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On the Synthesis of Carbon Nanofibers and Nanotubes by Microwave Irradiation: Parameters, Catalysts, and Substrates

Tamara S. Druzhinina、Stephanie Hoeppener、Ulrich S. Schubert2009-07-28Advanced Functional Materials

Abstract The microwave (MW)‐assisted synthesis of one dimensional carbon systems is introduced as a promising approach to improve the speed and cost‐effectiveness of the fabrication process. Improved reaction conditions are generated by direct MW heating and synthesis under advanced reaction conditions. The influence…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

A New Type of BTP/Zeolites Nanocomposites as Mixed-phase Fire Suppressant: Preparation, Characterization, and Extinguishing Mechanism Discussion

Xiaomin Ni、Kaiqian Kuang、Xishi Wang 等 4 位作者2009-07-28Journal of Fire Sciences

A new type of nanocomposites consisting of solid 4A zeolites and gaseous fire extinguishing agent of 2-bromo-3,3,3-trifluoropropene (BTP) was fabricated in large scale, in which BTP anchored in the porous zeolites. Laboratory-scale fire extinguishment tests showed that the nanocomposites as additives can greatly impro…

Fire dynamics and safety researchFlame retardant materials and propertiesCombustion and Detonation Processes

Mechanical strengths of epoxy resin composites reinforced by calcined pearl shell powders

Genzhong Ji、Hongqi Zhu、Xuewen Jiang 等 5 位作者2009-07-28Journal of Applied Polymer Science

Abstract A series of epoxy resin (EP) composites were prepared using ground pearl shell powders, which had been calcined at various temperatures. The EP composite containing ∼ 3% weight content of the calcined pearl shell powder had the highest impact strength and the presence of silane agent was found to be essential…

Dental materials and restorationsPolymer Nanocomposites and PropertiesPolymer composites and self-healing

A Numerical Model for the Optimal Vulcanization of 2D Polar Rubber Compounds Using Microwaves

Gabriele Milani、Federico Milani2009-07-28Macromolecular Theory and Simulations

Abstract A numerical model is presented for the optimal vulcanization of 2D extruded polar rubber with microwaves and peroxides. Magnetron power and curing time are used as the input production parameters, and the output mechanical property selected for optimization is the average tensile strength of the item. A 2D th…

Dielectric materials and actuatorsSynthesis and properties of polymersMicrowave-Assisted Synthesis and Applications

Mixed percolating network and mechanical properties of polypropylene/talc composites

D. Frihi、Karine Masenelli‐Varlot、Gérard Vigier 等 4 位作者2009-07-28Journal of Applied Polymer Science

Abstract Injected polypropylene/talc composites were studied to evaluate the conditions leading to the formation of a mixed talc/polymer crystalline lamella percolating network and the influence of such a network on the nanocomposite mechanical properties. The talc was either conventional micrometer‐sized (conventiona…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Synthesis and characterization of high‐impact polystyrene using a multifunctional cyclic peroxide as the initiator

Pablo Acuña、Graciela Morales、R. Díaz de León2009-07-28Journal of Applied Polymer Science

Abstract This work deals with the synthesis of high‐impact polystyrene (HIPS) using a novel cyclic multifunctional initiator, the diethyl ketone triperoxide (DEKTP), analyzing its effect on the prepolymerization step and its influence over the HIPS final properties. DEKTP showed a low selectivity toward grafting react…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Ternary Semiconductor Nanoparticles Embedded in PEO—Polymer Electrolyte Matrix

Pramod K. Singh、Hee‐Woo Rhee、S.K. Tomar 等 4 位作者2009-07-28Journal of Thermoplastic Composite Materials

Formation of nanosized mixed semiconductor Pb x Cd 1 —x S in situ into PEO—polymer electrolyte matrix at room temperature is reported. The disperse phase was identified by X-ray diffraction analysis. Optical microscopy shows the increase in amorphicity with dispersal of semiconductor while scanning electron microscope…

Advanced Battery Materials and TechnologiesQuantum Dots Synthesis And PropertiesConducting polymers and applications

The route to single magnetic particle detection: a carbon nanotube decorated with a finite number of nanocubes

Irina Rod、Olga Kazakova、David Cox 等 5 位作者2009-07-28Nanotechnology

We propose an experimental technique that allows us a straightforward and reliable fabrication of magnetic and electromechanical nanodevices for single particle detection and characterization. We demonstrate three different experimental methods for fabrication of nanoscale devices consisting of either single or multiw…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

Converting an insulating silicon nanochain to a conducting carbon nanotube by electrical breakdown

Takafumi Nogami、Yutaka Ohno、Satoshi Ichikawa 等 4 位作者2009-07-28Nanotechnology

Electrical breakdowns of individual silicon nanochains, in which silicon nanoparticles are covered with and connected by oxide alternatively forming nanowires, are studied by in situ transmission electron microscopy using a microprobe system. Individual silicon nanochains can endure a current typically as large as 10(…

Carbon Nanotubes in CompositesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

SIX DEGREE-OF-FREEDOM MICROVIBRATION HYBRID CONTROL SYSTEM FOR HIGH TECHNOLOGY FACILITIES

Yong Wang、Hongjun Liu2009-07-28International Journal of Structural Stability and Dynamics

With the view to achieving a more perfect microvibration-free working environment for high technology equipment such as semiconductors and optical microscopes, the authors investigate the use of a 6-DOF microvibration hybrid control system to mitigate two types of vibration (ground motion and direct disturbance). This…

Vibration Control and Rheological FluidsMagnetic Properties and ApplicationsMagnetic Bearings and Levitation Dynamics

Porous polymer monolith templated by small polymer molecules

Zhiwang Wu、Kyle Frederic、Mark Talarico 等 4 位作者2009-07-28The Canadian Journal of Chemical Engineering

Abstract Porous poly(ethylene glycol) diacrylate (PEGDA) monoliths have been prepared by UV‐initiated polymerization of PEGDA oligomer ( M n = 700 g/mol). In the mean time, the addition of hydrophobic poly(propylene oxide) (PPO, M n = 725 g/mol) as porogen into an ethanol solution of PEGDA oligomer to form a homogenou…

Mesoporous Materials and CatalysisBlock Copolymer Self-AssemblyCovalent Organic Framework Applications

Slotless axial flux hysteresis motor, modelling and performance calculation

Ahmad Darabi、Teymoor Ghanbari、M. Sanati-Moghadam2009-07-28IET Electric Power Applications

Hysteresis motors are exciterless and brushless machines with outstanding characteristics such as constant torque and speed, robust structure, low and constant starting current and smooth operation. On the contrary, hysteresis machines have some usage limitations such as low power factor, efficiency and torque density…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsPiezoelectric Actuators and Control

High pressure dynamics of polymer/plasticizer mixtures

Gustavo A. Schwartz、Marian Paluch、Ángel Alegría 等 4 位作者2009-07-28The Journal of Chemical Physics

Plasticizers are usually added to polymers to give them the desired flexibility and processability by changing the dynamical properties of the polymer chains. It is therefore important to give a quantitative description about how the dynamic behavior of a given polymer is modified by the incorporation of a second comp…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Porous Structure of Ordered Silica with Cagelike Pores Examined by Successive Adsorption of Water and Nitrogen

Kunimitsu Morishige、Yoshinori Kanzaki2009-07-28The Journal of Physical Chemistry C

To examine the porous structure of ordered silica with cagelike pores, we measured successive adsorption of water at 283 K and nitrogen at 77 K on four kinds of SBA-16 and four kinds of KIT-5. For materials with smaller necks, we found the amount of nitrogen condensed inside the large cavities decreased rapidly with a…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisAerogels and thermal insulation

Adsorption isotherme de l’acide acétique par des charbons d’origine végétale

Jérôme Avom、JK Mbadcam、MRL Matip 等 4 位作者2009-07-28African Journal of Science and Technology

The adsorption properties of six samples of carbons of which two are obtained from AYOUS (Triplochiton Scléroxylon), two from AKOM (Terminalia Superba) and two obtained commercially were studied from their adsorption isotherms of acetic acid at 30° and 45°C. This study has resulted in the determination of the two type…

biodegradable polymer synthesis and propertiesMesoporous Materials and CatalysisAdsorption, diffusion, and thermodynamic properties of materials

Defect‐Enhanced Dispersion of Carbon Nanotubes in DNA Solutions

Jin Hee Kim、Masakazu Kataoka、Daisuke Shimamoto 等 11 位作者2009-07-28ChemPhysChem

Nanotubes wrapped up: In nanotube–DNA hybrid structures (see figure), defects on the sidewall of carbon nanotubes effects the dispersibility. DNA is helically wrapped around the nanotubes in an irregular pattern and structural defects on the sidewall of the nanotubes provide additional sites for binding with DNA.

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

Improved dispersion of clay platelets in poly(butylene terephthalate) nanocomposite by ring‐opening polymerization of cyclic oligomers: Effect of the processing conditions and comparison with nanocomposites obtained by melt intercalation

Corrado Berti、Enrico Binassi、Martino Colonna 等 7 位作者2009-07-28Journal of Applied Polymer Science

Abstract Poly(butylene terephthalate) nanocomposites with organically modified montmorillonites have been prepared by in‐situ ring opening polymerization of PBT cyclic oligomers. High molecular weight polymers can be obtained by choosing the proper polymerization conditions and catalyst in very short polymerization ti…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Oxidation Anisotropy and Size-Dependent Reaction Kinetics of Zinc Nanocrystals

Xiaofei Ma、Michael R. Zachariah2009-07-28The Journal of Physical Chemistry C

Nanosized Zn and ZnO particles have attracted considerable interest for their various potential applications. Zn can act as both the fuel and a working catalyst in the Zn/ZnO thermochemical solar water splitting cycle for hydrogen generation, and ZnO is an important semiconductor. In this work, we combine two differen…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Understanding the Force-vs-Distance Profiles of Terminally Attached Poly(N-isopropyl acrylamide) Thin Films

Sergio Mendez、Brett Andrzejewski、Heather E. Canavan 等 7 位作者2009-07-28Langmuir

In this work, we examine the interaction between thin films composed of terminally anchored poly(N-isopropyl acrylamide) (PNIPAAm) immersed in water and test surfaces. Understanding this force of interaction can be important when using PNIPAAm surfaces in biotechnological applications such as biological cell cultures.…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsNanofabrication and Lithography Techniques

Fabrication of Metal Oxide Nanoparticles by Highly Exothermic Reactions

Karen S. Martirosyan、Dan Luss2009-07-28Chemical Engineering & Technology

Abstract The development of two methods using highly exothermic oxidation reactions to synthesize nanostructured oxide particles is described. The first method uses solution combustion to produce a high temperature front that moves through the sample and produces the nanoparticles. For example, Bi 2 O 3 nanoparticles…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsCopper-based nanomaterials and applications