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Characterization of KDP crystal grown from solution with low pH value

Zhong De‐Gao、Teng Bing、Dong Sheng-ming 等 7 位作者2009-03-11Crystal Research and Technology

Abstract Solubility curves of KDP (KH 2 PO 4 ) in solutions with different pH values were measured. It was found that the solubility of KDP crystal increased with the reduction pH value of solution. Transparent KDP crystal was grown from solution with 1.5 pH by point seed. Chemical etching experiments revealed that py…

Nonlinear Optical Materials ResearchSpectroscopy and Quantum Chemical StudiesCrystallization and Solubility Studies

Magnetic and structural properties of Co0.8MnxFe2.2−xO4 (x=0.2, 0.4, 0.6, 0.8) polycrystalline powders synthesized by sol-gel process

Zunming Lu、Z. W. Li、Jingcheng Shen 等 7 位作者2009-03-11Journal of Applied Physics

Co 0.8 Mn x Fe 2.2 − x O 4 (x=0.2, 0.4, 0.6, and 0.8) powders were prepared by a sol-gel process and annealed at different temperatures (Ta=600, 800, 1000, and 1200 °C). X-ray diffractometer results reveal that all the samples are inverse-type spinel with cubic structure. The magnetic properties were measured by vibra…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesMagneto-Optical Properties and Applications

Synthesis of Nanocrystalline α-Al2O3 Powder Using Acetylacetone

J. Chandradass、Ki Hyeon Kim2009-03-11Materials and Manufacturing Processes

Nanocrystalline α-Al2O3 powders have been prepared by pyrolysis of a complex compound of aluminum with acetylacetone. The volumetric ratio (alumina to acetylacetone) of the starting feedstock has been shown to be a critical factor for the formation of nano α-Al2O3 powders. The optimum calcinations temperature of the p…

Advanced ceramic materials synthesisThermal and Kinetic AnalysisX-ray Diffraction in Crystallography

Toward an antitumor form of bovine pancreatic ribonuclease: The crystal structure of three noncovalent dimeric mutants

Antonello Merlino、Irene Russo Krauss、Margherita Perillo 等 8 位作者2009-03-11Biopolymers

The cytotoxic action of bovine seminal ribonuclease (BS-RNase) depends on its noncovalent swapped dimeric form (NCD-BS), which presents a compact structure that allows the molecule to escape ribonuclease inhibitor (RI). A key role in the acquisition of this structure has been attributed to the concomitant presence of…

Protein Structure and DynamicsDNA and Nucleic Acid ChemistryEnzyme Structure and Function

Assessing how metal–carbon interactions affect the structure of supported platinum nanoparticles

Brian H. Morrow、Alberto Striolo2009-03-11Molecular Simulation

Towards understanding the effect of solid supports on the catalytic activity of supported metal nanoparticles, all-atom molecular dynamics (MD) simulations are often conducted. However, these calculations are hampered by the uncertainty related to describing metal–support interactions (typically described as Lennard-J…

Advanced Chemical Physics StudiesAdvancements in Battery MaterialsGraphene research and applications

Synthesis and characterization of a novel electrochromic aromatic polyamide from AB‐type triphenylamine‐based monomer

Guey‐Sheng Liou、Kai‐Han Lin2009-03-11Journal of Polymer Science Part A Polymer Chemistry

Abstract A new triphenylamine‐based polyamide I was prepared by direct polycondensation of AB‐type monomer, 4‐amino‐4′‐carboxy‐4″‐methoxytriphenylamine ( 4 ), in the presence of triphenyl phosphite and pyridine as condensation agents. The obtained polyamide I showed excellent solubility in aprotic polar solvents such…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and properties of polymers

Single-walled carbon nanotubes decorated with a pyrene–fluorenevinylene conjugate

Dimitrios Tasis、John A. Mikroyannidis、V. Karoutsos 等 5 位作者2009-03-11Nanotechnology

Single-walled carbon nanotubes are noncovalently functionalized using a pyrene-fluorenevinylene dye and the resulting nanohybrids are isolated from the free molecules. The tubes modified by means of this noncovalent approach show enhanced solubility in organic media. The structure and morphology of this hybrid materia…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Synthesis, Characterization, and Double Layer Capacitance Charging of Nanoclusters Protected by 6-Mercaptopurine

Alfonso J. Viudez、Rafael Madueño、Manuel Blázquez 等 4 位作者2009-03-11The Journal of Physical Chemistry C

The synthesis of gold nanoparticles by using the one-phase method of Brust has been carried out in this work to obtain 6-mercaptopurine monolayer protected gold nanoclusters (6MP-MPCs). The 6MP-MPCs are somewhat polar clusters that are soluble in polar solvents such as DMF and DMSO and in neutral and alkaline aqueous…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Properties of Co‐doped ZnO films prepared by electrochemical deposition

Y. X. Wang、X. Ding、Yan Cheng 等 9 位作者2009-03-11Crystal Research and Technology

Abstract We prepared Co‐doped ZnO films by the electrochemical deposition. X‐ray diffraction (XRD), high resolution transmission microscopy (HRTEM), x‐ray photoelectron spectroscopy (XPS), atomic force microscope (AFM), x‐ray absorption near‐edge structure (XANES), vibrating sample magnetometer (VSM), optical absorpti…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Can Green Scale Inhibitors Replace Phosphonate Scale Inhibitors?: Carbonate Coreflooding Experiments

Salima Baraka-Lokmane、K. S. Sorbie、Nathalie Poisson 等 4 位作者2009-03-11Petroleum Science and Technology

The oil industry is currently facing severe restrictions concerning the discharge of oilfield chemicals into the environment. The purpose of this study is to test the possibility of replacing an organic phosphonate scale inhibitor (DETPMP) by a more environmentally friendly “green” species: carboxymethyl inulin (CMI).…

Calcium Carbonate Crystallization and Inhibition

Gadolinium‐Associated Nephrogenic Systemic Fibrosis in a 9‐Year‐Old Boy

Clare E. Foss、Jeff K. Smith、Luis A. Ortiz 等 5 位作者2009-03-11Pediatric Dermatology

We describe a 9-year-old boy on chronic hemodialysis who presented with hyperpigmented, tightly bound-down, indurated plaques of his bilateral lower extremities. Pertinent history included a recent series of magnetic resonance imaging tests utilizing gadolinium-based contrast media. Histopathology showed widened septa…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesBiomedical Research and Pathophysiology

Biomimetic carbocationic polymerizations III: Investigation of isoprene polymerization initiated by dimethyl allyl bromide

Judit E. Puskás、Frédéric Peruch、Alain Deffieux 等 7 位作者2009-03-11Journal of Polymer Science Part A Polymer Chemistry

Abstract Natural rubber (poly(1,4‐ cis ‐isoprene), NR) is a polymer of considerable industrial importance due to its exceptional properties. It is mostly produced from the cultivation of Hevea brasiliensis , and to a limited extent from Parthenium argentatum . Till date none of the synthetic equivalent of NR exists. R…

biodegradable polymer synthesis and propertiesSynthetic Organic Chemistry MethodsPlant biochemistry and biosynthesis

Magnetoconductance of graphene nanoribbons

T.S. Li、Y. C. Huang、Shang-Chou Chang 等 5 位作者2009-03-11The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

The electronic and transport properties of monolayer and AB-stacked bilayer zigzag graphene nanoribbons subject to the influences of a magnetic field are investigated theoretically. We demonstrate that the magnetic confinement and the size effect affect the electronic properties competitively. In the limit of a strong…

Advancements in Battery MaterialsGraphene research and applicationsQuantum and electron transport phenomena

Synthesis and characterization of highly soluble poly(ether imide)s containing indane moieties in the main chain

Barnali Dasgupta Ghosh、Suman Sen、Samarendra Maji 等 5 位作者2009-03-11Journal of Applied Polymer Science

Abstract A new indane containing unsymmetrical diamine monomer ( 3 ) was synthesized. This diamine monomer leads to a number of novel semifluorinated poly (ether imide)s when reacted with different commercially available dianhydrides like benzene‐1,2,4,5‐tetracarboxylic dianhydride (PMDA), benzophenone‐3,3′, 4,4′‐tetr…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Magnetism of Cr-doped diamond-like carbon

Juan A. Santana、R. Skomski、Varshni Singh 等 9 位作者2009-03-11Journal of Applied Physics

Chromium-doped hydrogenated diamond-like carbon (Cr-DLC) and chromium carbide hydrogenated DLC alloys were synthesized by plasma-assisted vapor deposition and investigated by x-ray absorption near edge structure spectroscopy, extended x-ray absorption fine structure, and superconducting quantum interference device (SQ…

ZnO doping and propertiesMetal and Thin Film MechanicsDiamond and Carbon-based Materials Research

The physical and mechanical properties of polyurethanes from oleic acid polyols

Thamil Selvi Velayutham、W.H. Abd. Majid、Azhar Ahmad 等 5 位作者2009-03-11Journal of Applied Polymer Science

Abstract Three different polyester polyols, with various oleic acid content, were used in the preparation of polyurethane (PUR) coatings. The polyols were designated as Alk28, Alk40, and Alk65, in which 28, 40, and 65 represent the percentage of oleic acid of the polyol formulations. These polyester polyols were react…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Coherent Phonon Dynamics in Single-Walled Carbon Nanotubes Studied by Time-Frequency Two-Dimensional Coherent Anti-Stokes Raman Scattering Spectroscopy

Katsuyoshi Ikeda、Kohei Uosaki2009-03-11Nano Letters

Coherent phonon dynamics in single-walled carbon nanotubes were studied using broadband coherent anti-Stokes Raman scattering microscopy in time-frequency domain. Zone-center G-phonons were coherently created by optical excitation with the relaxation time of 1.1 +/- 0.1 ps, while zone-boundary D-phonons showed incoher…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchMechanical and Optical Resonators

Characterization of the Antiferromagnetism in Ag(pyz)2(S2O8) (pyz = Pyrazine) with a Two-Dimensional Square Lattice of Ag2+ Ions

Jamie L. Manson、Kevin H. Stone、H.I. Southerland 等 17 位作者2009-03-11Journal of the American Chemical Society

X-ray powder diffraction and magnetic susceptibility measurements show that Ag(pyz)(2)(S(2)O(8)) consists of 2D square nets of Ag(2+) ions resulting from the corner-sharing of axially elongated AgN(4)O(2) octahedra and exhibits characteristic 2D antiferromagnetism. Nevertheless, mu(+)SR measurements indicate that Ag(p…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesInorganic Fluorides and Related Compounds

Long term in vivo degradation and tissue response to photo‐cross‐linked elastomers prepared from star‐shaped prepolymers of poly(ε‐caprolactone‐co‐D,L‐lactide)

Rafi Chapanian、M. Yat Tse、Stephen C. Pang 等 4 位作者2009-03-11Journal of Biomedical Materials Research Part A

Long term in vivo degradation, and tissue response to, cylindrical elastomers made of photo-cross-linked star-poly(epsilon-caprolactone-co-D,L-lactide) triacrylate were investigated through subcutaneous implantation in rats. The elastomers were prepared via UV initiated crosslinking of prepolymers of equimolar amounts…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Predicting a major role of surface spins in the magnetic properties of ferrite nanoparticles

Ihab M. Obaidat、V.S. Mohite、Bashar Issa 等 5 位作者2009-03-11Crystal Research and Technology

Abstract Room‐temperature magnetization hysterisis measurements were conducted on Mn 0.5 Zn 0.5 Gd x Fe (2‐x) O 4 ferrite nanoparticles, with x = 0, 0.5, 1.0, 1.5. The structure of this ferrite is normal spinel where the added of Gd 3+ ions occupied the octahedral sites and replaces Fe 3+ ions. The saturation magnetiz…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesMagneto-Optical Properties and Applications