Materials Literature
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The intragrain pinning in high-$T_c$ superconductor compounds Y$_{1-x}$RE$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-δ}$ with low concentration of RE (La, Ce, Pr) was investigated. Magnetic and transport measurements reveal that the pinning is maximal for the concentration of heterovalent RE such that the average distance between the…
The difference in colour between emerald (Be3Si6Al2O18:Cr3+, green) and the Cr3+-doped spinel MgAl2O4 (red) is striking, considering that in both systems colour is due to CrO69- complexes with D3 symmetry and the measured Cr3+-O2- distance is practically the same (1.98 and 1.97 angstroms, respectively). By means of de…
Using a continuum model, expressions for the elastic energy, defect energy, structure entropy, and mixing entropy of carbon nanocones are proposed analytically. The optimal conformation of carbon nanocones is studied by imposing minimization of free energy and analyzing the effects that the buckling of a nanocone's wa…
In this paper we derive the general equilibrium equations of a polymer chain with a noncircular cross section by the variation of the free energy functional. From the equilibrium equation of the elastic ribbon we derive analytically the equilibrium conformations both of the helical ribbons and the twisted ribbons. We…
The optical properties of bulk $λ/2$ GaN microcavities working in the strong light-matter coupling regime are investigated using angle-dependent reflectivity and photoluminescence at 5 K and 300 K. The structures have an Al$_{0.2}$Ga$_{0.8}$N/AlN distributed Bragg reflector as the bottom mirror and either an aluminium…
Self-organizable dendronized helical polymers provide a suitable architecture for constructing molecular nanomachines capable of expressing their motions at macroscopic length scales. Nanomechanical function is demonstrated by a library of self-organized helical dendronized cis-transoidal polyphenylacetylenes ( cis-PP…
We report a general and facile approach for the fabrication of a new class of monodispersed, single-component and thick-walled polymer nanocapsules via the single-step assembly of macromolecules in solid core/mesoporous shell (SC/MS) silica particle templates, followed by cross-linking of the macromolecules and remova…
Our understanding of the biologic effects (including toxicity) of nanomaterials is incomplete. In vivo animal studies remain the gold standard; however, widespread testing remains impractical, and the development of in vitro assays that correlate with in vivo activity has proven challenging. Here, we demonstrate the f…
Magnesium-aluminum-chloride-layered double hydroxides (MgAl-Cl-LDHs) intercalated with low molecular weight heparin (LMWH) were prepared for the first time by the coprecipitation method and then characterized by XRD, elemental analysis, FTIR, SEM, and TEM. MgAl-LDH was studied as the drug carrier for LMWH, a widely us…
Nitrogen-rich carbon nitride (CN x , x >/= 1) network materials have been produced as disordered structures by a variety of precursor-based methods, many that involve solid-state thermolysis at or above 500 degrees C. One popular precursor building block is the triazine unit (C 3N 3), and most postulated amorphous CN…
Abstract ZnO films consisting of either polydisperse or monodisperse aggregates of nanocrystallites were fabricated and studied as dye‐sensitized solar‐cell electrodes. The results revealed that the overall energy‐conversion efficiency of the cells could be significantly affected by either the average size or the size…
Efficient carrier multiplication has been reported for several semiconductor nanocrystals: PbSe, PbS, PbTe, CdSe, InAs, and Si. Some of these reports have been challenged by studies claiming that carrier multiplication does not occur in CdSe, CdTe, and InAs nanocrystals, thus raising legitimate doubts concerning the o…
The fate of the charge-neutral Dirac point in graphene in a high magnetic field H has been investigated at low temperatures (T approximately 0.3 K). In samples with small gate-voltage offset V0, the resistance R0 at the Dirac point diverges steeply with H, signaling a crossover to a state with a very large R0. The app…
Metallic carbon nanotubes (CNTs) have received much attention for their unique characteristics as a possible alternative to Cu interconnects in future ICs. Until this date, while almost all fabrication efforts have been directed toward multiwalled CNT (MWCNT) interconnects, there is a lack of MWCNT modeling work. This…
The intrinsic transport properties of zigzag graphene nanoribbons (ZGNRs) are investigated using first-principles calculations. It is found that although all ZGNRs have similar metallic band structure, they show distinctly different transport behaviors under bias voltages, depending on whether they are mirror symmetri…
Metallic nanoparticles are among the most widely used types of engineered nanomaterials; however, little is known about their environmental fate and effects. To assess potential environmental effects of engineered nanometals, it is important to determine which species are sensitive to adverse effects of various nanoma…
Sub-10 nm wide graphene nanoribbon field-effect transistors (GNRFETs) are studied systematically. All sub-10 nm GNRs afforded semiconducting FETs without exception, with ${I}_{\mathrm{on}}/{I}_{\mathrm{off}}$ ratio up to ${10}^{6}$ and on-state current density as high as $\ensuremath{\sim}2000\text{ }\text{ }\ensurema…
The temperature evolution of the optical absorption edge of (NH 3 C 2 H 5 ) 2 CuCl 4 crystals has been investigated in the vicinity of their low temperature phase transitions. It was shown that the absorption edge in these materials possesses an exponential shape. In the temperature range below 65 K it follows the emp…
Summary Erosion/corrosion is a severe problem in oil and gas producing wells because of high flow velocity and sand particles entrained in the system. Using corrosion inhibitors to reduce erosion/corrosion has recently been proposed as an economically viable solution for carbon-steel piping systems (Smart 1991). In th…
The effect of adding rubber on the properties of glass-fibre-filled nylon 66 was investigated in this study. Styrene-Ethylene-Butylene-Styrene and Ethylene-Propylene elastomers grafted with maleic anhydride (SEBS-g-MA and EP-g-MA, respectively) were used to toughen the nylon-matrix composites. Impact strength and elon…