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Dynamics of polymer thin films in supercritical carbon dioxide

Tadanori Koga、Young‐Soo Seo、Xin Hu 等 9 位作者2002-11-01Europhysics Letters (EPL)

In situ neutron reflectivity and dynamic secondary ion mass spectrometry measurements were used to investigate the dynamics of polystyrene thin films in supercritical carbon dioxide (scCO 2 ). The results show that the large degree of anomalous swelling observed is associated with a decrease in glass transition temper…

Polymer crystallization and propertiesPhase Equilibria and ThermodynamicsPolymer Foaming and Composites

Smectic Phases with Cubic Symmetry: The Splay Analog of the Blue Phase

B. A. DiDonna、Randall D. Kamien2002-11-01Physical Review Letters

We report on a construction for smectic blue phases, which have quasi-long-range smectic translational order as well as long-range cubic or hexagonal order. Our proposed structures fill space with a combination of minimal surface patches and cylindrical tubes. We find that for the right range of material parameters, t…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsOcular Surface and Contact Lens

A Monte Carlo-Quantum Mechanics Study of the Solvent-Induced Spectral Shift and the Specific Role of Hydrogen Bonds in the Conformational Equilibrium of Furfural in Water

Roberto Rivelino、Kaline Coutinho、Sylvio Canuto2002-11-01The Journal of Physical Chemistry B

The solvation shift of the lowest absorption transition of furfural in water is analyzed as a function of the rotation angle for the interconversion between the two conformations, OO-cis and OO-trans, of furfural. In total, 20 Monte Carlo NPT simulations are performed, corresponding to different rotation angles of the…

Nonlinear Optical Materials ResearchPhotochemistry and Electron Transfer StudiesMolecular spectroscopy and chirality

Preparation of graft copolymers from deproteinized and high ammonia concentrated natural rubber latices with methyl methacrylate

Charoen Nakason、Azizon Kaesaman、N. Yimwan2002-11-01Journal of Applied Polymer Science

Abstract Deproteinized natural rubber (DPNR) latex was prepared by the incubation of fresh natural latex with a proteolytic enzyme. The DPNR latex was later used to prepare a graft copolymer with methyl methacrylate (MMA). High ammonia (HA) concentrated latex was also used to prepare a graft copolymer with MMA. The ap…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

Catalyst Coatings for Microstructure Reactors

K. Haas‐Santo、Oliver Görke、Peter Pfeifer 等 4 位作者2002-11-01CHIMIA International Journal for Chemistry

Catalytic active coatings for microchannels have been developed for metallic microstructure reactors in heterogeneous catalyzed gas phase reactions. To enhance the inner surface of microchannel reactors, porous metal oxide coatings have been made by various deposition techniques such as sol–gel processes, anodic oxida…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesAnodic Oxide Films and Nanostructures

Structural and chemical heterogeneity of illite-smectites from Upper Jurassic mudstones of East Greenland related to volcanic and weathered parent rocks

Victor A. Drits、B. A. Sakharov、Lidia G. Dainyak 等 5 位作者2002-11-01American Mineralogist

Article Structural and chemical heterogeneity of illite-smectites from Upper Jurassic mudstones of East Greenland related to volcanic and weathered parent rocks was published on November 1, 2002 in the journal American Mineralogist (volume 87, issue 11-12).

Geological and Geochemical AnalysisClay minerals and soil interactionsIron oxide chemistry and applications

Insulator Icing Test Methods and Procedure

M. Farzaneh、T. Baker、K. Brown 等 21 位作者2002-11-01IEEE Power Engineering Review

This is a position paper prepared by the IEEE Task Force on Insulator Icing Test Methods. Test methods for evaluating flashover voltage of ceramic and nonceramic insulators under ice, snow, and cold-fog conditions are recommended. The paper describes the procedure to be followed at various stages of an evaluation test…

High voltage insulation and dielectric phenomenaIcing and De-icing TechnologiesThermal Analysis in Power Transmission

Poly(ethylene glycol)-Supported Tetrahydroxyphenyl Porphyrin: A Convenient, Recyclable Catalyst for Photooxidation Reactions

Maurizio Benaglia、Tamara Danelli、Fabrizio Fabris 等 5 位作者2002-11-01Organic Letters

[reaction: see text] A new poly(ethylene glycol)-supported porphyrin has been prepared and its ability as a promoter in photooxidation reactions has been studied. The PEG-supported catalyst exhibits high activity, comparable to that of a nonanchored sensitizer, and it is easily removable by filtration from the reactio…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry Reactions

Structural Studies and Stability of Cluster-like RuxSey Electrocatalysts

Fabrice Dassenoy、W. Vogel、Nicolás Alonso‐Vante2002-11-01The Journal of Physical Chemistry B

Structural studies and stability of cluster-like particles of Ru x and Ru x Se y were performed in situ via X-ray diffraction at wide angles (WAXS). Both materials have a similar particle size (1.4−1.6 nm) in the reduced state. Whereas Ru x particles are rather sensitive to oxygen from air, the chemical stabilization,…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceQuantum Dots Synthesis And Properties

X-ray intensity fluctuation spectroscopy measurementsof the charge density wave phases of NbSe3

Mark Sutton、Y. Li、J. D. Brock 等 4 位作者2002-11-01Journal de Physique IV (Proceedings)

An introduction to X-ray Intensity Fluctuation Spectroscopy (XIFS) is given by describing its relationship to speckle from coherent sources. A brief description of the relationship of XIFS measurements to the underlying equations of motion is given. Preliminary results for the charge density wave (CDW) system NbSe 3 a…

Advanced Chemical Physics StudiesMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

X-ray diffraction and IR spectroscopy study of labuntsovite-group minerals

Р. К. Расцветаева、Н. В. Чуканов2002-11-01Crystallography Reports

The distribution of cations over the positions in the structures of labuntsovite-group minerals was studied by X-ray diffraction analysis and IR spectroscopy. Several types of cation order over the five key positions are established depending on cation composition and their force characteristics.

Crystal Structures and PropertiesX-ray Diffraction in CrystallographyGeotechnical and Geomechanical Engineering

A thermodynamic description of the B–Co system: modeling and experiment

Yong Du、Julius C. Schuster、Y. A. Chang 等 5 位作者2002-11-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract The B–Co system is investigated via thermodynamic modeling and experiments. In the modeling section, all of the experimental phase diagram and thermodynamic data available from the literature were critically reviewed and assessed by using thermodynamic models for the Gibbs energies of individual phases. In th…

Metallurgical Processes and ThermodynamicsAdvanced Materials Characterization TechniquesMetallurgical and Alloy Processes

Properties of Ionic‐Conducting β‐Bi 2 O 3 Containing Mixed Dopants

Stephen D. Nunn、E. Andrew Payzant2002-11-01Journal of the American Ceramic Society

β‐Bi 2 O 3 compositions were prepared to evaluate the effect on properties of using mixed dopants. Baseline compositions containing 28 mol% of the alkaline‐earth oxides CaO, SrO, or BaO were used for comparison. When the alkaline earths were combined in pairs to dope the bismuth oxide, the resulting properties were in…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Interfacial controlled growth of AgI nanoparticles

P. Senthil Kumar、C.S. Sunandana2002-11-01Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

AgI nanoparticles with zincblende structure are promising materials for laser based optical communication systems and therefore deserve to be optimally synthesized. We have explored ambient iodization as a strategy for controlled AgI nanoparticle growth on (a) mesoporous Ag foils, (b) Ag-Cu quasi-amorphous thin films…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

High pressure measurement of the uniaxial stress of host layers on intercalants and staging transformation of intercalation compounds

Ta-Ryeong Park、Tae Yang Park、Hyungrok Kim 等 4 位作者2002-11-01Journal of Physics Condensed Matter

A layered double-hydroxide intercalation compound was synthesized to measure the uniaxial stress the host layers exert on the intercalants. To measure the uniaxial stress, we employed the photoluminescence (PL) from the intercalated species, the Sm ion complex, as it is sensitive to the deformation of the intercalants…

Crystal Structures and PropertiesLayered Double Hydroxides Synthesis and ApplicationsInorganic Chemistry and Materials

A theoretical model for quiescent coarsening in immiscible polymer blends

Guo‐Hua Hu、Huxi Li、Lian‐Fang Feng2002-11-01AIChE Journal

Abstract The coalescence rate in immiscible polymer blends predicted by all existing models is two or three orders of magnitude lower than that observed experimentally. The model developed in this study considers for the first time that coarsening is driven by van der Waals forces and there is slippage at the interfac…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Initial Studies of Plutonium Corrosion

P. Roussel、Daniel Shaw、D.A. Geeson2002-11-01Journal of Nuclear Science and Technology

We report here our preliminary results of pliitonium corrosion studied using photoelectron spectroscopy and secondary ion mass spectrometry. Plutonium surfaces were cleaned by Ar ion bombardment, and examined using X-ray and ultraviolet photoelectron spectroscopy, Auger electron spectroscopy and secondary ion mass spe…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

X-ray powder diffraction analysis of cements

P. Barnes、J. Bensted2002-11-01OpenAlex

It is important to stress that XRD must not be used as a &s;black box&s; to characterize cementitious materials. Ordinary Portland cement (OPC) is not made from pure minerals but from quarries that generally contain substantial amounts of impurities. Thus, the alite component of Portland cement is not pure C^S but is…

Advanced ceramic materials synthesisAdvanced materials and compositesX-ray Diffraction in Crystallography

The crystal structure of Cu4Bi4Se9

Emil Makovicky、Inger Søtofte、Sven Karup-Møller2002-11-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract The crystal structure of Cu 4 Bi 4 Se 9 , synthesized at 400 °C, was determined from single crystal X-ray diffraction data and refined to the R 1 value of 0.05. The compound is orthorhombic, with a = 32.692 Å, b = 4.120 Å, and c = 12.202 Å, space group Pnma . The structure contains three square pyramidal Bi s…

High-pressure geophysics and materialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Analysis and Support Initiative for Structural Technology (ASIST) Delivery Order 0016: USAF Damage Tolerant Design Handbook: Guidelines For the Analysis and Design of Damage Tolerant Aircraft Structures

P. Miedlar、Alan P. Berens、Allan W. Gunderson 等 4 位作者2002-11-01Defense Technical Information Center (DTIC)

This is an electronic version of the revised U.S. Air Force Damage Tolerant Design Handbook. The technical content of the 2002 edition is enhanced by the addition of new developments in the areas of corrosion, widespread fatigue damage, and probabilistic methods. New sample problems are included which illustrate the s…

Fatigue and fracture mechanicsRocket and propulsion systems researchEngineering and Material Science Research