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Ion-induced surface activation, chemical sputtering, and hydrogen release during plasma-assisted hydrocarbon film growth

C. Hopf、W. Jacob、Achim von Keudell2005-04-15Journal of Applied Physics

Synergisms between different species emerging from hydrocarbon plasmas can enhance the chemisorption of radicals at the surface of a growing film. It has been shown that the rate of CH3 chemisorption can be increased by a simultaneously incident flux of ions or H atoms; the latter species cause the formation of surfac…

Diamond and Carbon-based Materials ResearchPlasma Diagnostics and ApplicationsIon-surface interactions and analysis

The structure of disordered carbon solids studied using a hybrid reverse Monte Carlo algorithm

George Opletal、Timothy C. Petersen、Dougal G. McCulloch 等 5 位作者2005-04-15Journal of Physics Condensed Matter

A hybrid reverse Monte Carlo (HRMC) algorithm, which incorporates both experimental and energy based constraints, is applied to investigate the microstructure of two disordered carbons of vastly different densities and bonding. We have developed a novel liquid quench procedure which in combination with the HRMC algori…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchMachine Learning in Materials Science

Thermally Gated Liposomes

Wen‐Hua Chen、Steven L. Regen2005-04-15Journal of the American Chemical Society

The combined use of a pore-forming amphiphile, 1 (derived from lysine, cholic acid, and spermine), and thermally sensitive liposomes (made from 1,2-dipalmitoyl-sn-glycero-3-phosphocholine, DPPC) to create "thermally gated liposomes" (TGLs) has been demonstrated. Thus, at temperatures that lie above the gel to liquid-c…

Lipid Membrane Structure and BehaviorSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Short pitch cholesteric electro-optical device stabilized by nonuniform polymer network

Sang Hwa Kim、Liang‐Chy Chien、L. Komitov2005-04-15Applied Physics Letters

We have developed a method for stabilization of the uniform lying helix (ULH) texture of short pitch cholesterics in an electro-optical device, based on the flexoelectro-optic effect in such a texture. By using a small concentration of photoreactive liquid crystal monomer (less than 5wt.%) and selecting the illuminati…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsForce Microscopy Techniques and Applications

Resonance Raman scattering from phonon overtones in double-wall carbon nanotubes

R. Pfeiffer、H. Kuzmany、Ferenc Simon 等 5 位作者2005-04-15Physical Review B

The resonance behavior and the dispersion of the ${\mathrm{G}}^{\ensuremath{'}}$ line in double-wall carbon nanotubes were investigated by multifrequency Raman scattering. Using a large number of laser lines for excitation, the dispersion for the response from the inner tubes and from the outer tubes was found to be 8…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Opposite Goos–Hänchen shifts for transverse-electric and transverse-magnetic beams at the interface associated with single-negative materials

Xiao‐Long Hu、Yidong Huang、Wei Zhang 等 5 位作者2005-04-15Optics Letters

Goos-Hänchen shifts are investigated when total reflection occurs at the interfaces associated with single-negative materials (SNMs). A general rule for judging the direction of the Goos-Hänchen lateral shift concerning lossless media is obtained: Whether the lateral shift is positive or negative depends on the sign o…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsQuantum optics and atomic interactions

Crystal structure and atomic arrangement of the metastable Ge2Sb2Te5 thin films deposited on SiO2∕Si substrates by sputtering method

Y. J. Park、Kyung Eun Lee、Min Soo Youm 等 5 位作者2005-04-15Journal of Applied Physics

The Ge2Sb2Te5 thin films deposited by a sputtering method on SiO2∕Si substrates were annealed through a rapid thermal annealing process and performed a high-resolution transmission electron microscopy study in order to investigate the atomic arrangement of the metastable Ge2Sb2Te5. The metastable rocksalt structure ha…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Design of DOEs for wavelength division and focusing

Leonid L. Doskolovich、Nikolay L. Kazanskiy、В. А. Сойфер 等 5 位作者2005-04-15Journal of Modern Optics

We propose a technique for calculating the color separation gratings aimed at separating plane light beams of different wavelengths into different diffraction orders. The technique is based on a special-type optimization criterion. With this criterion, the problem of calculating the piecewise-constant grating profile…

Photonic Crystals and ApplicationsAdvanced optical system designOptical Coatings and Gratings

In Situ Spatial and Time-Resolved Studies of Electrochemical Reactions by Scanning Transmission X-ray Microscopy

Daniel Guay、Jacob Stewart-Ornstein、Xuerong Zhang 等 4 位作者2005-04-15Analytical Chemistry

The first in situ measurements with scanning transmission X-ray microscopy (STXM) of an active electrochemical cell are reported. An electrochemical wet cell, consisting of an electrodeposited polyaniline thin film on a thin Au film covered by an overlayer of 1 M HCl solution sitting between two X-ray transparent sili…

Conducting polymers and applicationsForce Microscopy Techniques and ApplicationsElectrochemical Analysis and Applications

High-energy photoemission in silver: resolving d and sp contributions in valence band spectra

G. Panaccione、G. Cautero、Marco Cautero 等 14 位作者2005-04-15Journal of Physics Condensed Matter

We present high-resolution valence band and core level spectra of silver for photoelectron kinetic energies up to 8 keV. At these kinetic energies we estimate a surface contribution of less than 3%. Taking advantage of the favourable sp/d relative cross-sections, a comparison with the calculated density of states is p…

X-ray Spectroscopy and Fluorescence AnalysisMachine Learning in Materials ScienceElectron and X-Ray Spectroscopy Techniques

Thin-film spatial filters

Iván Moreno、J. Jesus Araiza、Maximino Avendaño‐Alejo2005-04-15Optics Letters

A thin-film optical filter used as a one-dimensional spatial filter is presented, and its design is briefly examined. The filter consists of a stack of quarter-wave dielectric layers upon a right-angle prism that selectively cancel a reflected or transmitted plane-wave front for various angles of incidence. Transmitta…

Liquid Crystal Research AdvancementsOptical Coatings and GratingsOptical Polarization and Ellipsometry

CVD Growth of N-Doped Carbon Nanotubes on Silicon Substrates and Its Mechanism

Maoshuai He、Shuang Zhou、Jin Zhang 等 5 位作者2005-04-15The Journal of Physical Chemistry B

In the present study, we report the chemical vapor deposition (CVD) of nitrogen-doped (N-doped) aligned carbon nanotubes on a silicon (Si) substrate using ferrocene (Fe(C5H5)2) as catalyst and acetonitrile (CH3CN) as the carbon source. The effect of experimental conditions such as temperature, gaseous environment, and…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Nonlinear Optical Crystal YxLayScz(BO3)4 (x + y + z = 4)

Ning Ye、Jennifer Stone‐Sundberg、Michael A. Hruschka 等 6 位作者2005-04-15Chemistry of Materials

The new nonlinear optical crystal Y x La y Sc z (BO 3 ) 4 ( x + y + z = 4) has been discovered. Phase boundaries have been established in the determination of the x, y, z composition parameters that define the existence region of the trigonal huntite-type structure. From single-crystal X-ray diffraction measurements,…

High-pressure geophysics and materialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

A practical extension of the 3ω method to multilayer structures

Brandon Olson、Samuel Graham、Kuan Chen2005-04-15Review of Scientific Instruments

An improved data reduction method is used to extend the popular 3ω method to general layered geometries. This approach utilizes an unapproximated analytical solution, cast in terms of thermal impedance, to simultaneously measure thermal conductivity, thermal capacity, conductivity anisotropy, and interlayer contact re…

Advanced ceramic materials synthesisThermal properties of materialsComposite Material Mechanics

Size- and shape-controlled synthesis of colloidal gold through autoreduction of the auric cation by poly(ethylene oxide)–poly(propylene oxide) block copolymers in aqueous solutions at ambient conditions

Toshio Sakai、Paschalis Alexandridis2005-04-15Nanotechnology

Gold nanoparticles with an average diameter in the range 5-20 nm have been synthesized from hydrogen tetrachloroaureate (III) hydrate (HAuCl(4)·3H(2)O) in air-saturated aqueous PEO-PPO-PEO block copolymer solutions at ambient temperature in the absence of any other reducing agent (PEO: poly(ethylene oxide), PPO: poly(…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsLaser-Ablation Synthesis of Nanoparticles

Conformal nanocoating of zirconia nanoparticles by atomic layer deposition in a fluidized bed reactor

Luis F. Hakim、Steven M. George、Alan W. Weimer2005-04-15Nanotechnology

Primary zirconia nanoparticles were conformally coated with alumina ultrathin films using atomic layer deposition (ALD) in a fluidized bed reactor. Alternating doses of trimethylaluminium and water vapour were performed to deposit Al(2)O(3) nanolayers on the surface of 26 nm zirconia nanoparticles. Transmission Fourie…

Catalytic Processes in Materials ScienceCoagulation and Flocculation StudiesParticle Dynamics in Fluid Flows

Direct correlation between adsorption‐induced changes in protein structure and platelet adhesion

Donna M. Hylton、Shalaby W. Shalaby、Robert A. Latour2005-04-15Journal of Biomedical Materials Research Part A

It is widely recognized that adsorbed proteins on biomaterial surfaces tend to initiate thrombus formation, although the specific mechanisms involved are still not well understood. In attempts to decrease the conformational change of adsorbed proteins, surface treatments that reduce surface hydrophobicity have been co…

Polymer Surface Interaction StudiesProtein purification and stabilityBlood properties and coagulation

The Electrochemical Behavior of Keggin Polyoxometalate Modified by Tricyclic, Aromatic Entity

Zhangang Han、Yu‐Long Zhao、Jun Peng 等 6 位作者2005-04-15Electroanalysis

Abstract The inorganic‐organic hybrid polyoxometalates (POMs), (pbpy) 4 H[PMo 12 O 40 (VO)] ( 1 ) and (pbpy) 4 H 4 [SiMo 12 O 40 ] ( 2 ) (pbpy=5‐phenyl‐2‐(4‐pyridinyl)pyridine), have been synthesized and were, respectively, used as a solid bulkmodifier to fabricate a three‐dimensional bulk‐modified carbon paste electr…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Cholesteric liquid crystal laser with wide tuning capability

Tsung‐Hsien Lin、Yi‐Jan Emery Chen、Chun-Hui Wu 等 6 位作者2005-04-15Applied Physics Letters

This letter examines a planar cholesteric cell (CLC) doped with two collocated laser dyes as a one-dimensional photonic crystal. Adding phototunable chiral material (AzoB) allows the CLC photonic crystal to be lased at the band edges of the photonic band gap with a tuning range of over 100nm. Tuning is performed by ir…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPlant Reproductive Biology

Versatile Visualization of Individual Single-Walled Carbon Nanotubes with Near-Infrared Fluorescence Microscopy

Dmitri Tsyboulski、Sergei M. Bachilo、R. Bruce Weisman2005-04-15Nano Letters

Fluorescence microscopy in the near-infrared between 950 and 1600 nm has been developed as a novel method to image and study single-walled carbon nanotubes (SWNTs) in a variety of environments. Intrinsic photoluminescence of disaggregated pristine SWNTs was excited by a diode laser and detected with a two-dimensional…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsNanotechnology research and applications