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Phase structure and electrical properties of 0.8Pb(Mg1/3Nb2/3)O3–0.2PbTiO3 relaxor ferroelectric ceramics prepared by the reaction‐sintering method

Chenlu Ding、Bijun Fang、Qingbo Du 等 4 位作者2009-12-08physica status solidi (a)

Abstract Phase pure perovskite 0.8Pb(Mg 1/3 Nb 2/3 )O 3 –0.2PbTiO 3 (0.8PMN–0.2PT) ferroelectric (FE) ceramics were prepared by the reaction‐sintering method at a sintering temperature range of 1200–1250 °C. The sintered ceramics exhibit large relative density, where the 0.8PMN–0.2PT ceramics sintered at 1250 °C posse…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Graft copolymerization modification of silk fabric with an organophosphorus flame retardant

Guan Jinping、Chen Guo-qiang2009-12-08Fire and Materials

Abstract This paper mainly deals with flame retardance of a silk fabric treated with a vinyl phosphate dimethyl 2‐(methacryloyloxyethyl) phosphate (DMMEP) onto silk fabric by a graft copolymerization technique. This paper also explores the relationship between limiting oxygen index (LOI) and weight gain of DMMEP treat…

Polymer composites and self-healingFlame retardant materials and propertiesThermal and Kinetic Analysis

Structure of the first representative of Pfam family PF09410 (DUF2006) reveals a structural signature of the calycin superfamily that suggests a role in lipid metabolism

Hsiu‐Ju Chiu、Constantina Bakolitsa、Arne Skerra 等 41 位作者2009-12-08Acta Crystallographica Section F Structural Biology and Crystallization Communications

The first structural representative of the domain of unknown function DUF2006 family, also known as Pfam family PF09410, comprises a lipocalin-like fold with domain duplication. The finding of the calycin signature in the N-terminal domain, combined with remote sequence similarity to two other protein families (PF0714…

Photosynthetic Processes and MechanismsEnzyme Structure and FunctionATP Synthase and ATPases Research

New Challenge for Classics: Neutral Zinc Complexes Stabilised by 2,2’-Bipyridine and 1,10-Phenanthroline and Their Application in the Ring-Opening Polymerisation of Lactide

J. Borner、Ülrich Flörke、Artjom Döring 等 6 位作者2009-12-08Sustainability

The zinc acetato and triflato complexes of 2,2’-bipyridine and 1,10-phenanthroline were prepared and completely characterised. The whole series (including the already described dichlorido complexes and the ligands themselves) were screened for their catalytic activity in the solvent free ring-opening polymerisation of…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Corrosion study of the X52 steel immersed in seawater with a corrosion inhibitor using a rotating cylinder electrode

Ricardo Galván-Martínez、Ricardo Orozco-Cruz、Roal Torres-Sánchez 等 4 位作者2009-12-08Materials and Corrosion

Abstract A corrosion study of API X52 steel was carried out in natural seawater with several concentrations of a corrosion inhibitor (10, 100 and 200 ppm) using a rotating cylinder electrode (RCE) to control the hydrodynamic conditions at environment temperature, atmospheric pressure and 24 h of the exposition time. T…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityNon-Destructive Testing Techniques

Transport in a magnetic field modulated graphene superlattice

Yu‐Xian Li2009-12-08Journal of Physics Condensed Matter

Using the transfer matrix method, we study the transport properties through a magnetic field modulated graphene superlattice. It is found that the electrostatic barrier, the magnetic vector potential, and the number of wells in a superlattice modify the transmission remarkably. The angular dependent transmission is bl…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Sunnhemp Fiber-reinforced Waste Polyethylene Bag Composites

Surya Nath Chaudhary、Shashikant. P. Borkar、S. S. Mantha2009-12-08Journal of Reinforced Plastics and Composites

The present article expounds the development of sunnhemp fiber-reinforced waste polyethylene bag composites. No surface modifications of fibers were made. Sunnhemp fibers of 25.4 mm in length with waste polyethylene bags were stacked and composite materials were fabricated using hot compression molding technique. Thes…

Natural Fiber Reinforced CompositesMechanical Engineering and Vibrations Research

Mechanical Properties of Nanolaminate Ti 3 SnC 2 Carbide Determined by Nanohardness Cartography

C. Tromas、Nadia Ouabadi、Véronique Gauthier‐Brunet 等 5 位作者2009-12-08Journal of the American Ceramic Society

Nanoindentation is used to measure hardness of Ti 3 SnC 2 , a recently synthesized nanolaminate carbide. Hardness cartography and optical microscopy are used to correlate hardness values and sample phases. An indentation size effect is observed, and a bulk hardness of 9.3 GPa is deduced for Ti 3 SnC 2 . Such a value i…

Metal and Thin Film MechanicsMXene and MAX Phase MaterialsAdvanced materials and composites

Free-Standing Mesoporous Silica/Carbon Composite Films with Crystalline Silica Wall from Ethylene-Bridged Organosilane

Sung Soo Park、Yuin Jung、Chunfeng Xue 等 6 位作者2009-12-08Chemistry of Materials

Free-standing periodic mesoporous organosilica (PMO) films were grown at the interface of an ethylene-bridged organosilica and surfactant template via a self-assembly process. After the pyrolysis of the PMO films with ethylene-bridged organosilica moieties in the pore walls under an Ar flow at temperatures ranging fro…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Nanocrystalline LaOCl:Tb^3+/Sm^3+ as promising phosphors for full-color field-emission displays

Guogang Li、Chunxia Li、Zhiyao Hou 等 6 位作者2009-12-08Optics Letters

Nanocrystalline LaOCl:Tb(3+)/Sm(3+) phosphors were synthesized by a Pechini-type sol-gel process. Under UV and electron-beam excitation, LaOCl:Tb(3+)/Sm(3+) show the characteristic emission of Tb(3+) ((5)D(3,4)-->(7)F(6),...2) and Sm(3+) ((4)G(5/2)-->(6)H(5/2,7/2,9/2)), respectively. In particular, the cathodoluminesc…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsLuminescence and Fluorescent Materials

Stability, elastic and electronic properties of palladium nitride

W Chen、John S. Tse、J.Z. Jiang2009-12-08Journal of Physics Condensed Matter

The crystal structure, stability, elastic constants and electronic properties of PdN(2) for four polymorph structures: pyrite, marcasite, CoSb(2) and ST(AA), have been investigated using first-principles calculations. At zero pressure all four polymorphs are metallic and thermodynamically unstable but mechanically sta…

Boron and Carbon Nanomaterials ResearchMXene and MAX Phase MaterialsInorganic Chemistry and Materials

Isothermal differential scanning calorimetry study of a glass/epoxy prepreg

Mehran Hayaty、Mohammad Hosain Beheshty、Masoud Esfandeh2009-12-08Polymers for Advanced Technologies

Abstract Isothermal differential scanning calorimetry (DSC) was used to study the curing behavior of epoxy prepreg Hexply®1454 system, based on diglycidyl ether of bisphenol A (DEGBA)/dicyandiamid (DICY) reinforced by glass fiber. Cure kinetics of an autocatalytic‐type reaction were analyzed by general form of convers…

Epoxy Resin Curing ProcessesThermal and Kinetic AnalysisPolymer Synthesis and Characterization

Imidazole Based Biocompatible Polymer Coating in Deriving <25 nm Functional Nanoparticle Probe for Cellular Imaging and Detection

Nikhil R. Jana、Pranab K. Patra、Arindam Saha 等 5 位作者2009-12-08The Journal of Physical Chemistry C

Although synthetic methods for high quality near-monodispersed nanoparticles of metal and semiconductor are well established, their conversion into various functional nanoparticles is challenging. We report here an imidazole based polymer coating that can be used in deriving <25 nm diameter water-soluble functional na…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And Properties

Immunoassay on Free-Standing Electrospun Membranes

Dapeng Wu、Daewoo Han、A. J. Steckl2009-12-08ACS Applied Materials & Interfaces

For the purpose of immunoassay, electrospun membranes can be thought as the threadlike self-assembling of nano/microbeads. Nonwoven membranes of electrospun poly(epsilon-caprolactone) (PCL) fibers display excellent tenacity, flexibility and suitable surface energy. These PCL membranes exhibit easy handling in air, fas…

Advanced biosensing and bioanalysis techniquesAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Pressure-induced phase transitions in ferroelectric Bi2MoO6—a Raman scattering study

Mirosław Mączka、Paulo Freire、C. Luz‐Lima 等 6 位作者2009-12-08Journal of Physics Condensed Matter

A high pressure Raman scattering study of Bi(2)MoO(6), a member of the bismuth layered Aurivillius family of ferroelectrics, is presented. This study showed the onset of two reversible second-order phase transitions near 2.8 and 7.0 GPa. The pressure dependence of the Raman bands provides strong evidence that the stru…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsSolid-state spectroscopy and crystallography

Novel Shape‐Memory Materials Based on Potato Starch

Cyril Véchambre、Laurent Chaunier、Denis Lourdin2009-12-08Macromolecular Materials and Engineering

Abstract Shape‐memory properties such as shape fixity and recovery ratio of amorphous starch‐based materials extruded under normal conditions were evaluated for the case of single and cyclic recovery processing. This study focused on the effect of moisture as a stimulus for the activation of recovery. A high recovery…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesPolymer composites and self-healing

Silica‐Supported Silver Nanoparticles with Surface Oxygen Species as a Reusable Catalyst for Alkylation of Arenes

Ken‐ichi Shimizu、Yuji Miyamoto、Atsushi Satsuma2009-12-08ChemCatChem

Abstract A series of silica‐supported silver catalysts with various Ag loading (3–30 wt %) and different treatment (oxidation and subsequent reduction by H 2 ) were prepared, and their local structures were characterized by extended X‐ray absorption fine structure (EXAFS) analysis. In oxidized catalysts, silver were m…

Catalytic Processes in Materials ScienceAsymmetric Hydrogenation and CatalysisNanomaterials for catalytic reactions

Dendronized polymers via Diels–Alder “click” reaction

Murat Tonga、Nergiz Cengiz、Meliha Merve Kose 等 5 位作者2009-12-08Journal of Polymer Science Part A Polymer Chemistry

Abstract A modular approach toward the synthesis of polymers containing dendron groups as side chains is developed using the Diels–Alder “click” reaction. For this purpose, a styrene‐based polymer appended with anthracene groups as reactive side chains was synthesized. First through third‐generation polyester dendrons…

Chemical Synthesis and AnalysisClick Chemistry and ApplicationsDendrimers and Hyperbranched Polymers

Preparation and Unique pH‐Responsive Properties of Novel Biodegradable Nanocapsules Composed of Poly(γ‐glutamic acid) and Chitosan as Weak Polyelectrolytes

Takayuki Imoto、Toshiyuki Kida、Michiya Matsusaki 等 4 位作者2009-12-08Macromolecular Bioscience

Novel biodegradable hollow nanocapsules composed of two kinds of weak polyelectrolytes, CT and gamma-PGA, were successfully prepared by the deposition of their LbL-assembled films onto silica particles and the subsequent removal of the silica. These CT-gamma-PGA hollow nanocapsules showed unique size increases at pH =…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesBiopolymer Synthesis and Applications

Molecular Rotors Based on the Boron Dipyrromethene Fluorophore

Andrew C. Benniston、Anthony Harriman、Victoria L. Whittle 等 4 位作者2009-12-08European Journal of Organic Chemistry

Abstract In order to examine how changes in the size of the rotary group affect the efficacy of molecular probes for monitoring changes in local viscosity, a boron dipyrromethene dyebearing a meso ‐phenanthrene unit has been synthesized and fully characterized. 19 F NMR spectroscopy, together with molecular modelling,…

Molecular Sensors and Ion DetectionConducting polymers and applicationsLuminescence and Fluorescent Materials