComplexesDendrimers and Hyperbranched Polymers

Stopped-Flow Spectrophotometric Study of the Kinetics and Mechanism of CO2 Uptake by cis-[Cr(C2O4)(BaraNH2)(OH2)2]+ Cation and the Acid-Catalyzed Decomposition of cis-[Cr(C2O4)(BaraNH2)OCO2]− Anion in Aqueous Solution

Dagmara Jacewicz、Aleksandra Dąbrowska、Lech Chmurzyński2011-09-09Molecules

The kinetics of CO(2) uptake by the cis-[Cr(C(2)O(4))(BaraNH(2))(OH(2))(2)]+ complex cation and the acid hydrolysis of the cis-[Cr(C(2)O(4))(BaraNH(2))OCO(2)]- complex anion (where BaraNH(2) denotes methyl 3-amino-2,3-dideoxy-b-D-arabino-hexopyranoside) were studied using the stopped-flow technique. The reactions unde…

Metal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceIonic liquids properties and applications

Evaluation of fatigue properties of high-performance fibers based on fixed-point bending fatigue test

Guangming Cai、Xiaoguang Wang、Xianjun Shi 等 4 位作者2011-09-09Journal of Composite Materials

The main aim of this article is to introduce a bending fatigue testing apparatus and a new fatigue testing method, which can be used to characterize the bending fatigue behavior of flexible materials by setting the following parameters: pre-tension, bending angle, and bending frequency. The Kevlar 49, poly(p-phenylene…

Mechanical Behavior of CompositesTextile materials and evaluationsFiber-reinforced polymer composites

Amyloid fibril formation from crude protein mixtures

Shiva P. Rao、Susie J. Meade、Nigel I. Joyce 等 7 位作者2011-09-09Biotechnology Progress

Amyloid fibrils have potential as bionanomaterials. A bottleneck in their commercial use is the cost of the highly purified protein typically needed as a starting material. Thus, an understanding of the role of heterogeneity in the mixtures from which amyloid fibrils are formed may inform production of these structure…

Alzheimer's disease research and treatmentsProteins in Food SystemsSupramolecular Self-Assembly in Materials

Low Oxygen Concentrations Impair Tissue Development in Tissue-Engineered Cardiovascular Constructs

Marijke A. A. van Vlimmeren、Anita Driessen‐Mol、Cees W.J. Oomens 等 7 位作者2011-09-09Tissue Engineering Part A

Cardiovascular tissue engineering has shown considerable progress, but in vitro tissue conditioning to stimulate the development of a functional extracellular matrix still needs improvement. We investigated the environmental factor oxygen concentration for its potential to increase the amount of collagen and collagen…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Synthesis of an Antitumoral Diarylheptanoid Containing 1,3‐Diol Functionality

Shaomin Zhang、Yikang Wu2011-09-09Chinese Journal of Chemistry

Abstract A bioactive derivative of a natural diarylheptanoid containing a 1,3‐anti diol motif was synthesized with the oxygen‐carrying stereogenic centers taken from an enantiopure epoxy chiral building block derived from inexpensive and readily available D‐glucolactone.

Carbohydrate Chemistry and SynthesisPorphyrin and Phthalocyanine ChemistrySynthetic Organic Chemistry Methods

Reformer and Membrane Modules (RMM) for Methane Conversion Powered by a Nuclear Reactor

Mriganka De、Annarita Salladini、E. Palo 等 4 位作者2011-09-09InTech eBooks

In the last few years, significant developments in membrane science and the vision of process intensification by multifunctional reactors have stimulated the academic and industrial research focused on membrane reactor application to chemical processes (Mendes et al., 2010, Dittmeyer et al., 2001, Basile et al., 2005a…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis for Biomass Conversion

Arthonia anatolica sp. nov. (Arthoniaceae) on Aspicilia contorta subsp. hoffmanniana, a new lichenicolous species from Turkey

Mehmet Gökhan Halıcı、Mehmet Candan2011-09-09Mycotaxon

Arthonia anatolica sp. nov. is described on Aspicilia contorta subsp. hoffmanniana on calcareous rocks from central and eastern Turkey. The new species clearly differs from the other Arthonia species reported on Aspicilia sp. and most closely resembles Arthonia amylospora, a species known on Porpidia rugosa. The diffe…

Lichen and fungal ecologyDiatoms and Algae ResearchBotany and Plant Ecology Studies