D. S. Chiu、Zhanpeng Zhang、G. G. Siu1996-01-01Journal of Reinforced Plastics and Composites
Thermoplastic elastomers, e.g., EPR, EPDM etc., are commonly used as modifiers of the ductility of PP, PE, HDPE or other general purpose thermoplastics. The objective of this study is to develop a high performance PP/HDPE/SBS polymer blend which possesses excellent toughness and strength equivalent to those of more ex…
Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties
Sun De、Priyankari Bhattacharya1996-01-01TAPPI Journal
Recovery of water with inorganic compounds in kraft black liquor was studied by pressure carbonation followed by different combinations of membrane separation processes. Experiments were carried out to observe the effect of carbonation on black liquor, in terms of conversion of lignin-bound alkali compounds into carbo…
Advanced Cellulose Research StudiesLignin and Wood Chemistry
Claire J. Carmalt、John Crossley、Nicholas C. Norman 等 4 位作者1996-01-01Chemical Communications
EXAFS data for amorphous Ph3SbO are consistent with a structure in which trigonal-bipyramidal SbPh3O2 units share their axial oxygens to form a chain kinked at the oxygen atoms.
Luminescence Properties of Advanced MaterialsGlass properties and applicationsX-ray Diffraction in Crystallography
John Evans、Martyn Pillinger、Jacqueline M. Rummey1996-01-01Journal of the Chemical Society Dalton Transactions
Extended X-ray absorption fine structure (EXAFS) spectroscopy has been used to characterise polyoxometalates of the type MmOyn– and XxMmOyn– in the solid state and in solution. The best fit to the low-temperature (80 K) niobium K-edge EXAFS of K7[HNb6O19]·13H2O was obtained with one terminal oxygen at 1.79 Å(M–Ot), fo…
Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization
M.K. Lü、Fanqing Meng、Zhe Yang 等 5 位作者1996-01-01Crystal Research and Technology
Abstract A new organic UV nonlinear optical crystal urea‐(DL)tartaric acid [CO(NH 2 ) 2− (DL) C 4 H 6 O 6 ] (abbreviated as U(DL)T) is reported. Large single crystals have been grown from aqueous solution by the cooling method. They belong to the monoclinic space group P2 1 and the lattice parameters are: a = 7.6973 Å…
Crystal structures of chemical compoundsCrystallography and molecular interactionsNonlinear Optical Materials Research
Kathleen A. Carrado、S.R. Wasserman1996-01-01Chemistry of Materials
The Cu(II) and Fe(III) complexes of water-soluble tetrakis( N, N, N -trimethylanilinium)porphyrin (TTAP) and tetrakis( N -methylpyridyl)porphyrin (TMPyP) were placed within the interlayers of Ca(II)−montmorillonite through ion exchange. The free base forms of the porphyrins were also added to samples of Cu(II)− and Fe…
Porphyrin and Phthalocyanine ChemistryIron oxide chemistry and applicationsSurface Chemistry and Catalysis
Jean‐Luc Blin、Annick Rubbens、F. Wallart 等 4 位作者1996-01-01Journal of Materials Chemistry
A previous investigation of EuVO4–BtVO4 binary system has indicated the existence of a solid-solution of Eu1–xBixVO4 up to x= 0.60, with a zircon-type structure. In this work we have reinvestigated the synthesis conditions, thus extending the upper limit to x= 0.74. X-Ray diffraction techniques associated with Raman a…
Luminescence Properties of Advanced MaterialsGlass properties and applicationsAdvanced Condensed Matter Physics
Stephen D. Evans、H. Allinson、N. Boden 等 4 位作者1996-01-01Faraday Discussions
Self-assembled monolayers of alkanethiol derivatives have been used to control the anchoring of nematic films of alkylcyanobiphenyl (nCB) liquid crystals. Variation of the surface field, via the ω-functional group presented at the liquid crystal interface, has allowed us to explore both orientational wetting and ancho…
Liquid Crystal Research AdvancementsSpectroscopy and Quantum Chemical StudiesElectrowetting and Microfluidic Technologies
Hiroshi Mitomo、Tetsuya Sasaoka、Fumio Yoshii 等 5 位作者1996-01-01Sen i Gakkaishi
A typical hydrophilic monomer, acrylic acid (AAc), was graft polymerized onto poly (3-hydroxybutyrate) (PHB) and its copolymer poly (3-hydroxybutyrate-co-3-hydroxyvalerate) |P (HB-HV)| by 60Co-γ-rays preirradiation technique. Degree of grafting (Xg) of PHB was higher than that of the copolymer of 24 mol% HV content (2…
biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications
H. N. McMurray1996-01-01Cronfa (Swansea University)
A scanning reference electrode technique (SRET) is described which is sufficiently stable and sensitive as to allow the automatic acquisition of time lapse isopotential contour maps of localised corrosion phenomena occurring in contact with molar concentrations of aqueous electrolyte. The SRET is demonstrated to be a…
Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityNon-Destructive Testing Techniques
Masaki Nishiyama、Akira Isogai、Fumihiko Onabe1996-01-01Sen i Gakkaishi
Alkenyl succinic anhydride (ASA) gives sizing features efficiently to papersheet by being added to pulp suspensions as cationic ASA emulsions. Although the reactive structure of ASA is necessary for paper sizing, the previous paper revealed that alkenyl succinic acid (ASAcid), the hydrolyzed form of ASA, is the predom…
Advanced Cellulose Research StudiesMaterial Properties and Processing
Joseph M. Thomas、F. Kaufman1996-01-01The Journal of Physical Chemistry
The concentration of the product nitric oxide, [NO(X 2 Π r )] product, formed in the title reactions is measured as a function of the vibrational energy distribution in the for v‘ ≤ 6 in a rapidly pumped discharge-flow reactor at ∼298 K and a total pressure of ∼2 Torr using laser-excited fluorescence techniques. For t…
Atmospheric chemistry and aerosolsCatalytic Processes in Materials ScienceSpectroscopy and Laser Applications
Richard W. Strange、Loretta M. Murphy、Göran Karlsson 等 5 位作者1996-01-01Biochemistry
A pH-dependent X-ray absorption fine structure (XAFS) study has been undertaken to provide a structural interpretation of the spectroscopic properties of the Met121 Glu mutant of azurin from Pseudomonas aeruginosa (Azp). Ligand binding studies have been carried out to investigate the effect of the cavity formed at the…
Glycosylation and Glycoproteins ResearchEnzyme Structure and FunctionEnzyme Production and Characterization
Jiřı́ Brus、Jiří Karhan、Petr Kotlı́k1996-01-01Collection of Czechoslovak Chemical Communications
29 Si NMR spectrometry has been used to determine the number molecular weight distribution of polymerization degrees of a system of oligomers formed in the sol-gel polycondensation of tetraethoxysilane (TEOS). On the basis of identification of the oligomers, monitoring of the concentration changes during the initial p…
Polyoxometalates: Synthesis and ApplicationsSilicone and Siloxane ChemistryChemical Synthesis and Characterization
Noriko Yoshizawa、Y. Yamada、Minoru Shiraishi 等 5 位作者1996-01-01Journal of the Chemical Society Faraday Transactions
A fine pore characterization method for less-crystalline porous solids has been applied to activated carbons. In the analysis, the microporosity of the solid was classified into effective micropores and inaccessible pores, depending upon the accessibility of the pore to an N2 molecule at 77 K. The volume fraction of e…
Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisAerogels and thermal insulation
M.A. Rahman、R. Qin1996-01-01IEEE Transactions on Industry Applications
This paper presents the design, analysis, and application of permanent magnets in a hysteresis motor with a view to improve the overall performance of such motors. The novel rotor consists of 36% cobalt steel alloys with neodymium boron iron permanent magnets. This hybrid design combines the advantageous performance f…
Electric Motor Design and AnalysisMagnetic Properties and ApplicationsMagnetic Properties of Alloys
Hülya Kırkıcı、M.F. Rose、T. Chaloupka1996-01-01IEEE Transactions on Dielectrics and Electrical Insulation
A low-mass solution to electrical insulation in the lunar environment may be possible by embedding bare HV conductors within the lunar soil itself. In the paper, a 'standard' NASA soil (lunar simulant) representing chemical and physical conditions found in some lunar samples was used in laboratory experiments, and its…
Ionosphere and magnetosphere dynamicsHigh voltage insulation and dielectric phenomenaGeophysical and Geoelectrical Methods
A. Hynes、M. J. Shenton、J. P. S. Badyal1996-01-01Macromolecules
The plasma polymerization of a variety of substituted perfluorocyclohexane monomers (perfluorocyclohexane, perfluoromethylcyclohexane, perfluoro-1,2-dimethylcyclohexane, perfluoro-1,3-dimethylcyclohexane, and perfluoro-1,3,5-trimethylcyclohexane) is systematically compared under identical experimental conditions. The…
Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsSilicone and Siloxane Chemistry
Frank Lutz、Robert Bau、Ping Wu 等 6 位作者1996-01-01Inorganic Chemistry
The structure of the complex [(η5-Cp*)Co]2H3, a compound once believed to have an unsupported CoCo double bond, has been accurately determined with single-crystal neutron diffraction techniques. The arrangement of three hydrogen atoms in an equilateral triangle bridging the cobalt−cobalt bond, first revealed in an X-r…
Organometallic Complex Synthesis and CatalysisHydrogen Storage and MaterialsAsymmetric Hydrogenation and Catalysis
Miguel Á. Vicente、Miguel Angel Bañares-Muñoz、Mercedes Suárez 等 7 位作者1996-01-01Langmuir
A high iron content saponite from Griffith Park, CA, (griffithite variety) was pillared by aluminum polycation solutions with different Al/clay ratios. X-ray diffraction shows that the intercalation process begins when aluminum polycation solutions are added, being completed during the dialysis washing of the samples.…
Mesoporous Materials and CatalysisClay minerals and soil interactionsIron oxide chemistry and applications