Materials Literature
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We report the interface structure and the initial microstructure of TaN films, prepared by using the atomic layer deposition (ALD) method. We prepared 3-, 5-, 10-, 20-, 30-, and 50-cycled films to reveal the physical morphology of the initial growth. Since the ALD growth strongly depends on the initial surface state a…
We derived the relation between the time position tm, at which the maximum of the difference between the magnetic induction at the sample centre and the induction of the applied magnetic field appears, and the time constant τ of superconducting cables or normal metals. This enables the determination of the time consta…
Since the 1980s, different devices based on superelastic alloys have been developed to fulfill orthodontic applications. Particularly in the last decades several researches have been carried out to evaluate the mechanical behavior of Ni-Ti alloys, including their tensile, torsion and fatigue properties. However, studi…
An unsymmetrical trinickel metal complex, [Ni3(dpa)4(4-sb)(H2O)]×3H2O (1), where dpa is a 2,2’-dipyridylamine anion and 4-sb is 4-sulfobenzoate dianion, was synthesized and characterized by X-ray crystallography, IR, elemental analysis, fluorescence, and cyclic voltammetry. The molecular structure of 1 is a cluster wi…
A novel approach in target specific molecular prototype drug delivery system concerns the attempt to employ radical affording substances (RAS) or radical quenching substances (RQS) as prodrugs able to produce irreversible damage on the desired target and therefore to stimulate cellular apoptosis. However, radical spec…
The synthesis and fundamental spectroscopic properties of eight hemicyanine (HC) dyes are presented. The dyes were prepared by the condensation of N‐methyl‐5,6,7,8‐tetrahydroisoquinolinium iodide with p‐(N,N‐dialkylamino)benzaldehydes. The compounds were characterised by nuclear magnetic resonance spectroscopy and the…
The solid complex Tb(III)-bathophenanthroline (Bphen) was synthesized and characterized by elemental analysis, IR spectra, and thermalanalysis. The formation of binary and ternary complexes of Tb(III) with N -acetylamino acids ( N -acetylaspartic acid, N -acetylhistidine, and N -acetylhistamine), and Bphen or anthrace…
Glutathione peroxidase (GPx) is a key enzyme of cellular detoxification systems that defend cells against reactive oxygen species. It can be divided into selenium-dependent GPx (Se-GPx) and selenium-independent GPx (non-Se-GPx) subfamilies. In this study, the full-length cDNA of a non-Se-GPx was identified from Veneru…
Nanoscale interfaces that form between two immiscible liquids can be harnessed to create patterned nanoarray structures. Pattern formation is achieved with nanodrop effusion of an uncured prepolymer of polydimethylsiloxane by mechanically compressing the wrinkle-patterned mold, followed by UV-assisted molding of the n…
A new CaCu 5 related antimonide, CePt 5 Sb, has been identified. This ternary compound undergoes a structural phase transition at about 80 K according to room- and low-temperature X-ray and neutron diffraction, and measurements of electrical resistivity, specific heat and magnetism. The room temperature phase forms a…
Single crystals of manganese(II) octa-uranium(IV) hepta-deca-sulfide, MnU(8)S(17), were grown from the reaction of the elements in a RbCl flux. MnU(8)S(17) crystallizes in the space group C2/m in the CrU(8)S(17) structure type. The asymmetric unit is composed of the following atoms with site symmetries shown: U1 (1),…
Abstract A series of poly(N‐vinyl carbazole) (PNVCz)/sodium montmorillonite (Na+MMT) and PNVCz/organo‐MMT composite materials have been successfully prepared by in situ free radical polymerization with cerium ammonium nitrate (CAN) as initiator in the presence of inorganic nanolayers of hydrophilic Na+MMT or organophi…
HIV-1 protease (PR) was cocrystallized in competitive mixtures of saquinavir (SQV) and ritonavir (RTV) in an attempt to compare the relative potencies of inhibitors using a crystallographic approach. The mixture ratio of the RTV/SQV was in the range of 1:1 to 50:1. The crystal form obtained with 1:1 and 5:1 ratios of…
We have fabricated MgB 2 superconducting tapes with a powder-in-tube (PIT) technique using Mg(BH 4 ) 2 precursor. Heat treatment decomposes Mg(BH 4 ) 2 and subsequently forms MgB 2 as nearly single phase. Although the tapes carry supercurrent at 4.2 K and 0 T, the transport critical current ( I c ) values of the tapes…
The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thio-cyanate and one sulfate anion, two bis-(3-amino-prop-yl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one…
There are two independent La(III) cations in the polymeric title compound, {[La(2)(C(7)H(3)NO(4))(3)(H(2)O)(4)]·2H(2)O}(n). One is nine-coordinated in an LaN(2)O(7) tricapped trigonal-prismatic geometry formed by three pyridine-2,6-dicarboxyl-ate anions and two water mol-ecules, while the other is ten-coordinated in a…
In the title compound, [Ni(C(11)H(13)N(2)O(4))(2)]·C(3)H(7)NO, the Ni(II) ion is octa-hedrally coordinated in an N(2)O(4) environment by two identical Schiff base ligands. The Ni-O bond lengths range from 2.004 (2) to 2.106 (2) Å, while the Ni-N bond lengths are 2.038 (2) and 2.0465 (19) Å. The cis bond angles range f…
In this work, we present the variation of exchange constant (J exc ) and magnetocaloric effect (MCE) in LaFe 13-x Si x (x = 1.6, 1.9 and 2.2) compounds. NaZn 13-type LaFe 13-x Si x intermetallic compounds were prepared by arc melting in an atmosphere of highly pure argon gas. X-ray results indicated a slight decrease…
The crystal structure of despujolsite [tricalcium manganese bis-(sulfate) hexahydroxide tri-hydrate], the Ca/Mn member of the fleischerite group, ideally Ca(3)Mn(4+)(SO(4))(2)(OH)(6)·3H(2)O, was previously determined based on X-ray diffraction intensity data from photographs, without H-atom positions located [Gaudefro…
The in situ molecular scale response of end-grafted polystyrene to shear against a deuterated polystyrene melt was investigated with neutron reflectometry. The derived grafted polystyrene density profiles showed that the grafted polystyrene was retained on the quartz wafer during the measurements. The profiles suggest…