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Enhanced Spin Susceptibility toward the Charge-Ordering Transition in a Two-Dimensional Extended Hubbard Model

Kazuyoshi Yoshimi、Takeo Kato、Hideaki Maebashi2009-09-25Journal of the Physical Society of Japan

Based on the non-skeleton diagrammatic expansion satisfying the compressibility and spin-susceptibility sum rules, we investigate static charge and spin responses in a two-dimensional extended Hubbard model with the nearest-neighbor Coulomb repulsion in the vicinity of its charge-ordering transition point. In this exp…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

High Power SOFC Using LSGM Film on NiFe Porous Bi-metal Substrate

Young‐Wan Ju、Hiroyuki Eto、Toru Inagaki 等 4 位作者2009-09-25ECS Transactions

Sr and Mg doped LaGaO3 (LSGM) thin film was prepared on NiO-Fe2O3 bi-metal substrate by Pulsed Laser Deposition (PLD) method. Substrate preparation conditions were studied at different sintering temperatures in order to optimize the preparation condition for dense disk with smooth surface. By the thermal reduction, th…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Oxygen Reduction Kinetics and Transport Properties of (Ba,Sr)(Co,Fe)O3-δ and Related SOFC Cathode Materials

Lei Wang、Rotraut Merkle、Joachim Maier2009-09-25ECS Transactions

Oxygen surface reduction kinetics is studied with the help of impedance spectra measured on dense thin film microelectrodes of (Ba 1-x Sr x )(Co 1-y Fe y )O 3-δ (BSCF) and related SOFC cathode materials. Effective oxygen exchange rate constants k q , calculated from area-specific surface resistances R s extracted from…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Prediction of Surface Oxygen Vacancy Concentrations of (La1-xSrx)MnO3

Yueh‐Lin Lee、Dane Morgan2009-09-25ECS Transactions

Perovskite materials of the form ABO 3 are an important family of compounds for use in solid oxide fuel cell (SOFC) cathodes. In particular, their surface properties play an essential role in their catalytic ability. This paper combines bulk defect models fit to experimental data with ab initio surface energies to pre…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Texture Studies on Die-Upset Nd-Lean Nd-Fe-(Cu)-Ga-B Alloy

Hae-Woong Kwon、Ji‐Hun Yu2009-09-25IEEE Transactions on Magnetics

Melt-spun Nd-lean NdxFe93.5-xGa0.5B6(x = 9, 10.5 and 12) alloys were die-upset, and the Nd2Fe14B grain texture in the die-upset samples were investigated. The effect of Cu-addition on the texture of the die-upset Nd-lean NdxFe93.5-xGa0.5B6(x = 9, 10.5,and 12) alloys was studied, and the texture formation mechanism ope…

Rare-earth and actinide compoundsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Positively charged and pH self-buffering quantum dots for efficient cellular uptake by charge mediation and monitoring cell membrane permeability

Suhua Wang、Haipeng Song、Wei Yi Ong 等 5 位作者2009-09-25Nanotechnology

Positively charged and pH self-buffering quantum dots (Tren-QDs) were achieved by surface functionalization with tris(2-aminoethyl)amine (Tren) derivatives, which are attached to the inorganic cores of QDs through bidentate chelating of dithiocarbamates. The Tren-QDs exhibit pH buffering capability by absorbing or rel…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Al 13 H − : Hydrogen atom site selectivity and the shell model

Andrej Grubisic、X. Li、S. T. Stokes 等 10 位作者2009-09-25The Journal of Chemical Physics

Using a combination of anion photoelectron spectroscopy and density functional theory calculations, we explored the influence of the shell model on H atom site selectivity in Al(13)H(-). Photoelectron spectra revealed that Al(13)H(-) has two anionic isomers and for both of them provided vertical detachment energies (V…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsBoron and Carbon Nanomaterials Research

Dealloyed Nanoporous Metals for PEM Fuel Cell Catalysis

Jonah Erlebacher、Joshua Snyder2009-09-25ECS Transactions

Although the majority of PEM fuel cell catalysts are made of nanoparticles, similar surface area/volume, specific surface area, and precious metal loading can be made by using ultrathin (~100 nm) nanoporous metal membranes. We discuss here how ultrathin porous membranes can be made using electrochemical dealloying, an…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationNanoporous metals and alloys

Soft random solids and their heterogeneous elasticity

Xiaoming Mao、Paul M. Goldbart、Xiangjun Xing 等 4 位作者2009-09-25Physical Review E

Spatial heterogeneity in the elastic properties of soft random solids is examined via vulcanization theory. The spatial heterogeneity in the structure of soft random solids is a result of the fluctuations locked-in at their synthesis, which also brings heterogeneity in their elastic properties. Vulcanization theory st…

Material Dynamics and PropertiesTheoretical and Computational PhysicsComposite Material Mechanics

Crystalline three-dimensional cubic mesoporous niobium oxide

Lin Ye、Songhai Xie、Bin Yue 等 8 位作者2009-09-25CrystEngComm

A well-ordered three-dimensional (3D) cubic Ia3d mesoporous niobium oxide with amorphous wall is prepared under controlled humidity by a sol-gel method and further converted to crystalline 3D niobium oxide with the retention of its original mesoporous system.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Development of an Electromagnetic Wave Shielding Textile by Electroless Ni-Based Alloy Plating

Makoto Sonehara、Shujiro Noguchi、Tadashi KURASHINA 等 6 位作者2009-09-25IEEE Transactions on Magnetics

A polyester nonwoven textile with Ni-based alloy coating was fabricated, and the effect of electromagnetic wave shielding was evaluated. The Ni-based was coated by electroless plating on the textile. The electromagnetic wave shielding effect of the textile with Ni-B coating was about 99.98% over the induction range of…

Electromagnetic wave absorption materials

Development and Field Test Results of Residential SOFC CHP System

Minoru Suzuki、Shin Iwata、Katsuki Higaki 等 8 位作者2009-09-25ECS Transactions

At 2004, Osaka Gas Co., Ltd. and Kyocera Corporation launched joint development of residential SOFC CHP system. In order to fit Japanese urban market, we decided rated output of system as 700W and have reduced the size of a power generation. At rated power, ac 700W, net ac efficiency and hot water heat recovery effici…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Nonreciprocal Phase-Shift Composite Right/Left Handed Microstrip Lines Using Ferrite-Rod-Embedded Substrate

Tetsuya Ueda、Masahiro Akiyama2009-09-25IEEE Transactions on Magnetics

Nonreciprocal phase-shift composite right/left handed transmission lines with small nonreciprocity in the amplitude of the transmission coefficients are proposed. The present structures are composed of a microstrip line periodically loaded with series capacitance and shunt inductance, and a ferrite rectangular rod is…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsMicrowave Engineering and Waveguides

NMR Studies of the Hydrogen Storage Compound NaMgH3

David T. Shane、R. Corey、R. C. Bowman 等 8 位作者2009-09-25The Journal of Physical Chemistry C

Hydrogen and 23 Na NMR were performed to 400 °C on NaMgH 3 powder produced by reactive ball-milling of NaH and MgH 2 . The H resonance shows narrowing already at 100 °C as a narrow line superimposed on the broad, rigid-lattice signal. With increasing temperature, the fraction of spins in the narrow component grows smo…

Hydrogen Storage and MaterialsSuperconducting Materials and ApplicationsQuantum, superfluid, helium dynamics

Temperature Dependence of Magnetic Properties of CoAl$_{\rm x}$Fe$_{2-{\rm x}}$O$_{4}$

N. Ranvah、Ikenna C. Nlebedim、Yevgen Melikhov 等 7 位作者2009-09-25IEEE Transactions on Magnetics

The temperature dependence of magnetic properties of a series of aluminium-substituted cobalt ferrite, with the general composition of CoAlxFe2-xO4(x = 0, 0.1, 0.2, 0.5), has been studied. It was observed that the magnetization, at an applied field of mu0H = 5 T and a temperature of 10 K, does not change significantly…

Magnetic Properties and Synthesis of FerritesMagnetic Properties and ApplicationsIron oxide chemistry and applications

Design and methodology for evaluating aerodynamic characteristics of sports textiles

Harun Chowdhury、Firoz Alam、David E. Mainwaring 等 7 位作者2009-09-25Sports Technology

The material characteristics of textiles used in elite sports garments have been shown to exhibit a significant influence on both the sporting performance, as well as their aesthetics, particularly in those sports where aerodynamic resistance and its associated energy expenditure impact on winning times. The present s…

Textile materials and evaluations

Synthesis of Hybrid Gold/Iron Oxide Nanoparticles in Block Copolymer Micelles for Imaging, Drug Delivery, and Magnetic Hyperthermia

Dong‐Hyun Kim、Elena A. Rozhkova、Tijana Rajh 等 5 位作者2009-09-25IEEE Transactions on Magnetics

In our study, hybrid gold/iron oxide loaded thermoresponsive micelles were synthesized for combined hyperthermia and chemotherapy, and optical imaging. Polymeric micelles made of amphiphilic block copolymer of poly(N-isopropylacrylamide-co-acrylamide)-block-poly(epsiv-caprolactone) were conjugated with gold/iron oxide…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsCharacterization and Applications of Magnetic Nanoparticles

Solution-processible fabrication of large-area patterned and unpatterned gold nanostructures

Xinping Zhang、Hongmei Liu、Shengfei Feng2009-09-25Nanotechnology

Solution-processible fabrication of large-area plasmonic nanostructures using colloidal gold nanoparticles has proven its advantages not only in its simplicity, low cost, high speed, and high flexibility, but also in the realization of some nanoscale optoelectronic devices that cannot be achieved by conventional metho…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

A2MO4+δ Oxides: Flexible Electrode Materials for Solid Oxide Cells

Jean Claude Grenier、Fabrice Mauvy、Cécile Lalanne 等 8 位作者2009-09-25ECS Transactions

Until now, most cathode materials used in high temperature ceramic solid electrolyte oxide cells (SEOC) are perovskite-type MEIC compounds, AMO3-δ, showing oxygen sub-stoichiometry. Recently, a new family of overstoichiometric oxides, formulated A2MO4+δ with A = La, Nd, Pr, Sr and M = Ni, Cu, has been investigated. Du…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsCatalysis and Oxidation Reactions

Colorless polyimide nanocomposite films containing hexafluoroisopropylidene group

Il Hwan Choi、Jin‐Hae Chang2009-09-25Polymers for Advanced Technologies

Abstract Poly(amic acid) (PAA) was prepared by the reaction of 4,4'‐(hexafluoro‐isopropylidene)diphthalic anhydride (6FDA) with 2,2'‐bis[4‐(4‐aminophenoxy)phenyl] hexafluoropropane (BAPP) in N , N ‐dimethylacetamide (DMAc). Hybrid films were obtained from blend solutions of the precursor polymer and the organoclay Clo…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry