Materials Literature
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Abstract A new carbazole‐derived, triphenylamine (TPA)‐containing aromatic dicarboxylic acid monomer, 4,4′‐dicarboxy‐4″‐(3,6‐di‐ tert ‐butylcarbazol‐9‐yl)TPA, was synthesized, and it led to a series of electroactive aromatic polyamides with main‐chain TPA and pendent 3,6‐bis( tert ‐butyl)carbazole units by reacting it…
info:eu-repo/semantics/published
Novel 'nano in nano' composites consisting of biodegradable polymer nanoparticles incorporated into polymer nanofibers may efficiently modulate drug delivery. This is shown here using a combination of model compound-loaded biodegradable nanoparticles encapsulated in electrospun fibers. The dye coumarin 6 is used as mo…
Abstract High cis ‐1,4 polyisoprene with narrow molecular weight distribution has been prepared via coordinative chain transfer polymerization (CCTP) using a homogeneous rare earth catalyst composed of neodymium versatate (Nd(vers) 3 ), dimethyldichlorosilane (Me 2 SiCl 2 ), and diisobutylaluminum hydride (Al( i ‐Bu)…
Abstract Large‐scale molecular dynamics (MD) simulations of semicrystalline entangled polymers are carried out to explore crystallization and melting processes. Semicrystalline polymers are obtained from disordered melts via homogeneous nucleation. In the early stage of the crystallization process, the collective scat…
We report on the phase transitions, solution structure, and consequent effect on the photophysical properties of poly[3-(6-trimethylammoniumhexyl)thiophene] bromide (P3TMAHT) in aqueous sodium dodecylsulfate (SDS). Polythiophene was mixed with SDS or deuterated SDS to form P3TMAHT(SDS)(x) complex (x = the molar ratio…
Abstract The effect of carbon dioxide (CO 2 ) on the physical properties of poly( L ‐lactic acid) (PLLA) and on the formation of crystalline domains was investigated. The presence of CO 2 in the matrix was found to induce crystallization in PLLA, with the crystallinity increasing with increasing CO 2 pressure. The com…
The authors report the conversion of β-Ga2O3nanowires (NWs) to GaN NWs through ammonification and the fabrication of a GaN NW photodetector (PD). Compared with conventional 2-D GaN PDs, it was found that we could achieve a 1000 times larger photocurrent from the GaN NW PD. It was also found that dynamic response of th…
We report a semilocal and hybrid Hartree-Fock density functional study of native defects in three oxide semiconductors: ZnO, SrTiO(3), and SnO. The defect that is responsible for the n-type conductivity of ZnO has been debated, in which the O vacancy, Zn interstitial, their complexes, and residual H impurity are consi…
Nanostructured mesoporous silica (SiO(2)) films are used to load and release the monoclonal antibody bevacizumab (Avastin) in vitro. A biocompatible and biodegradable form of mesoporous SiO(2) is prepared by electrochemical etching of single crystalline Si, followed by thermal oxidation in air at 800 °C. Porous SiO(2)…
Silicate ions increase the thermal stability of the unstable amorphous calcium carbonate (ACC). This effect was observed first by comparing ACC from two different species of cystoliths, small calcified bodies formed in the leaves of some plants. The temperature of crystallization to calcite in the silicate-rich cystol…
Abstract Self‐organized oxide nanostructures grown by controlled anodic oxidation of a metal substrate attracted wide scientific interest due to a broad number of potential applications. The present work gives an overview on growth principles and mechanistic aspects of self‐organized TiO 2 nanotubular layers and relat…
We have investigated the dependence of the static first hyperpolarizability on the bond-length alternation (BLA) parameter. Our analysis indicates that the validity of the first hyperpolarizability/BLA parameter relationship is restricted to the no-field, vacuum, limit, while it successively breaks down along with inc…
To improve water-resistant ability and mechanical properties of silk fibroin (SF)/hydroxybutyl chitosan (HBC) nanofibrous scaffolds for tissue-engineering applications, genipin, glutaraldehyde (GTA), and ethanol were used to crosslink electrospun nanofibers, respectively. The mechanical properties of nanofibrous scaff…
Abstract We present the results of the quasi‐static cyclic tensile tests of Cu–Al–Mn shape memory alloy (SMA) bars of 4 and 8 mm diameters to examine their superelasticity and other mechanical properties closely related to seismic applications. The present Cu–Al–Mn SMA bars have achieved the recovery strains of over 8…
Abstract The synthesis of double‐hydrophilic core/shell cylindrical polymer brushes (CPBs), their hybrids with magnetite nanoparticles, and the directed alignment of these magnetic hybrid cylinders by a magnetic field are demonstrated. Consecutive grafting from a polyinitiator poly(2‐(2‐bromoisobutyryloxy)ethyl methac…
We address the determination of physical observables in graphene in the presence of Coulomb interactions of density-density type modeled with a static Coulomb potential within a quantum field theory perturbative renormalization scheme. We discuss the similarities and differences of the model with quantum electrodynami…
Time-resolved luminescence (TRL) microscopy can image signals from lanthanide coordination complexes or other probes with long emission lifetimes, thereby eliminating short-lifetime (<100 ns) autofluorescence background from biological specimens. However, lanthanide complexes emit far fewer photons per unit time than…
Theoretical studies on the total energy, electronic structure, and bonding of the Zr 0.9 Ti 0.1 NiMn 0.5 Cr 0.25 V 0.25 alloy and its hydrides were performed using density functional theory calculations. This alloy crystallizes in the C14 Laves phase. To determine the equilibrium structural parameters for this compoun…
We study the electronic band structure of monolayer graphene when Rashba spin-orbit coupling is present. We show that if the Rashba spin-orbit coupling is stronger than the intrinsic spin-orbit coupling, the low-energy bands undergo trigonal-warping deformation and that for energies smaller than the Lifshitz energy, t…