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Chemically oxidized polypyrrole: Influence of the experimental conditions on its electrical conductivity and morphology

X. Chen、J‐P. Issi、Jacques Devaux 等 4 位作者1995-04-01Polymer Engineering and Science

Abstract The effect of synthesis conditions on the electrical conductivity and the morphology of a chemically oxidized polypyrrole was investigated. It was found that the electrical conductivity of polypyrrole was strongly dependent on the pyrrole/FeCl 3 ratio, which controls the redox potential of the reaction medium…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Deuteron NMR study of liquid crystals confined in aerogel matrices

Aleksander Zidanšek、Samo Kralj、G. Lahajnar 等 4 位作者1995-04-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The temperature dependence of the deuteron NMR line shape was studied in pentylcyanobiphenyl (5CB) and octylcyanobiphenyl (8CB) liquid crystals confined in porous silica aerogel matrices with two different pore size distributions. The average pore sizes 〈${\mathit{R}}_{\mathit{c}}$〉 of the two aerogel matrices were 0.…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesNonlinear Dynamics and Pattern Formation

An Efficient, Box Shape Independent Non-Bonded Force and Virial Algorithm for Molecular Dynamics

Henk Bekker、E. J. Dijkstra、Mkr Renardus 等 4 位作者1995-04-01Molecular Simulation

A notation is introduced and used to transform a conventional specification of the non-bonded force and virial algorithm in the case of periodic boundary conditions into an alternative specification. The implementation of the transformed specification is simpler and typically a factor of 1.5 faster than a conventional…

Supramolecular Chemistry and ComplexesMass Spectrometry Techniques and ApplicationsMachine Learning in Materials Science

Conformational Control of Intramolecular Hydrogen Bonding in Heme Models: Maximal CoII-O2 Binding in a C-Clamp Porphyrin

Chi K. Chang、Ying Liang、Gladys Avilés 等 4 位作者1995-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConformational Control of Intramolecular Hydrogen Bonding in Heme Models: Maximal CoII-O2 Binding in a C-Clamp PorphyrinC. K. Chang, Ying Liang, Gladys Aviles, and Shie-Ming PengCite this: J. Am. Chem. Soc. 1995, 117, 14, 4191–4192Publication Date (Print):April 1, 1995Public…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Raman Spectra of Poly(2,3-R,R-thieno[3,4-b]pyrazine). A New Low-Band-Gap Polymer

Johann Kastner、H. Kuzmany、Dániel Végh 等 6 位作者1995-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRaman Spectra of Poly(2,3-R,R-thieno[3,4-b]pyrazine). A New Low-Band-Gap PolymerJ. Kastner, H. Kuzmany, D. Vegh, M. Landl, L. Cuff, and M. KerteszCite this: Macromolecules 1995, 28, 8, 2922–2929Publication Date (Print):April 1, 1995Publication History Published online1 May 2…

Synthesis and biological activitySynthesis and properties of polymersSynthesis and Characterization of Heterocyclic Compounds

In vitroAntimyxovirus and Anti-Human Immunodeficiency Virus Activities of Polyoxometalates

Shirô Shigeta、S Mori、Junko Watanabe 等 7 位作者1995-04-01Antiviral chemistry & chemotherapy

Polyoxometalates have been shown to inhibit the replication of retro-, toga-, paramyxo- and herpesviruses. The primary mechanism of the anti-human immunodeficiency virus type 1 (HIV-1) action of polyoxometalates seems to be inhibition of binding of virus to cells and inhibition of syncytium formation. Since myxoviruse…

HIV Research and TreatmentPolyoxometalates: Synthesis and ApplicationsSulfur-Based Synthesis Techniques

Fracture Toughness of Al 2 O 3 ‐Particle‐Dispersed Y 2 O 3 ‐Partially Stabilized Zirconia

Jing‐Feng Li、Ryuzo Watanabe1995-04-01Journal of the American Ceramic Society

The fracture toughness of 3 mol% Y 2 O 3 ‐ZrO 2 (3Y‐PSZ) composites containing 10–30 vol% Al 2 O 3 with different particle sizes was investigated. It was found that Al 2 O 3 dispersion of up to 30 vol% increased the fracture toughness by 17% to 30%, and the toughness increase was more remarkable in the composite dispe…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

The `Seed-Skewness' Method for Integration of Peaks on Imaging Plates

Robert Bolotovsky、Melanie White、A. Darovsky 等 4 位作者1995-04-01Journal of Applied Crystallography

A new method of area-detector peak integration based on the statistical analysis of pixel intensities is described. The presence of the peak in the integration box causes the skewness of the pixel intensity distribution to increase compared to the skewness of the noise distribution. After the pixel intensities have be…

Advanced Electron Microscopy Techniques and ApplicationsAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Microscopic dynamics in liquid lithium

Alessandro Torcini、U. Balucani、P.H.K. de Jong 等 4 位作者1995-04-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

A detailed analysis of the dynamic properties of liquid lithium at three distinct thermodynamic points has been performed by computer simulation. The reliability of the adopted potential model is supported by a comparison with neutron- and x-ray scattering data. Several dynamical properties (both single-particle and c…

Material Dynamics and PropertiesTheoretical and Computational PhysicsThermodynamic and Structural Properties of Metals and Alloys

Application of statistical experimental strategies to the process optimization of waterborne polyurethane

Chien‐Hsin Yang、Shih‐Min Lin、Ten‐Chin Wen1995-04-01Polymer Engineering and Science

Abstract A modified acetone process for the preparation of aqueous polyurethane (PU) dispersion is investigated. PU dispersions were prepared by polyaddition of isophorone diisocyanate (IPDI) to poly(tetramethylene ether glycol) (PTMG) and dimethylolpropionic acid (DMPA), followed by neutralization of pendant COOH gro…

Asphalt Pavement Performance EvaluationPolymer composites and self-healingInfrastructure Maintenance and Monitoring

Electronic transport of quasicrystals with random phason strain: The two-dimensional Penrose lattice

Susumu Yamamoto、Takeo Fujiwara1995-04-01Physical review. B, Condensed matter

The electronic density of states, eigenstates, length dependence, and Fermi-energy dependence of the dc conductance in the two-dimensional Penrose lattice are calculated by using an exact diagonalization, Landauer formula and the forced oscillator method in finite size, zero-temperature systems with and without random…

Rare-earth and actinide compoundsQuasicrystal Structures and PropertiesMineralogy and Gemology Studies

Amphiphilic Networks. 9. Surface Characterization

Dongkyu Park、B. Keszler、Vassilios Galiatsatos 等 5 位作者1995-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAmphiphilic Networks. 9. Surface CharacterizationDongkyu Park, Balazs Keszler, Vassilios Galiatsatos, Joseph P. Kennedy, and Buddy D. RatnerCite this: Macromolecules 1995, 28, 8, 2595–2601Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Pub…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresAdvanced Biosensing Techniques and Applications

Intrinsic magnetic properties ofRFe10Mo2compounds (R=Y, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, or Tm)

X.C. Kou、R. Größinger、G. Wiesinger 等 7 位作者1995-04-01Physical review. B, Condensed matter

A systematic investigation of the intrinsic magnetic properties of R${\mathrm{Fe}}_{10}$${\mathrm{Mo}}_{2}$ compounds (with R=Y, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, and Tm) has been performed by means of ac susceptibility measurements, singular-point-detection techniques, and magnetization measurements. Spin reorientation…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Properties of n-type tetrahedral amorphous carbon (ta-C)/p-type crystalline silicon heterojunction diodes

V.S. Veerasamy、G.A.J. Amaratunga、J.S. Park 等 5 位作者1995-04-01IEEE Transactions on Electron Devices

Heterojunction diodes fabricated by filtered cathodic vacuum arc (FCVA) deposition of n-type (nitrogen-doped) tetrahedral amorphous carbon (ta-C) on p-type crystalline silicon are analyzed in terms of their electronic and photoresponse properties. The thin ta-C films are deposited at room temperature allowing the read…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchVacuum and Plasma Arcs

Evaluation of Bridging Parameters in Aluminas from R ‐Curves by Use of the Fracture Mechanical Weight Function

T. Fett、D. Münz、G. Thun 等 4 位作者1995-04-01Journal of the American Ceramic Society

Coarse‐grained Al 2 O 3 shows an R ‐curve behavior which is characterized by an increase in crack growth resistance with increasing crack extension. In case of alumina, this effect is caused by crack‐border interactions in the wake of the advancing crack. In the first part of the paper, the weight function method for…

Advanced ceramic materials synthesisNumerical methods in engineeringHigh-Velocity Impact and Material Behavior

Changes in Peroxide Melt-Modified Poly(L-lactide)

Anders Soedergaard、Maria Niemi、Johan‐Fredrik Selin 等 4 位作者1995-04-01Industrial & Engineering Chemistry Research

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChanges in Peroxide Melt-Modified Poly(L-lactide)Anders Soedergaard, Maria Niemi, Johan-Fredrik Selin, and Jan H. NaesmanCite this: Ind. Eng. Chem. Res. 1995, 34, 4, 1203–1207Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissu…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesCollagen: Extraction and Characterization

Synthesis, Characterization, and X-ray Study of a Heteroleptic Samarium(III) Porphyrin Double Decker Complex

Georgios A. Spyroulias、Athanassios G. Coutsolelos、Catherine P. Raptopoulou 等 4 位作者1995-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, Characterization, and X-ray Study of a Heteroleptic Samarium(III) Porphyrin Double Decker ComplexG. A. Spyroulias, A. G. Coutsolelos, C. P. Raptopoulou, and A. TerzisCite this: Inorg. Chem. 1995, 34, 9, 2476–2479Publication Date (Print):April 1, 1995Publication Hi…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Synthesis and pyrolysis of liquid organometallic precursors for advanced Si‐Ti‐C‐N composites

Jörg Hapke、Günter Ziegler1995-04-01Advanced Materials

Single‐source precursors for hybrid nano‐scaled SiC/Si 3 N 4 ‐TiC/TiN composites are reported. These precursors avoid the segregation of Ti and Si during pyrolysis and other probems associated with mixtures, blends, or slurries of precursors. They are liquids, oxygen‐free (important due to the detrimental effects of o…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsAdvanced materials and composites

FORMATION OF PROTEIN‐BOUND 3,4‐DIHYDROXYPHENYLALANINE IN COLLAGEN TYPES I AND IV EXPOSED TO ULTRAVIOLET LIGHT

Yoji Kato、Takashi Nishikawa、Shunrô Kawakishi1995-04-01Photochemistry and Photobiology

Collagen was exposed to an ultraviolet (UV) lamp that emitted predominantly in the UVB range. The cross-linking of collagen type I and type IV by UV irradiation was observed. Amino acid analyses revealed that Tyr residues in both collagen types I and IV were decreased by irradiation. In collagen type IV, losses of His…

biodegradable polymer synthesis and propertiesMarine Biology and Environmental ChemistryCollagen: Extraction and Characterization

Identification and surface structure of crystalline cellulose studied by atomic force microscopy

Lauri Kuutti、Jouko Peltonen、Jaakko Pere 等 4 位作者1995-04-01Journal of Microscopy

Summary A combination of molecular modelling and atomic force microscopy (AFM) techniques was used to study the surface structure of crystalline cellulose. Two‐dimensional Fourier analysis of the AFM raw data gave crystal parameters as well as a highly filtered inverse‐transformed image. Molecular modelling was used t…

Advanced Cellulose Research StudiesForce Microscopy Techniques and ApplicationsAdvanced Surface Polishing Techniques