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Giant reversible anisotropic magnetocaloric effect in an antiferromagnetic EuFe2As2 single crystal

M. S. Kim、N. H. Sung、Yoonkook Son 等 5 位作者2011-04-25Applied Physics Letters

Here, we report the characterization of a giant reversible anisotropic magnetocaloric effect in a EuFe2As2 single crystal. The magnetic properties of EuFe2As2 single crystals are quite interesting; they display a small magnetic hysteresis, anisotropy, and a first-order magnetic phase transition. The maximum magnetic e…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsIron-based superconductors research

Identification of a myeloid‐derived suppressor cell cystatin‐like protein that inhibits metastasis

Angela M. Boutté、David Friedman、Matthew Bogyo 等 6 位作者2011-04-25The FASEB Journal

Myeloid-derived suppressor cells (MDSCs) are significantly increased in cancer patients and tumor bearing-animals. MDSCs infiltrate into tumors and promote tumor invasion and metastasis. To identify the mediator responsible for the prometastatic property of MDSCs, we used proteomics. We found neutrophilic granule prot…

Nanoparticle-Based Drug DeliveryProtease and Inhibitor MechanismsImmune cells in cancer

Self crimped and aligned fibers

Senthilram Thinakaran、L. Amalorpava Mary、Jayarama Reddy Venugopal 等 6 位作者2011-04-25Materials Today

Electrospinning is one of the most successful means of producing nanofibers with enormous application potential. New methods of producing nanofibers without high voltages are presently being explored by researchers around the globe. In the present work, a facile method of producing aligned and crimped fibers with poly…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Electrical current mediated interconversion between graphene oxide to reduced grapene oxide

Hao Fatt Teoh、Yi Tao、Eng Soon Tok 等 5 位作者2011-04-25Applied Physics Letters

In this work, we demonstrate that graphene oxide (GO) can be reversibly converted to reduced-graphene-oxide (rGO) through the use of electric current. Strong electric field could cause ionization of water molecules in air to generate H+ ions at cathode, causing GO to be reduced. When the bias is reversed, the same ele…

Graphene research and applicationsCarbon and Quantum Dots ApplicationsGraphene and Nanomaterials Applications

Microelectrochemical Investigation of Hydrogen Absorption and Dissolution Behavior of MnS Inclusions in Carbon Steel

Izumi Muto、Jun Shinozaki、Tomohiko Omura 等 5 位作者2011-04-25ECS Transactions

Microelectrochemical polarization and silver decoration techniques were performed on the small area with and without MnS inclusions. MnS inclusions were found to be partially dissolved in the potential range from 0.15 to -0.45 V (vs. Ag/AgCl, 3.33 M KCl) in a boric-borate buffer (pH 8.45) with 10 mM NaCl, whereas the…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsElectrodeposition and Electroless Coatings

Essential aspects of Negative Bias Temperature Instability (NBTI)

Ahmad E. Islam、Souvik Mahapatra、Shweta Deora 等 5 位作者2011-04-25ECS Transactions

We develop a comprehensive theoretical framework for explaining the key and characteristic experimental signatures of NBTI. The framework is based on an uncorrelated dynamics of interface-defect creation/annihilation described by Reaction-Diffusion (R-D) theory and hole trapping/detrapping into/out-of oxide defects ba…

Textile materials and evaluations

Multiscale Simulation of Electro-Chemo-Mechanical Coupling Behavior of PEN Structure under SOFC Operation

Kenjiro Terada、‪Tatsuya Kawada、Kazuhisa Sato 等 13 位作者2011-04-25ECS Transactions

Numerical simulations are performed to characterize the micro- and macro-scale aspects of the electro-chemo-mechanical coupling behavior of a positive-electrolyte-negative (PEN) structure under SOFC operation. The mathematical homogenization method is applied to evaluate the macroscopic material properties of porous e…

Corrosion Behavior and InhibitionFuel Cells and Related MaterialsMaterial Properties and Processing

Intravalley multiple scattering of quasiparticles in graphene

J. Y. Vaishnav、Justin Q. Anderson、Jamie D. Walls2011-04-25Physical Review B

We develop a theoretical description of intravalley scattering of quasiparticles in graphene from multiple short-range scatterers of size much greater than the carbon-carbon bond length. Our theory provides a method to rapidly calculate the Green's function in graphene for arbitrary configurations of scatterers. We de…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Defect-induced multicomponent electron scattering in single-walled carbon nanotubes

Dario Bercioux、Gilles Buchs、Hermann Grabert 等 4 位作者2011-04-25Physical Review B

We present a detailed comparison between theoretical predictions on electron scattering processes in metallic single-walled carbon nanotubes with defects and experimental data obtained by scanning tunneling spectroscopy of Ar${}^{+}$ irradiated nanotubes. To this purpose, we first develop a formalism for studying quan…

Carbon Nanotubes in CompositesGraphene research and applicationsChemical and Physical Properties of Materials

Patterning with Amorphous Carbon Thin Films

G. A. Antonelli、Sirish K. Reddy、Pramod Subramonium 等 11 位作者2011-04-25ECS Transactions

Amorphous carbon hard mask films grown with plasma enhanced chemical vapor deposition are an enabling technology for advanced front-end-of-line patterning technologies. These films must have a low etch rate and be weakly roughened in dielectric etch chemistries, high transparency at lithography alignment wavelengths,…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchPlasma Diagnostics and Applications

Elasticity of Dispersions Based on Carbon Nanotubes Dissolved in a Lyotropic Nematic Solvent

Franco Tardani、Camillo La Mesa2011-04-25The Journal of Physical Chemistry C

Single-walled carbon nanotubes were dispersed in a nematic solvent, made of sodium dodecyl sulfate, decanol, and water. Fine and homogeneous dispersions were obtained, depending on the preparation procedures and on the weight percent of carbon nanotubes in that solvent. Modifications in optical textures were compared…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

In search of energy landscape for network glasses

R. Golovchak、A. Kovalskiy、O. Shpotyuk 等 4 位作者2011-04-25Applied Physics Letters

Quick scanning extended x-ray absorption fine-structure spectroscopy is used to obtain in situ structural information on the real-time response of network glasses at the nanoscale level of atomic organization to the temperature ramp through the glass transition range. The results testify nonlinear, real-time temperatu…

Material Dynamics and PropertiesTheoretical and Computational PhysicsPhase-change materials and chalcogenides

High-temperature thermoelectric properties of Cu2Ga4Te7 with defect zinc-blende structure

Theerayuth Plirdpring、Ken Kurosaki、Atsuko Kosuga 等 9 位作者2011-04-25Applied Physics Letters

Here we show the high-temperature thermoelectric (TE) properties of Cu2Ga4Te7 with the defect zinc-blende structure in which one-seventh of the cation sites are structural vacancies. Cu2Ga4Te7 exhibited relatively low electrical resistivity (ρ) and thermal conductivity (κ) and moderate positive Seebeck coefficient (S)…

Quantum Dots Synthesis And PropertiesAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

Redox-Rich Spin–Spin-Coupled Semiquinoneruthenium Dimers with Intense Near-IR Absorption

Tanaya Kundu、Biprajit Sarkar、Tapan Kumar Mondal 等 9 位作者2011-04-25Inorganic Chemistry

Using the [RuCl(μ-tppz)ClRu](2+) [tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine] platform for bridging two o-quinone/catecholate two-step redox systems (unsubstituted, Q(n), or 3,5- di-tert-butyl-substituted, DTBQ(n)), we have obtained the stable complexes [(Q(•-))Ru(II)Cl(μ-tppz)ClRu(II)(Q(•-))] (1) and the structurally…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesInorganic Chemistry and Materials

Effect of surface passivation on dopant distribution in Si quantum dots: The case of B and P doping

Jie Ma、Su‐Huai Wei、Nathan R. Neale 等 4 位作者2011-04-25Applied Physics Letters

Despite many efforts, the doping behavior in Si quantum dots (QDs) is still not well understood. Theoretical work shows that boron as an acceptor prefers to stay near the surface and phosphorous as a donor may stay close to the center in a perfectly hydrogen passivated QD. However, experiment studies seem suggesting a…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceSemiconductor materials and interfaces

Synthesis and self‐assembly of thermotropic block copolymer with long alkyl tethered cage silsesquioxane in the side chain

Yoshihito Ishida、Tomoyasu Hirai、Raita Goseki 等 6 位作者2011-04-25Journal of Polymer Science Part A Polymer Chemistry

Abstract Thermotropic POSS‐containing poly(methacrylate) with long alkyl chain tethered polyhedral oligomeric silsesquioxane (POSS) in the side chain and the block copolymers (PMMA‐b‐PMAC11POSS) were developed by through living anionic polymerization. The resulting polymers indicated a phase transition temperature at…

Advanced Polymer Synthesis and CharacterizationBlock Copolymer Self-AssemblySynthesis and properties of polymers

Cadmium resisting bacteria in Alexandria Eastern Harbor (Egypt) and optimization of cadmium bioaccumulation by Vibrio harveyi

Abd Elnaby Hanan、Malia Gehan、A El Sersy Nermeen2011-04-25AFRICAN JOURNAL OF BIOTECHNOLOGY

Cadmium resisting bacteria (CRB) were present in all water and sediments (samples) collected from Alexandria Eastern Harbor, Egypt. The occurrences of CRB in sediments samples were higher than in water samples and reached up to 77.22% of total counts. Five isolates were selected to be the most resistant to cadmium wit…

Nanoparticles: synthesis and applications

Production of Sustainable Fuels by Means of Solid Oxide Electrolysis

John Bøgild Hansen、N. Christiansen、Jens Ulrik Nielsen2011-04-25ECS Transactions

Electrolysis by means of Solid Oxide Cells (SOC) offers unique possibilities with respect to production of sustainable fuels from carbon dioxide and steam. High temperature waste heat can be utilized to reduce the consumption of electric power and the ability to co-electrolyze carbon dioxide and steam makes it possibl…

Advancements in Solid Oxide Fuel CellsZeolite Catalysis and SynthesisMolten salt chemistry and electrochemical processes

Enhancement of Epoxidation Efficiencies for Ta-SBA15 Catalysts. The Influence of Modification with –EMe 3 (E = Si, Ge, Sn) Groups

Paul J. Cordeiro、T. Don Tilley2011-04-25Langmuir

Site-isolated Ta(V) centers were introduced onto the surface of a mesoporous SBA-15 support via the thermolytic molecular precursor method. After thermal treatment under oxygen, the resulting Si-OH and Ta-OH sites of TaSBA15-O(2)were modified with a series of trimethyl group 14 species, Me(3)E-, by treatment with Me(3…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Performance of a 10 kW SOFC Demonstration Unit

Matias Halinen、Markus Rautanen、Jaakko Saarinen 等 10 位作者2011-04-25ECS Transactions

Experimental results of the performance of a solid oxide fuel cell (SOFC) unit are presented. The unit was designed, manufactured and tested at the VTT Technical Research Centre of Finland. The 10 kW power class SOFC stack and stack module were designed and manufactured by Versa Power Systems (VPS). A successful commi…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials