Materials Literature
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In the Ge on Si model heteroepitaxial system, metal patterns on the silicon surface provide unprecedented control over the morphology of highly ordered Ge islands. Island shape including nanorods and truncated pyramids is set by the metal species and substrate orientation. Analysis of island faceting elucidates the pr…
The interaction of cobalt(II) tetraphenylporphyrin (CoTPP) and cobalt(II) tetrakis-(3,5-di-tert-butylphenyl)porphyrin (CoTTBPP) with a Ag(111) surface has been investigated with photoelectron spectroscopy (XPS/UPS). It is demonstrated that these adsorbed metal complexes are excellent model systems for studying the ele…
To evaluate the influence of thickness on structural, electrical, and optical properties of ZnO:Al (AZO) films, a set of polycrystalline AZO samples with different thicknesses were deposited by pulsed laser deposition. X-ray diffraction measurement shows that the crystal quality of AZO films was improved with the incr…
Medium and high voltage power cables are widely used in the electrical industry with substantial growth over the last 20-30 years ago, particular in the use of XLPE insulated systems. Ageing of the cable insulation is becoming an increasing problem that requires development of reliable methods for on-line condition as…
The dynamic adsorption/desorption behavior of volatile organic compounds (VOCs) such as toluene (C7H8) and benzene (C6H6) was evaluated for three kinds of mesoporous silicas of SBA-15, all having almost the same mesopore size of ca. 5.7 nm, and a MCM-41 silica with a smaller pore size of 2.1 nm using a continuous thre…
The coexistence of the magnetic and the electrical properties in lanthanum (La)-modified bismuth ferrite (Bi1−xLaxFeO3, x=0.05, 0.1, 0.15, and 0.2) ceramics was studied and compared with those of bismuth ferrite (BiFeO3). The presence of a small secondary phase of BiFeO3 (arises due to excess Bi2O3) was removed on La…
The Sun provides approximately 100,000 terawatts to the Earth which is about 10000 times more than the present rate of the world's present energy consumption. Photovoltaic cells are being increasingly used to tap into this huge resource and will play a key role in future sustainable energy systems. So far, solid-state…
The photoluminescence of mercaptoacetic acid (MAA)-capped CdSe/ZnSe/ZnS semiconductor nanocrystal quantum dots (QDs) in SKOV-3 human ovarian cancer cells is pH-dependent, suggesting applications in which QDs serve as intracellular pH sensors. In both fixed and living cells the fluorescence intensity of intracellular M…
Abstract Hierarchical carbon materials with functional groups residing at the surface are prepared for the first time by using nanostructured silica materials as templates in combination with hydrothermal carbonization at mild temperatures (180 °C). Different carbon morphologies (e.g., macroporous casts, hollow sphere…
A comparative study of antimicrobial activity is done using three different electrospun nanofibers namely-CA, PAN, and PVC used as control and with various amounts of AgNO(3) being treated with UV-irradiation leading to the enhancement of silver nanoparticles. DMF is used as the common solvent which helps to undergo s…
Co-electrospinning is ideally suited for fabricating continuous fibers encasing materials within a polymer sleeve, but requires relatively complex coannular nozzles. A single-nozzle co-electrospinning technique is demonstrated using blends of poly(methyl methacrylate) (PMMA)/polyacrylonitrile (PAN) solutions in dimeth…
Plasmon-resonant gold nanorods, which have large absorption cross sections at near-infrared frequencies, are excellent candidates as multifunctional agents for image-guided therapies based on localized hyperthermia. The controlled modification of the surface chemistry of the nanorods is of critical importance, as issu…
Magnetic nanoparticles with appropriate surface coatings are increasingly being used clinically for various biomedical applications, such as magnetic resonance imaging, hyperthermia, drug delivery, tissue repair, cell and tissue targeting and transfection. This is because of the nontoxicity and biocompatibility demand…
Fining and homogenization of melts during batch melting is closely related to the redox reaction of polyvalent element M (M:Sb, As etc), M (x+n)+ +n/2O 2? → M x+ +n/4O₂. In this study, square wave voltammetry (SWV) measurements were performed to examine the redox behavior of an antimony ion in cathode ray tube (CRT) g…
Miscibility behavior of blends of isotactic and syndiotactic poly(methyl methacrylate) (iPMMA and sPMMA) was investigated as a function of annealing temperature and molecular weight of the iPMMA component. Annealing experiments clearly indicate that for the high molecular weight iPMMA sample formation of stereocomplex…
In the framework of all-electron density functional theory, we present a comparative study of the pure carbon and BC 3 compound nanotubes containing different kinds of topological defects (seven-, eight- and nine-membered rings) under uniaxial tensions. The formation energies of the topological defects for pure carbon…
The objective of this work was to study the transfer of four aroma compounds (ethyl butyrate, ethyl hexanoate, cis-3-hexenol, and benzaldehyde) from a solid and complex-flavored food matrix (sponge cake) toward and through packaging films placed in indirect contact during storage in accelerated aging conditions (38 de…
Abstract The aim of this work is to evaluate the behaviour of bronze in archaeological soil by gravimetric study, electrochemical research and analytic survey. Archaeological soil samples were collected from Jama that date back to the second Punic war. Mineralogical, micro‐structural, micro‐morphological and chemical…
Ferromagnetic material–carbon nanotube composites are promising magnetic nanowires that have recently been prepared, with many possible applications. In this paper, using carbon nanotubes as a nucleate template, one-dimensional carbon nanotube–FexCy nanocrystal composites were successfully synthesized by the chemical…
The existence of sitting-atop metalloporphyrin complexes, the proposed intermediates in the metalation of free-base porphyrins, has been explored via the microscopic reverse reaction, i.e., protonation of metalloporphyrins with a strong acid. The reaction of M(Tp-TP) (M = Zn, Cu, Ni; Tp-TP = dianion of tetra-p-tolylpo…