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Combined Kinetic Analysis of Solid-State Reactions: A Powerful Tool for the Simultaneous Determination of Kinetic Parameters and the Kinetic Model without Previous Assumptions on the Reaction Mechanism

Luis A. Pérez‐Maqueda、J. M. Criado、Pedro E. Sánchez‐Jiménez2006-10-21OpenAlex

The combined kinetic analysis implies a simultaneous analysis of experimental data representative of the forward solid-state reaction obtained under any experimental conditions. The analysis is based on the fact that when a solid-state reaction is described by a single activation energy, preexponetial factor and kinet…

Energetic Materials and CombustionThermal and Kinetic AnalysisChemistry and Chemical Engineering

Photoreversibly Switchable Superhydrophobic Surface with Erasable and Rewritable Pattern

Ho Sun Lim、Joong Tark Han、Donghoon Kwak 等 5 位作者2006-10-21OpenAlex

We report the facile fabrication of a functional nanoporous multilayer film with wettability that is reversibly tunable between superhydrophobicity and superhydrophilicity with UV/visible irradiation. Our approach controls surface roughness with an electrostatic self-assembly process and makes use of the photoresponsi…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdhesion, Friction, and Surface Interactions

Preparation and Optical Characterization of Mesoporous Silica Films with Different Pore Sizes

Jae Young Bae2006-10-20Bulletin of the Korean Chemical Society

Mesoporous silica films with three different pore sizes were prepared by using cationic surfactant, non-ionic surfactant, or triblock copolymer as structure directing agents with tetramethylorthosilicate as silica source in order to control the pore size and wall thickness. They were synthesized by an evaporation-indu…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsAerogels and thermal insulation

Phosphorylated copolymers containing pendant, crosslinkable spiro orthoester moieties

Judit Canadell、Barry J. Hunt、A. G. Cook 等 5 位作者2006-10-20Journal of Polymer Science Part A Polymer Chemistry

Abstract The synthesis of a novel spiro orthoester containing monomer, 1,4,6‐trioxaspiro[4.4]‐2‐nonylmethyl acrylate, is presented. This monomer was polymerized via a free‐radical system to yield the homopolymer and a series of copolymers with phosphorus‐containing comonomers. Diethyl vinyl phosphonate, allyldiphenylp…

Flame retardant materials and propertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Physical and Mechanical Properties of Iron Powder Filled Polystyrene Composites

Münir Taşdemi̇r、H. Özkan Gülsoy2006-10-20Polymer-Plastics Technology and Engineering

This article reports on an experimental study of the physical and mechanical properties of Polystyrene (PS) and Fe-PS polymer composites containing 5, 10, and 15 vol.% of Fe powder. After mixing Fe powder and PS in a twin-screw extruder, an injection-molding machine was used to prepare unfilled PS and Fe-PS polymer co…

Natural Fiber Reinforced CompositesInjection Molding Process and PropertiesPolymer Foaming and Composites

Forced Hydrolysis vs Self-Hydrolysis of Zinc Acetate in Ethanol and Iso-butanol

Geonel Rodríguez‐Gattorno、Gerko Oskam2006-10-20ECS Transactions

In the present work we have explored the synthesis of ZnO nanoparticles in two different alcohols, using an alkali- alcohol (forced hydrolysis) or water-alcohol mixture (self- hydrolysis) as source of OH- for initiation of the condensation reactions. Characterization of the particle size was accomplished by means of U…

ZnO doping and propertiesQuantum Dots Synthesis And Properties

Studies on the Thermal and Mechanical Properties of Foamed Wood-Polymer Composites

Satyendra Mishra、J. Verma2006-10-20Polymer-Plastics Technology and Engineering

Wood flour-polypropylene foamed composites, in ratios of 10:90, 20:80, 30:70, and 40:60 (wt./wt.), were prepared with and without maleic anhydride treatment of wood flour and maleic anhydride-grafted PP (MAgPP). The effects of the amount of wood flour and its treatment on the morphology, the mechanical properties, and…

Natural Fiber Reinforced CompositesPolymer composites and self-healingPolymer Foaming and Composites

Novel graft copolymer containing a polyallene backbone and poly(tert‐butyl acrylate) side chains

Xiaohuan Zhang、Dan Peng、Guolin Lu 等 5 位作者2006-10-20Journal of Polymer Science Part A Polymer Chemistry

A series of novel, well-defined graft copolymers with polyallene-based backbones and poly(tert-butyl acrylate) side chains were synthesized by the combination of the living coordination polymerization of 6-methyl-1,2-heptadiene-4-ol (MHDO) and the atom transfer radical polymerization (ATRP) of tert-butyl acrylate. Fir…

Advanced Polymer Synthesis and CharacterizationSynthetic Organic Chemistry MethodsCovalent Organic Framework Applications

Power Output Improvement of Silicon-Germanium Thermoelectric Generators

Martin Wagner、G. Span、Stefan M. Holzer 等 6 位作者2006-10-20ECS Transactions

We present a technology for thermoelectric generators using large area pn-junctions. Thermally generated carriers are separated by the gradient of the built-in potential caused by the pn-junction. The use of these structures for waste heat recovery implies an externally applied temperature gradient in-plane with the p…

Advanced Thermoelectric Materials and DevicesMolecular Junctions and NanostructuresAdvanced Thermodynamics and Statistical Mechanics

Giant isotope effect and spin state transition induced by oxygen isotope exchange in(Pr1−xSmx)0.7Ca0.3CoO3

Guoyu Wang、Xianhui Chen、Tao Wu 等 6 位作者2006-10-20Physical Review B

We systematically investigate the effect of the oxygen isotope in $({\mathrm{Pr}}_{1\ensuremath{-}x}{\mathrm{Sm}}_{x}{)}_{0.7}{\mathrm{Ca}}_{0.3}{\mathrm{CoO}}_{3}$ which shows a crossover with $x$ from ferromagnetic metal to the insulator with spin-state transition. A striking feature is that effect of oxygen isotope…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Effects of internal structural parameters on the properties of Ba-substitutedLa0.5Sr0.5MnO3

O. Chmaissem、B. Da̧browski、S. Koleśnik 等 6 位作者2006-10-20Physical Review B

A series of barium substituted ${\mathrm{La}}_{0.5}{\mathrm{Sr}}_{0.5\ensuremath{-}x}{\mathrm{Ba}}_{x}\mathrm{Mn}{\mathrm{O}}_{3}$ materials has been synthesized and investigated using neutron powder diffraction. We show that Ba substitution suppresses the low-temperature orbital ordering that has been previously obse…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Synthesis, characterization and properties of photoresponsive polymers comprising photocrosslinkable pendant chalcone moieties

M. Tamilvanan、A. Pandurangan、Boreddy S. R. Reddy 等 4 位作者2006-10-20Polymer International

Abstract New methacrylate monomers, namely 4‐methacryloyloxyphenyl‐4′‐fluorostyryl ketone and 4‐methacryloyloxyphenyl‐4′‐ethylstyryl ketone comprising a free radical polymerizable group and a photocrosslinkable group, were synthesized by reacting the respective hydroxychalcones with methacryloyl chloride in the presen…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersPhotopolymerization techniques and applications

Effect of Talc Filler on Physical Properties of Polyurethane Rigid Foams

Mir Mohammad Alavi Nikje、Amir Bagheri Garmarudi、Moslem Haghshenas2006-10-20Polymer-Plastics Technology and Engineering

This article reports on the properties of polyurethane rigid foams, which are used as insulating materials. Most polyurethane rigid foams, derived from cellular polymers, are unstable and tend to crack when acted upon by external forces. These foams are classified as a subgroup of cellular polymers, and thus their low…

Polymer composites and self-healingWind and Air Flow StudiesPolymer Foaming and Composites

Thermoluminescence emission from localized recombination model

C.M. Sunta、Munish Kumar、R.K. Kher 等 4 位作者2006-10-20Journal of Physics D Applied Physics

A simple model of thermoluminescence (TL), in which the trap and the recombination centre exist in the same defect complex, is assumed. It is called the localized recombination model (LRM). The analytical expression derived for this model turns out to be of first order irrespective of whether the system is recombinati…

Photochemistry and Electron Transfer StudiesThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Nonisothermal Crystallization Modeling and Simulation for Polypropylene/Nano CaSO4 Composites with Variations in Nanosizes and Wt.% of Loading

Satyendra Mishra、Arindam Mukherji、D.K. Sharma2006-10-20Polymer-Plastics Technology and Engineering

Avrami and Ozawa's combined analysis was employed to study the nonisothermal crystallization kinetics of Polypropylene (PP): CaSO4 (of 12 and 22 nm) composites using a Differential Scanning Calorimeter (DSC). The parameters, such as Avrami's exponent (n) and growth rate constant (Zt), that characterized the system of…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Solid–liquid transitions of sodium chloride at high pressures

Qi An、Lianqing Zheng、Rongshan Fu 等 5 位作者2006-10-20The Journal of Chemical Physics

We investigate solid-liquid transitions in NaCl at high pressures using molecular dynamics simulations, including the melting curve and superheating/supercooling as well as solid-solid and liquid-liquid transitions. The first-order B1-B2 (NaCl-CsCl type) transition in solid is observed at high pressures besides contin…

High-pressure geophysics and materialsMaterial Dynamics and Propertiesnanoparticles nucleation surface interactions

Low Temperature Void Free Hydrophilic or Hydrophobic Silicon Direct Bonding

Frank Fournel、H. Moriceau、R. Beneyton2006-10-20ECS Transactions

For both hydrophilic and hydrophobic surface preparation, using the combination of advanced surface treatment and tuned annealing process, void free Si/Si direct bonding have been successfully obtained. The pre-bonding procedure involves only low temperature (<500{degree sign}C) treatment in order to be compatible…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdhesion, Friction, and Surface Interactions

Grafting Short Peptides onto Polybutadiene‐block‐poly(ethylene oxide): A Platform for Self‐Assembling Hybrid Amphiphiles

Yan Geng、Dennis E. Discher、Justyna Justynska 等 4 位作者2006-10-20Angewandte Chemie

Durch das Anbinden eines hydrophoben Peptids an Polybutadien-block-polyethylenoxid verschieben sich die Morphologien des Systems in Wasser zu solchen mit geringerer Krümmung – von kugelförmigen Micellen zu wurmartigen Micellen und Vesikeln (siehe Bild; PBD=Polybutadien, PEO=Polyethylenoxid, wEO: Gewichtsanteil des hyd…

Advanced Polymer Synthesis and CharacterizationChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials

Oligodeoxynucleotide nanostructure formation in the presence of polypropyleneimine dendrimers and their uptake in breast cancer cells

Alex M. Chen、Latha M. Santhakumaran、Sandhya K. Nair 等 7 位作者2006-10-20Nanotechnology

Oligodeoxynucleotide nanostructure formation in the presence of polypropyleneimine dendrimers and their uptake in breast cancer cells, Chen, Alex M, Santhakumaran, Latha M, Nair, Sandhya K, Amenta, Peter S, Thomas, Thresia, He, Huixin, Thomas, T J

Advanced biosensing and bioanalysis techniquesRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Densification of silica glass at ambient pressure

Lianqing Zheng、Qi An、Rongshan Fu 等 5 位作者2006-10-20The Journal of Chemical Physics

We show that densification of silica glass at ambient pressure as observed in irradiation experiments can be attributed to defect generation and subsequent structure relaxation. In our molecular dynamics simulations, defects are created by randomly removing atoms, by displacing atoms from their nominal positions in an…

Geological and Geochemical AnalysisGlass properties and applicationsNuclear materials and radiation effects