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Epitaxial Growth of ϵ-Fe2O3 on Mullite Found through Studies on a Traditional Japanese Stoneware

Yoshihiro Kusano、Tatsuo Fujii、Jun Takada 等 7 位作者2007-12-11Chemistry of Materials

In the course of our study on a Japanese traditional stoneware called “Bizen”, we have found that ϵ-Fe 2 O 3, which has been classically known but recently limelighted for its magnetic potentiality, crystallizes epitaxially on needlelike crystals of mullite, 3(Al,Fe) 2 O 3 ·2SiO 2 . This interesting reaction occurred…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsIron oxide chemistry and applications

Photostability of quantum dots with amphiphilic polymer-based passivation strategies

Dawn Nida、Nitin Nitin、William W. Yu 等 5 位作者2007-12-11Nanotechnology

Quantum dots (QDs) have many appealing properties for biological fluorescence imaging, but exhibit photostabilities that are dependent upon surface passivation to minimize susceptibility to oxygen and light. Here, through spectroscopy and imaging techniques, we compare the photostability of micelle-encapsulated QDs wi…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Variable narrow-band transmission filters for spectrometry from space 2 Fabrication process

A. Piegari、Jiri Bulir、Anna Sytchkova2007-12-11Applied Optics

The optical components described here are variable narrow-band transmission filters, where the transmittance peak varies with the position along the surface of the filter itself. They allow the construction of ultracompact and low-weight spectrometers for space applications. The theoretical behavior of graded filters…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Optical Analysis of Beads Encoded with Quantum Dots Coated with a Cationic Polymer

Claudine Nì. Allen、Nicolas Lequeux、Christophe Chassenieux 等 5 位作者2007-12-11Advanced Materials

Quantum dots are incorporated onto small beads made of various materials thanks to the versatile layer-by-layer method. The high contrast, tri-color gradient TEM image of a bead emphasizes quantum dots in red-yellow spots. Below, quantum dot coated magnetic beads demonstrate bimodality with their bright fluorescence a…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesNear-Field Optical Microscopy

Interfacial Reactions in Glass–Ceramic‐to‐Metal Seals

Ian W. Donald、Brian L. Metcalfe、L.A. Gerrard2007-12-11Journal of the American Ceramic Society

During the sealing of glass–ceramics to metals, undesirable interfacial reactions may occur between constituents of the glass and diffusing metal species, and any reaction products formed may have serious consequences on the lifetime behavior of seal components. This paper reviews the factors influencing the lifetime…

Advanced ceramic materials synthesisGlass properties and applicationsNuclear materials and radiation effects

In Situ Heating TEM Study of Onion-like WS2and MoS2Nanostructures Obtained via MOCVD

Nicole Zink、Helen Annal Therese、Julien Pansiot 等 6 位作者2007-12-11Chemistry of Materials

We report on the in situ heating transmission electron microscopy (TEM) study of WS 2 and MoS 2 nanoparticles obtained from metal–organic chemical vapor deposition (MOCVD). The general behavior of MoS 2 and WS 2 is similar: Round, amorphous particles in the pristine sample transform to hollow, onion-like particles upo…

Electrocatalysts for Energy Conversion2D Materials and ApplicationsMXene and MAX Phase Materials

Decoration of amyloid fibrils with luminescent conjugated polymers

Anna Herland、Daniel Thomsson、Oleg Mirzov 等 5 位作者2007-12-11Journal of Materials Chemistry

In this work we report the coating of a biological template with a polar, but uncharged, luminescent conjugated polymer, soluble in organic solvents but not in water, to produce a nanowire. Amyloid fibrils from bovine insulin were decorated with an alternating polyfluorene derivative. Decorated fibrils were partially…

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

Functional Faceted Silver Nano-Hexapods: Synthesis, Structure Characterizations, and Optical Properties

Xiaohua Liu、Rui Huang、Jing Zhu2007-12-11Chemistry of Materials

We report a new application of the polyol process to produce silver nanohexapods (AgNHs) with a well-defined concave shape and a unique crystal structure. The structure was studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), selected-area electron diffraction (SAED), and high-resolution electron…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Monoclinic Ferroelastic Domains in LaCoO3‐Based Perovskites

Per Erik Vullum、Randi Holmestad、Hilde Lea Lein 等 6 位作者2007-12-11Advanced Materials

In addition to the well known ferroelastic domains formed by deformation twinning in rhombohedral perovskites, a monoclinic structure is observed by transmission electron microscopy in LaCoO3-based materials. The monoclinic domains consist of a one-dimensional superstructure corresponding to doubling or tripling of th…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Maximum Rate of Crystallization and Morphology of Random Propylene Ethylene Copolymers as a Function of Comonomer Content up to 21 mol %

Kanghoon Jeon、Ysela Chiari、Rufina G. Alamo2007-12-11Macromolecules

We report a study of the primary chain microstructure, crystallization kinetics, and crystalline morphologies of propylene ethylene copolymers (PE) synthesized with metallocene catalysts in a range of ethylene up to 21 mol %. A 13 C NMR triad distribution analysis lends support for a random distribution of the comonom…

Organometallic Complex Synthesis and CatalysisPolymer crystallization and propertiesbiodegradable polymer synthesis and properties

Ice‐Templating of Core/Shell Microgel Fibers through ‘Bricks‐and‐Mortar’ Assembly**

Qiang Shi、Zesheng An、Chia‐Kuang Tsung 等 7 位作者2007-12-11Advanced Materials

A ‘bricks-and-mortar’ assembly approach can be used to create well- defined fibers on the microscale with alternating organic-inorganic arrangement through a simple ice-templating strategy. The fibers are constructed from closely packed monodisperse inorganic nanoparticles@PNIPAm core/shell microgels. A series of func…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdvanced Materials and Mechanics

Enthalpy and Anisotropy Relaxation of Glass Fibers

Min Ya、Joachim Deubener、Yuanzheng Yue2007-12-11Journal of the American Ceramic Society

Optical birefringence and calorimetric studies have been conducted with respect to structural relaxation of E‐glass (a type of calcium–alumosilicate glass system) fibers. Upon fiber drawing, the liquid of E‐glass is thermally hyperquenched and mechanically stretched. Hyperquenching (cooling rate >10 6 K/min) leads…

Material Dynamics and PropertiesGlass properties and applicationsTheoretical and Computational Physics

Effects of Joint Vibrational States on Thermal Boundary Conductance

Patrick E. Hopkins、Pamela M. Norris2007-12-11Nanoscale and Microscale Thermophysical Engineering

The accuracy of predictions of the thermal boundary conductance (hBD ) made using traditional models such as the diffuse mismatch model (DMM) varies depending on the types of material comprising the interface. At interfaces of materials with very different material properties, the discrepancy between the measured hBD…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Near-Infrared Laser-Induced Photothermal Coloration in WO3·H2O Nanoflakes

Yuping He、Yiping Zhao2007-12-11The Journal of Physical Chemistry C

The structure and chromic properties of WO 3 ·H 2 O nanoflakes have been investigated in situ by Raman spectroscopy and optical transmission under 785-nm laser irradiation with different powers. At a small power below 48 mW, the characteristic stretching vibrations of orthorhombic WO 3 ·H 2 O at ν 1 ≈ 650 cm -1 (W 6+…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsPhotoacoustic and Ultrasonic Imaging

Multiple Functionalization of Mesoporous Silica in One‐Pot: Direct Synthesis of Aluminum‐Containing Plugged SBA‐15 from Aqueous Nitrate Solutions

Zhenyu Wu、H. J. Wang、Tingting Zhuang 等 6 位作者2007-12-11Advanced Functional Materials

Abstract Aluminum‐containing plugged mesoporous silica has been successfully prepared in an aqueous solution that contains triblock copolymer templates, nitrates, and silica sources but without using mineral acid. The acidity of the solution can be finely tuned from pH 1.4 to 2.8 according to the amount of the introdu…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisCovalent Organic Framework Applications

Optical‐Fiber‐Mounted Porous Silicon Photonic Crystals for Sensing Organic Vapor Breakthrough in Activated Carbon

Bruce H. King、Anne M. Ruminski、J. L. Snyder 等 4 位作者2007-12-11Advanced Materials

An electrochemically fabricated 1D photonic crystal of porous Si displaying a single reflectance peak is coupled to an optical fiber and embedded in activated carbon to sense the breakthrough of organic vapors (see figure). The sensor responds to various organic vapors, demonstrating filter end-of- service-life applic…

Gas Sensing Nanomaterials and SensorsSilicon Nanostructures and PhotoluminescenceGa2O3 and related materials

l-Glutamic Acid Precipitation: Agglomeration Effects

Christian Lindenberg、Jochen Schöll、Lars Vicum 等 5 位作者2007-12-11Crystal Growth & Design

In this work, the effect of agglomeration on the final particle size distribution is investigated for batch precipitation processes carried out in stirred tank reactors. Agglomeration kinetics of α l -glutamic acid was determined based on seeded batch experiments by a combination with a population balance model and an…

Coagulation and Flocculation StudiesMinerals Flotation and Separation TechniquesCrystallization and Solubility Studies

Bluish-White Emission from Radical Carbonyl Impurities in Amorphous Al2O3 Prepared via the Pechini-Type Sol−Gel Process

Cuikun Lin、Min Yu、Ziyong Cheng 等 6 位作者2007-12-11Inorganic Chemistry

Many efforts have been devoted to exploring novel luminescent materials that do not contain expensive or toxic elements, or do not need mercury vapor plasma as the excitation source. In this paper, amorphous Al2O3 powder samples were prepared via the Pechini-type sol-gel process. The resulting samples were characteriz…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSilicon Nanostructures and Photoluminescence

Ramie fibre: part I. Chemical composition and chemical properties. A critical review of recent developments

S. N. Pandey2007-12-11Textile Progress

The monograph deals with a critical review of the recent research work and development on ramie, a long vegetable bast fibre. The review is divided into two parts. Part I discusses the progress of recent work on ramie, chemical components like fibre degumming, its effects on fibre composition, chemical constituents, i…

Food composition and propertiesNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

A Novel Heterostructure of Co3O4/ZnO Nanowire Array Fabricated by Photochemical Coating Method

Youngjo Tak、Kijung Yong2007-12-11The Journal of Physical Chemistry C

We developed a facile solution-based synthetic route for the fabrication of two different types of novel Co 3 O 4 /ZnO nanowire heterostructures: tip-coated array type and fully coated horizontal (or colloidal) type. Two-step solution-based methods were used for the fabrication of the Co 3 O 4 /ZnO nanowire heterostru…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsNanowire Synthesis and Applications