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DNA Functionalized Carbon Nanotubes for Nonbiological Applications

Ambarish Paul、Baidurya Bhattacharya2010-08-31Materials and Manufacturing Processes

Functionalization of an inorganic nanomaterial like carbon nanotube (CNT) with biological macromolecules like deoxyribonucleic acid (DNA) leads to the formation of hybrid materials with fascinating properties. This article describes the structures of CNT and DNA, portrays the van der Waals force-dominant non-covalent…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesNanotechnology research and applications

Electronic Structure and Chemical Modification of Graphene Antidot Lattices

Fangping Ouyang、Zhixiong Yang、Jin Xiao 等 5 位作者2010-08-31The Journal of Physical Chemistry C

Using the spin-polarized density functional theory, we have demonstrated the electronic structure of graphene antidot lattices (GALs). It is found that due to the symmetry broken of α, β atomic sublattices, GALs behave semiconducting in general. And the triangular GALs present some electronic localized states around t…

Advancements in Battery MaterialsGraphene research and applications2D Materials and Applications

Experimental and Numerical Modeling of the Controllable Wettability Gradient on Poly(propylene) Created by SF6 Plasma

Dave Mangindaan、Wei‐Hsuan Kuo、Yilin Wang 等 4 位作者2010-08-31Plasma Processes and Polymers

Abstract A continuous and scalable wettability gradient of water contact angle (WCA) (20–135°) were successfully prepared on poly(propylene) film by applying O 2 plasma for pretreatment followed by SF 6 plasma treatment under a specially designed mask. Moreover, the role of mass transfer processes in the plasma treatm…

Membrane Separation TechnologiesSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials

Properties of uniaxially stretched polypropylene films: effect of drawing temperature and random copolymer content

F. Sadeghi、Seyed H. Tabatabaei、Abdellah Ajji 等 4 位作者2010-08-31The Canadian Journal of Chemical Engineering

Abstract Cast films of two linear polypropylenes (PP) having different molecular weights and their blends with 20 wt% random copolymer were prepared by extrusion. The produced cast films were then uniaxially hot drawn at T = 110 and 140°C under a draw ratio (DR) of 6 using a machine direction orientation (MDO) unit. T…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Distinct High-TTransitions in UnderdopedBa1−xKxFe2As2

R. R. Urbano、D. Green、W. G. Moulton 等 10 位作者2010-08-31Physical Review Letters

In contrast with the simultaneous structural and magnetic first order phase transition ${T}_{0}$ previously reported, our detailed investigation on an underdoped ${\mathrm{Ba}}_{0.84}{\mathrm{K}}_{0.16}{\mathrm{Fe}}_{2}{\mathrm{As}}_{2}$ single crystal unambiguously revealed that the transitions are not concomitant. T…

Corporate Taxation and AvoidanceIron-based superconductors research

Photocoercivity of Nano‐Stabilized Au:Fe Superparamagnetic Nanoparticles

Lapo Bogani、Lucia Cavigli、César de Julián Fernández 等 8 位作者2010-08-31Advanced Materials

We demonstrate light-induced switching of the coercive field of true nano-stabilized Au:Fe nanoparticles with exceptionally good magneto-optical response. Two separate processes are identified, both exploitable for photocommutation. This innovative material allows combining appealing photoswitching properties with the…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNanocluster Synthesis and Applications

The effects of retardation on plasmon hybridization within metallic nanostructures

Mark D. Turner、Md Muntasir Hossain、Min Gu2010-08-31New Journal of Physics

Plasmon hybridization theory (PHT) is an analytical model developed for understanding plasmonic interactions within complex metallic nanostructures, and gives a useful insight for optimizing design parameters. However, this theory is based on the electrostatic limit, which restricts the model to nanostructures much sm…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNonlinear Optical Materials Studies

Scrutinizing the Chemical Nature and Photophysics of an Expanded Hemiporphyrazine: The Special Case of [30]Trithia-2,3,5,10,12,13,15,20,22,23,25,30-dodecaazahexaphyrin

Olga Trukhina、M. Salomé Rodríguez‐Morgade、Silke Wolfrum 等 10 位作者2010-08-31Journal of the American Chemical Society

Thirty π-electron-expanded hemiporphyrazines 1a-c have been prepared by crossover condensation reaction of 2,5-diamino-1,3,4-thiadiazole and the corresponding phthalonitrile (3) or diiminoisoindoline (4) derivatives. The expanded azaporphyrin hexamers have been unequivocally characterized by means of spectroscopic, cr…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

D-STEM: A Parallel Electron Diffraction Technique Applied to Nanomaterials

K. J. Ganesh、Masahiro Kawasaki、Jun-Si Zhou 等 4 位作者2010-08-31Microscopy and Microanalysis

An electron diffraction technique called D-STEM has been developed in a transmission electron microscopy/scanning transmission electron microscopy (TEM/STEM) instrument to obtain spot electron diffraction patterns from nanostructures, as small as ∼3 nm. The electron ray path achieved by configuring the pre- and postsp…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesAdvanced Electron Microscopy Techniques and Applications

Silver Nanoparticle Impregnated Poly (ɛ-Caprolactone) Scaffolds: Optimization of Antimicrobial and Noncytotoxic Concentrations

Ragaseema V. Madhavan、M. J. Rosemary、Maya A. Nandkumar 等 5 位作者2010-08-31Tissue Engineering Part A

Use of silver nanoparticles (SNPs) for control of implant-associated infection is a promising strategy, if optimum antimicrobial yet nontoxic dose to mammalian cells is identified. This study was done to determine essential quantity of SNPs, which stimulate antimicrobial activity without cytotoxicity, when immobilized…

Bone Tissue Engineering MaterialsNanoparticles: synthesis and applicationsInfectious Aortic and Vascular Conditions

The properties of cotton-Tencel and cotton-Promodal blended yarns spun in different spinning systems

Musa Kiliç、Ayşe Okur2010-08-31Textile Research Journal

In this study, structural, physical and mechanical properties of cotton-Tencel and cotton-Promodal blended ring, compact and vortex spun yarns were compared. Yarn properties such as hairiness, unevenness, imperfections, diameter, density, roughness, roundness, breaking force and elongation were evaluated. In general,…

Dyeing and Modifying Textile FibersTextile materials and evaluationsStructural Analysis and Optimization

Applications of Oligomers for Nanostructured Conducting Polymers

Yue Wang、Henry D. Tran、Richard B. Kaner2010-08-31Macromolecular Rapid Communications

This Feature Article provides an overview of the distinctive nanostructures that aniline oligomers form and the applications of these oligomers for shaping the nanoscale morphologies and chirality of conducting polymers. We focus on the synthetic methods for achieving such goals and highlight the underlying mechanisms…

Organic Electronics and PhotovoltaicsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Hydrothermal Synthesis of Single Crystalline Nano CeO 2 and Its Structural, Optical, and Electronic Characterization

Saroj Kumar Sahoo、Mamata Mohapatra、Arun Kumar Singh 等 4 位作者2010-08-31Materials and Manufacturing Processes

Single crystalline CeO2 powder was prepared by precipitation-hydrothermal technique. The hydrothermal treatment temperature and time were the two parameters chosen to observe their effect on nature of ceria. The synthesized samples were characterized for structural, optical, and electrical properties using X-ray diffr…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Electron-Mediated CO Oxidation on the TiO2(110) Surface during Electronic Excitation

Zhen Zhang、John T. Yates2010-08-31Journal of the American Chemical Society

The role of electrons and holes in the electronically excited oxidation of adsorbed CO on TiO(2)(110) has been investigated by tuning the surface electron and hole availability by the adsorption of Cl(2) or O(2). The presence of an electron acceptor (Cl(2) or O(2)) on the TiO(2)(110) surface causes upward band bending…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Dynamic Culturing of Smooth Muscle Cells in Tubular Poly(Trimethylene Carbonate) Scaffolds for Vascular Tissue Engineering

Song Yan、J.W.H. Wennink、Marloes M. J. Kamphuis 等 8 位作者2010-08-31Tissue Engineering Part A

Porous, tubular, flexible, and elastic poly(trimethylene carbonate) (PTMC) scaffolds (length 8 cm and inner diameter 3 mm) for vascular tissue engineering were prepared by means of a dip-coating and particulate leaching procedure. Using NaCl as porogen, scaffolds with an average pore size of 110 μm and a porosity of 8…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Phase Separation and Suppression of the Structural and Magnetic Transitions in Superconducting Doped Iron Tellurides, Fe1+xTe1−ySy

P. Zajdel、Ping‐Yen Hsieh、Efrain E. Rodriguez 等 9 位作者2010-08-31Journal of the American Chemical Society

Single crystal and powder samples of the series of iron chalcogenide superconductors with nominal composition, Fe((1.15))Te((1-)y)S(y), are found to form for 0 ≤ y ≤ 0.15. They crystallize in the tetragonal anti-PbO structure, which is composed of layers of edge-shared Fe(Te, S)(4) tetrahedra. For y = 0, Fe(1+x)Te (x…

Corporate Taxation and AvoidanceIron-based superconductors research

Investigation of the Galvanic Mechanism for Localized Carbon Dioxide Corrosion Propagation Using the Artificial Pit Technique

Jianxin Han、Bruce Brown、Srdjan Nešić2010-08-31CORROSION

Localized carbon dioxide (CO2) corrosion is the most dangerous type of internal corrosion to mild steel pipelines in the oil and gas industry since the penetration rate of localized corrosion can be one or more magnitudes higher than that of uniform corrosion. In this study, the focus is on propagation of localized CO…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Sol Gel-Derived SBA-16 Mesoporous Material

Eric M. Rivera‐Muñoz、R. Huirache–Acuña2010-08-31International Journal of Molecular Sciences

The aim of this article is to review current knowledge related to the synthesis and characterization of sol gel-derived SBA-16 mesoporous silicas, as well as a review of the state of the art in this issue, to take stock of knowledge about current and future applications. The ease of the method of preparation, the orde…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

High Relaxivity Magnetic Resonance Imaging Contrast Agents Part 1

Stéphane Dumas、Vincent Jacques、Wei‐Chuan Sun 等 8 位作者2010-08-31Investigative Radiology

RATIONALE AND OBJECTIVES: The donor atoms that bind to gadolinium in contrast agents influence inner-sphere water exchange and electronic relaxation, both of which determine observed relaxivity. The effect of these molecular parameters on relaxivity is greatest when the contrast agent is protein bound. We sought to de…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis