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A Molecular Dynamics Study of the Thermodynamic Properties of Calcium Apatites. 1. Hexagonal Phases

Fernando J. A. L. Cruz、José N. Canongia Lopes、Jorge C. G. Calado 等 4 位作者2005-12-01The Journal of Physical Chemistry B

Structural and thermodynamic properties of crystal hexagonal calcium apatites, Ca10(PO4)6(X)2 (X = OH, F, Cl, Br), were investigated using an all-atom Born-Huggins-Mayer potential by a molecular dynamics technique. The accuracy of the model at room temperature and atmospheric pressure was checked against crystal struc…

Crystallography and molecular interactionsThermal and Kinetic AnalysisX-ray Diffraction in Crystallography

Calorimetric analysis of polymer behaviour using a pixel calibration of an IRFPA camera

V. Honorat、Stéphane Moreau、Jean-Michel Muracciole 等 5 位作者2005-12-01Quantitative InfraRed Thermography Journal

A pixel calibration of an IRFPA camera was developed to detect very small temperature variations induced by quasi-static loading of materials. The thermographic data were then used to estimate heat sources accompanying the deformation of PMMA and PC polymers during cyclic tests. The calorimetric balance analysis led u…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorIon-surface interactions and analysis

Fabrication of Nanoparticle Composite Porous Films Having Ultralow Dielectric Constant

Shota Nunomura、Kazunori Koga、Masaharu Shiratani 等 7 位作者2005-12-01Japanese Journal of Applied Physics

Nanoparticle composite porous films having a dielectric constant of ε r =1.7–3.5 have been deposited using plasma chemical vapor deposition. Nanoparticles as nano-building blocks and radicals as adhesives are generated in plasmas, and nanoparticles are deposited together with radicals on substrates to form porous film…

Advanced ceramic materials synthesisSemiconductor materials and devicesCopper Interconnects and Reliability

Manganese Azides Based on Co‐Ligands with a Flexible Tail: Diverse Structural and Magnetic Properties

Shi‐Qiang Bai、En‐Qing Gao、Zheng He 等 6 位作者2005-12-01European Journal of Inorganic Chemistry

Abstract Three azido‐bridged coordination polymers, namely [Mn(L 1 )(N 3 ) 2 ] n ( 1 ), [Mn(L 2 )(N 3 ) 2 ] n ( 2 ), and [Mn(L 3 )(N 3 ) 2 ] n ( 3 ) [L 1 = N ‐(2‐pyridylmethylene)methylamine, L 2 = N ‐(2‐pyridylmethylene)ethylamine, and L 3 = N ‐(2‐pyridylmethylene)octylamine], have been synthesized with Schiff‐base c…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Subwavelength surface-relief gratings for stellar coronagraphy

Dimitri Mawet、Pierre Riaud、Jean Surdej 等 4 位作者2005-12-01Applied Optics

We present a new design of a phase mask coronagraph implemented with subwavelength diffractive optical elements consisting of optimized surface-relief gratings. Phase mask coronagraphy is a recent technique that seeks to accommodate both high dynamic and high angular resolution imaging of faint sources around bright a…

Photonic and Optical DevicesAdaptive optics and wavefront sensingOptical Coatings and Gratings

Numerical modeling of Tm-doped double-clad fluoride fiber amplifiers

Marc Eichhorn2005-12-01IEEE Journal of Quantum Electronics

Theoretical modeling of Watt-level average power Tm-doped fluoride glass fiber amplifiers operating at 1.87 /spl mu/m is presented. To characterize and optimize these devices a computer model has been developed taking into account the full spectral information of the laser transition as well as all important ionic lev…

Glass properties and applicationsPhotonic Crystal and Fiber OpticsSolid State Laser Technologies

Structure and enhancement of negative thermal expansion in the PbTiO3–CdTiO3 system

Jun Chen、Xianran Xing、Ranbo Yu 等 4 位作者2005-12-01Applied Physics Letters

The structures of Pb1−xCdxTiO3 (x=0.03 and 0.06) were investigated by the x-ray Rietveld method at room temperature. It is surprising to find that the spontaneous polarization displacements of Pb∕Cd and Ti atoms according to the oxygen polyhedron decrease, although the c∕a ratio increases with doping-cadmium content.…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisThermal Expansion and Ionic Conductivity

Crystallographic pitting in magnesium single crystals

C. R. McCall、Mary Ann Hill、R. S. Lillard2005-12-01Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control

The corrosion behaviour of three low index planes of an hcp magnesium (Mg) single crystal was investigated in 10−2M NaCl/10−4M dichromate solution. The Mg (0001) surface exhibited pitting corrosion susceptibility at the open circuit potential. However, the (1010), and (1120) surfaces were passive at open circuit and p…

Corrosion Behavior and InhibitionMagnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure Properties

A Kinetically Controlled Trans Bifunctionalized Organoimido Derivative of the Lindqvist-Type Hexamolybdate: Synthesis, Spectroscopic Characterization, and Crystal Structure of (n-Bu4N)2{trans-[Mo6O17(NAr)2]} (Ar = 2,6-dimethylphenyl)

Yun Xia、Yongge Wei、Yuan Wang 等 4 位作者2005-12-01Inorganic Chemistry

A kinetically controlled trans bifunctionalized organoimido derivative of hexamolybdate, (n-Bu(4)N)(2){trans-[Mo(6)O(17)(NAr)(2)]} (Ar = 2,6-dimethylphenyl) 1, in which the two 2,6-dimethylphenylimido groups are bonded to hexamolybdate at the trans positions, has been successfully synthesized in ca. 60% yield under mi…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsInorganic Chemistry and Materials

Reinforced Thermoplastic Acetylated Starch with Layered Silicates

Xiuying Qiao、Wenbo Jiang、Kang Sun2005-12-01Starch - Stärke

Montmorillonite (MMT) and organically modified montmorillonite (OMMT) were utilized to reinforce the thermoplastic acetylated starch (TPAS) composite prepared with glycerol as a plasticizer. After the addition of layered silicates, the restriction of the motion of the intercalated acetylated starch molecular chains by…

Nanocomposite Films for Food PackagingPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Determination of phonon dispersion relations by X-ray thermal diffuse scattering

Ruqing Xu、Tai C. Chiang2005-12-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract Thermal diffuse scattering (TDS) of X-rays from crystals contains information on phonons. This paper reviews the general theory of TDS and some recent experiments aimed at further developing TDS into a useful and efficient method for studying phonon dispersion relations.

Nuclear materials and radiation effectsX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena

Electrochemical and optical studies of conjugated polymers for three primary colours

Aparna Misra、Pankaj Kumar、Ritu Srivastava 等 6 位作者2005-12-01Indian Journal of Pure & Applied Physics

The Cyclic Voltammetry investigation and optical properties of some of the commonly used conjugated polymers for the fabrication of organic LEDs, like poly [2-methoxy 5- (2'-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), poly [2,3-bis (2-ethylhexyloxy)l,4-phenylenevinylene] (BEH-PPV) and poly[(9,9'-di(2'-ethylhexyl)…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Hydrothermal synthesis of one-dimensional zinc oxides with different precursors

Y. Ming、Guangsheng Pang、Linfeng Jiang 等 4 位作者2005-12-01Nanotechnology

The influence of precursors on the morphology of ZnO is studied. The diameter and the aspect ratio of the ZnO nanorods, as well as the aggregate state, vary when different precursors are used. ZnO nanorods, nanotubes, nanoneedles, as well as aggregates of flower- and quasi-sphere-like nanorods are obtained. Besides th…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Compatible Solutes of the HyperthermophilePalaeococcus ferrophilus: Osmoadaptation and Thermoadaptation in the OrderThermococcales

Clélia Neves、Milton S. da Costa、Helena Santos2005-12-01Applied and Environmental Microbiology

The effect of salinity and growth temperature on the accumulation of intracellular organic solutes was examined in the hyperthermophilic archaeon Palaeococcus ferrophilus. The genus Palaeococcus represents a deep-branching lineage of the order Thermococcales, which diverged before Thermococcus and Pyrococcus. Palaeoco…

Drug Transport and Resistance MechanismsEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Visualization of Localized Holes in Manganite Thin Films with Atomic Resolution

J. X.、Dane T. Gillaspie、E. W. Plummer 等 4 位作者2005-12-01Physical Review Letters

The magnetic and transport behaviors of manganites are critically related to the spatial distribution and correlation of doped holes. Using in situ scanning tunneling microscopy, we have imaged both occupied and unoccupied states simultaneously in a hole-doped (La(5/8-0.3)Pr0.3)Ca(3/8)MnO3 epitaxial thin film grown by…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Atomic pair distribution function analysis of materials containing crystalline and amorphous phases

Thomas Proffen、Katharine Page、Sylvia E. McLain 等 8 位作者2005-12-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract The atomic pair distribution function (PDF) approach has been used to study the local structure of liquids, glasses and disordered crystalline materials. In this paper, we demonstrate the use of the PDF method to investigate systems containing a crystalline and an amorphous structural phase. We present two ex…

Glass properties and applicationsMetallic Glasses and Amorphous AlloysX-ray Diffraction in Crystallography

Contribution of surface conductivity to the current forms of partial discharges in voids

Kai Wu、T. Ijichi、Takeyoshi Kato 等 6 位作者2005-12-01IEEE Transactions on Dielectrics and Electrical Insulation

The current form of partial discharge (PD) in a void was divided into fast and slow components, with short and long fall times, respectively. Comparing these with the current shape of PD in a void between two metal surfaces, in which the slow component was not observed, it was suggested that the formation of fast comp…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrostatic Discharge in Electronics

Effect of Ga doping on the multiferroic properties ofRMn1−xGaxO3(R=Ho,Y)

Haidong Zhou、J.C. Denyszyn、John B. Goodenough2005-12-01Physical Review B

Structural, thermal expansion, thermal conductivity, magnetic, and dielectric measurements on single-crystal $R{\mathrm{Mn}}_{1\ensuremath{-}x}{\mathrm{Ga}}_{x}{\mathrm{O}}_{3}$ ($R=\mathrm{Ho}$ or Y) hexagonal compounds have revealed that the $c$ axis decreases with increasing temperature with a larger $\ensuremath{\…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

A Strong Deviation from Vegard’s Rule: X-Ray Powder Investigations of the Three Quasi-Binary Phase Systems BiOX–BiOY (X, Y = Cl, Br, I)

Egbert Keller、Volker Krämer2005-12-01Zeitschrift für Naturforschung B

The three quasi-binary phase systems BiOX-BiOY (X, Y = Cl, Br, I) have been investigated by X-ray powder methods. No quaternary phases were found in the three systems. BiOCl-BiOBr and BiOBr-BiOI form systems of unlimited mutual solubility. BiOCl-BiOI is a system of limited solubility at the iodine-rich side. In the Bi…

Solid-state spectroscopy and crystallographyX-ray Diffraction in CrystallographyInorganic Fluorides and Related Compounds

Poly(dimethyl siloxane) (PDMS) XPS Reference Core Level and Energy Loss Spectra

Pierre Louette、Frederic Bodino、Jean‐Jacques Pireaux2005-12-01Surface Science Spectra

XPS measurements of poly(dimethyl siloxane) recorded with a SSX-100 spectrometer in standardized experimental conditions are presented: survey scan, high resolution core level spectra as well as the energy loss regions of carbon, oxygen, and silicon peaks are analyzed. This is part of a contract work aiming to record…

Advancements in Photolithography TechniquesElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis