Materials Literature
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The effect of water on the morphology of BaO/Al 2 O 3 -based NO x storage materials was investigated using Fourier transform infrared spectroscopy, temperature programmed desorption, and time-resolved synchrotron X-ray diffraction techniques. The results of this multispectroscopy study reveal that in the presence of w…
Polarization techniques have been implemented to determine the size and shape of LaF 3 core−shell nanoparticles in aqueous colloidal solutions, by studying the optical properties of the Eu 3+ active ion inserted as a dopant in the core of the nanoparticles. A luminescence anisotropy as high as 0.4 has been measured fo…
The thermodynamic and kinetic factors that determine the localization of carbon black particles at interfaces in polymer blends were established. Substantial differences in particle localization conditions at the interfaces of two high-molecular-mass or low-molecular-mass liquids were revealed; these differences are m…
Detailed experimental studies are described for reactions of several nitrogen oxides with iron porphyrin models for heme/NxOy systems. It is shown by FTIR and optical spectroscopy and by isotope labeling experiments that reaction of small increments of NO2 with sublimed thin layers of the iron(II) complex Fe(Por) (Por…
Neutron reflectometry was used to investigate the structures of end-tethered protein resistant polymer layers based on poly(oligo(ethylene glycol) methyl ether methacrylate) [poly(OEGMA)] and poly(2-methacryloyloxyethyl phosphorylcholine) [poly(MPC)]. Layers having different graft densities were studied in both the dr…
A mechanistic study of chloroboron subphthalocyanine (SubPc) formation from phthalonitrile and BCl 3 in aromatic solvents such as p-xylene or toluene suggests that rearrangement of the initial phthalonitrile- BCl 3 adduct produces (1 Z )-3-chloro-N-(dichloroboryl)-1 H -isoindol-1-imine 3, following rearrangement of th…
Abstract Low density polyethylene (LDPE) composites based on cellulose fibres have been processed by high shear extrusion with water injection to help dispersion of fibres and release nanofibres from cellulose. Influence of extrusion parameters as shear, residence time, storage conditions of the matrix, and effect of…
Lead-free tetragonal tungsten bronze Sr2LaTi2Nb3O15 ceramics were prepared and its crystal structure determined. Dielectric response of Sr2LaTi2Nb3O15 was investigated in a broad frequency (100 Hz–90 THz) and temperature range. The observed relaxor-like behavior can be generally described in the framework of polar nan…
Abstract The present contribution reports the electrospinning of PS/MEH‐PPV fibers with average diameters ranging from 0.165 to 1.190 µm from solutions of PS/MEH‐PPV (PS/MEH‐PPV = 7.5:1, w/w) in 1,2‐dichloroethane. With the addition of pyridinium formate (PF), a volatile organic salt, to the PS/MEH‐PPV solution, the e…
Abstract We have developed a flame‐retardant polycarbonate resin whose flame retardancy is greatly enhanced by adding fly ash (a by‐product from thermal power plants). Fly ash with comparatively small average particle sizes (<10 µm) raised the flame retardancy of polycarbonate because of the hydrogen bond that form…
Abstract Various segmented polyurethanes with a hard segment content of about 50 wt% were prepared from 4,4′‐diphenylmethane diisocyanate (MDI), a poly(tetramethylene adipate) glycol with an M n of 2000, and various combinations of aliphatic diols as chain extenders by a one‐shot, hand‐cast bulk polymerization method.…
Abstract Spinel cobalt oxide doped with nickel and zinc are deposited using a CVD reactor equipped with a pulsed spray evaporation system. This process allows easy control of the film composition through the adjustment of the composition of the liquid feedstock; a linear dependence is observed in both cases. Doped spi…
AZ31 Mg alloy samples were processed by equal channel angular pressing (ECAP) at 220°C for four passes. An average grain size of ∼1·9 μm with reasonable homogeneity was obtained. The ECAP process imparted large plastic shear strains and strong deformation textures to the material. Subsequent annealing of the equal cha…
The Raman spectrum of 5wt% yttria-stabilized tetragonal zirconia from 25to1250°C is reported. All six Raman bands broaden and shift toward lower energy with increasing temperature. The shift associated with thermally induced volume changes is shown to be the main contribution for all bands, but does not explain the un…
Abstract Large nanomembranes, which are characterized by aspect ratios (size/thickness) of greater than one million, are described. The combination of nanometer thickness and macroscopic size facilitates important applications in materials separation, selective transport and electrochemical devices. In the past, only…
Abstract Novel composites based on poly(ε‐caprolactone) (PCL) and an organically modified layer double hydroxide (LDH) obtained using the melt‐extrusion technique have been characterized through structural, thermal, and mechanical analyses. Although exfoliation has not been achieved and despite the very low content of…
We describe experimental difficulties, and associated artefacts, that arose during the study of thin epitaxial films of the proposed multiferroic materials BiFeO3 and BiMnO3. The problems experienced include large leakage currents and charge injection from Nb-doped SrTiO3 substrates used as bottom electrodes. Charge i…
Silver nanoparticles have drawn extensive attention as biomaterial components. Human fibroblasts were grown on various concentrations of silver nanoparticles during the period observation. Normal viability (0% silver particles) was increased from 6 to 72 hours, increasing the amount of human fibroblasts (1.5 × 10 4 to…
Edible films of gelatin and corn zein were prepared by incorporating nisin to the film-forming solutions. Corn zein film with nisin of 12,000 IU/ml had an increase of 11.6 MPa in tensile strength compared with the control, whereas gelatin film had a slight increase with the increase of nisin concentration added. Water…
Abstract A simple method to embed noble metal (Ag, Au) nanoparticles in organic–inorganic nanocomposite films by single step method is described. This is accomplished by the assistance of Keggin ions present in the composite film. The photochemically reduced composite film has served both as a reducing agent and host…