Materials Literature
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Abstract The polymer bound Schiff‐base ligand (PS‐SalGlu) has been prepared from polystyrene bound salicylaldehyde and glutamic acid, and its complex (PS‐SalGlu‐Co) has also been synthesized. The polymer ligand and its complex were characterized by infrared spectroscopy, small area X‐ray photoelectron spectroscopy, an…
Abstract Aniline was polymerized directly into polyaniline‐sulfate salt without using protonic acid in this work. Polyaniline‐sulfate salt was prepared by emulsion and aqueous polymerization pathways. The dopant i.e. sulfate ion in polyaniline‐sulfate salt was generated from ammonium persulfate which was used for oxid…
Thick cubic boron nitride (cBN) films showing clear crystal facets were achieved by chemical vapor deposition. The films show the highest crystallinity of cBN films ever achieved from gas phase. Clear evidence for the growth via a chemical route is obtained. A growth mechanism is suggested, in which fluorine preferent…
BACKGROUND: Tissue engineering is a promising approach for obtaining lifetime durability in biological heart valves. Basic questions with respect to the selection of suitable cell populations as well as scaffolds remain unsolved. The purpose of this study was to develop a tissue-like substitute in vitro for replacemen…
Zirconia is more chemically stable than silica and γ-alumina, which are commonly used in the preparation of inorganic membranes. However, the hydrolysis of zirconia alkoxides, typical zirconia precursors, proceeds rapidly, leading to difficulties in preparing clear sols. Thus, an attempt was made to reduce the hydroly…
Single-walled carbon nanotubes (SWCNs) encapsulated in multiwalled WS2 nanotubes are produced by pyrolyzing a mixture of WO3−x and SWCNs in N2/H2S atmosphere.
Abstract Fluorosilicone elastomer based on the poly[(3,3,3‐trifluoropropyl)methylsiloxane‐co‐(3,3,4,4,5,5,6,6,6‐nonafluorohexyl)methylsiloxane] was studied. First, the synthesis of fluorosilicone polymer based on the poly[(3,3,4,4,5,5,6,6,6‐nonafluorohexyl)methylsiloxane] (PNFHMS) was examined by the polymerization of…
In this paper we consider the numerical approximation of phase field and sharp interface models for diffusion-induced grain boundary motion. The phase field model consists of a double-obstacle Allen-Cahn equation with a forcing obtained from the solution of a degenerate diffusion equation. On the other hand the sharp…
All articles of this category A general two-step, one-pot-synthesis of meso -triphenylcorrole from 5-phenyldipyrrane is presented. A number of p -phenyl-substituted 5-phenyldipyrranes were condensed with substituted benzaldehydes under acid catalyzed conditions to produce a mixture highly enriched in the corresponding…
We found that the sound velocity changes drastically near the coercive field for a 0.955Pb(Zn1/3Nb2/3)O3–0.045PbTiO3 ferroelectric single crystal, which reflects that domain rotation occurred during polarization switching. This velocity change associated with polarization switching provides a powerful method to study…
Electromigration in the lower metal (M1) and the upper metal (M2) of Cu dual-damascene interconnections has been studied. The failure times of M2 test structures are significantly longer than those of identical M1 structures. It is proposed that this asymmetry is the result of a difference in the location of void form…
Three hydrogen-terminated diamonds with different surface roughness and morphologies have been investigated by conductivity and Hall experiments in the temperature regime 0.34–350 K. The sheet hole densities are weakly temperature dependent above a critical temperature Tc (20 K⩽Tc⩽70 K), below Tc carriers freeze out.…
All articles of this category The preparation of a novel polystyrene-supported dehydrating agent and its application to the synthesis of 1,3,4-oxadiazoles under thermal and microwave conditions is described. An alternative procedure using tosyl chloride and P-BEMP is also presented. oxadiazoles - polymer-supported rea…
Arterial vascular cells have been successfully utilized for tissue engineering in human cardiovascular structures, such as heart valves. The present study evaluates saphenous vein-derived myofibroblasts as an alternative, easy-to-access cell source for human cardiovascular tissue engineering. Biodegradable polyurethan…
The influence of an applied electric field on carbon nanotubes protruding from a surface was investigated in situ using a high-resolution scanning electron microscopy. Under the applied electric field, the nanotubes flexed to orient themselves parallel to the electric field lines. For moderate field strengths below th…
Optical gain at 1.54 μm in erbium-doped silicon-rich silicon oxide (SRSO) is demonstrated. Er-doped SRSO thin film was fabricated by electron-cyclotron resonance enhanced chemical vapor deposition of silicon suboxide with concurrent sputtering of erbium followed by a 5 min anneal at 1000 °C. Ridge-type single mode wav…
This is the text of the 'Theory' opening talk at the 2001 Strongly Correlated Electron Systems conference. It contains opinions about some of the outstanding scientific challenges facing the theory side of the correlated electrons field.
It has been claimed that quasistatic granular materials, as well as nanoscale materials, exhibit departures from elasticity even at small loadings. It is demonstrated, using 2D and 3D models with interparticle harmonic interactions, that such departures are expected at small scales [below O(100) particle diameters], a…
Patterned growth of single-walled carbon nanotubes (SWNTs) is achieved on full 4-in. SiO2/Si wafers. Catalytic islands with high uniformity over the entire wafer are obtained by a deep ultraviolet photolithography technique. Growth by chemical vapor deposition of methane is found to be very sensitive to the amount of…
Volume 44 of Reviews in Mineralogy and Geochemistry contains descriptions of the inorganic and biological processes by which nanoparticles form, information about the distribution of nanoparticles in the atmosphere, aqueous environments, and soils, discussion of the impact of size on nanoparticle structure, thermodyna…