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On the Chemla effect in molten alkali nitrates

Mauro C. C. Ribeiro2002-07-01The Journal of Chemical Physics

The Chemla effect concerns the strong composition dependence of the internal ionic mobilities of cations in mixtures of two molten salts with a common anion, in which the mobility of the large cation can be higher than the small one at low concentrations of the latter. Molecular dynamics simulations of molten (Li,Cs)N…

Advanced Battery Materials and TechnologiesGlass properties and applicationsSolid-state spectroscopy and crystallography

Electromagnetic Interference Shielding Effectiveness of Hybrid Conductive Polymer Composite

Narayan Chandra Das、Dipak Khastgir、T. K. Chaki 等 4 位作者2002-07-01Journal of Elastomers & Plastics

Electromagnetic interference (EMI) shielding characteristics of ethylene vinyl acetate (EVA) and ethylene propylene diene (EPDM) and their 50: 50 blend filled with conductive carbon black and short carbon fibre (SCF) have been studied. The measurements of shielding effectiveness (SE) were carried out in two different…

Natural Fiber Reinforced CompositesElectromagnetic wave absorption materialsFiber-reinforced polymer composites

Dye-sensitized solar cells based on nanocrystalline TiO2 sensitized with a novel pyridylquinoline ruthenium(ii) complex

Masatoshi Yanagida、Ashraful Islam、Yasuhiro Tachibana 等 7 位作者2002-07-01New Journal of Chemistry

[NBu4]2n[cis-Ru(H2−ndcpq)2(NCS)2] {n = 0 or 1; H2dcpq = 4-carboxy-2-[2′-(4′-carboxypyridyl)]quinoline} were newly synthesized, and their photophysical and photovoltaic properties were characterized and compared with those of [NBu4]2n[cis-Ru(H2−ndcbiq)2(NCS)2] (H2dcbiq = 4,4′-dicarboxy-2,2′-biquinoline) and [NBu4]2n[ci…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in Catalysis

Effect of Silicon Content on the Corrosion Properties of Calcium-Modified Weathering Steel in a Chloride Environment

K. Y. Kim、Yongtaek Hwang、Jae‐Young Yoo2002-07-01CORROSION

The effect of Si on the corrosion properties of Ca-modified weathering steel was evaluated with respect to the formation behavior of complex inclusions in the steel and the dissolution behavior of the inclusions in thin water film by pH measurement and electrochemical impedance spectroscopy (EIS). To understand the lo…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Microstructure and magnetic characteristics of low-temperature-fired modified Z-type hexaferrite with Bi/sub 2/O/sub 3/ additive

Hongguo Zhang、Ji Zhou、Yongli Wang 等 6 位作者2002-07-01IEEE Transactions on Magnetics

We have investigated the effect of Bi/sub 2/O/sub 3/ additive on the densification, low-temperature firing, and magnetic characteristics of modified Z-type Ba/sub 3/Co/sub 2/(1-x-y)Zn/sub 2x/Cu/sub 2y/Fe/sub 23.5/O/sub 41/ hexaferrite. Our results show that Bi/sub 2/O/sub 3/ additive not only improves the densificatio…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesMagnetic Properties and Applications

Transport and magnetic properties of Ca3−xSrxCo4O9

L. B. Wang、A. Maignan、D. Pelloquin 等 5 位作者2002-07-01Journal of Applied Physics

Ca 3−x Sr x Co 4 O 9 (x=0,0.5,1.0) samples were prepared by solid state reaction. As expected from the radii of Sr2+ and Ca2+, the cell parameters increase with Sr content x. Simultaneously, the resistivity and the carrier localization at low temperature are enhanced. The thermoelectric power is not sensitive to the S…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Ion-conductive liquid crystals: Formation of stable smectic semi-bilayers by the introduction of perfluoroalkyl moieties

Koji Hoshino、Kiyoshi Kanie、Toshihiro Ohtake 等 8 位作者2002-07-01Macromolecular Chemistry and Physics

Liquid-crystalline compounds 1 and 3 having perfluoroalkyl-terminated mesogens at both ends of poly(ethylene oxide) chains have been prepared. These compounds show smectic A (SA) and C phases over 100 °C. The SA-Iso (isotropic) transition temperatures are higher by about 70 °C than those of the corresponding alkyl-sub…

Liquid Crystal Research AdvancementsIonic liquids properties and applicationsSurfactants and Colloidal Systems

Development of a Flax/Polypropylene Composite with Optimal Mechanical Characteristics by Fiber and Matrix Modification

Kathleen Van de Velde、Paul Kiekens2002-07-01Journal of Thermoplastic Composite Materials

Dew retted hackled long flax was treated with propyltrimethoxysilane, phenylisocyanate and maleic acid anhydride modified polypropylene (MAA-PP). The results of these treatments on fiber wetting and interfacial properties have already been reported in a previous article [Van de Velde, K. and Kiekens, P. (2001). J. The…

Natural Fiber Reinforced CompositesElectromagnetic wave absorption materialsFiber-reinforced polymer composites

Surface structures of poly[(R)-3-hydroxybutyrate] and its copolymer single crystals before and after enzymatic degradation with an extracellular PHB depolymerase

Tadahisa Iwata、Masakatsu Shiromo、Yoshiharu Doi2002-07-01Macromolecular Chemistry and Physics

Lamellar single crystals of poly[(R)-3-hydroxybutyrate] (P(3HB)) with three types of molecular weights and four kinds of P(3HB) copolymers with different secondary monomer units were grown from dilute solutions of chloroform and ethanol under isothermal crystallization conditions. The surface morphologies of all the s…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Cathodic Reactivity of Platinum and Palladium in Electrolytes in Superdry Conditions

Charles Cougnon、Jacques Simonet2002-07-01Platinum Metals Review

Platinum and Palladium behave in an unexpected manner when cathodically polarised in the presence of electrolytes dissolved in carefully dried polar organic solvents, such as N,N-dimethylformamide. A reductive layer is formed on the metal the thickness of which depends on the amount of electricity consumed during the…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesAdvanced Materials Characterization Techniques

Assessment of intergranular corrosion in AISI Type 316L stainless steel weldments

H. Shaikh、B.P.C. Rao、Satyapriya Gupta 等 8 位作者2002-07-01British Corrosion Journal

This paper deals with the applicability of various techniques for the assessment and quantification of sensitisation in AISI Type 316L welds. Welded joints of AISI Type 316L stainless steel were aged at 973 K for periods of up to 200 h. The base and weld metal components of the aged joints were then assessed for susce…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Three-dimensional Structure of Human γ-Glutamyl Hydrolase

Hongmin Li、Thomas J. Ryan、Karen J. Chave 等 4 位作者2002-07-01Journal of Biological Chemistry

gamma-Glutamyl hydrolase catalyzes the cleavage of the gamma-glutamyl chain of folylpoly-gamma-glutamyl substrates and is a central enzyme in folyl and antifolyl poly-gamma-glutamate metabolism. The crystal structure of human gamma-glutamyl hydrolase, determined at 1.6-A resolution, reveals that the protein is a homod…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismCancer Research and Treatments

Thermal Quenching of Thermoluminescence in Natural Quartz

Rashmi Nanjundaswamy、Kenneth Lepper、S.W.S. McKeever2002-07-01Radiation Protection Dosimetry

The thermal quenching properties of the thermoluminescence (TL) from several natural quartz specimens were examined, at two different wavelengths, using the heating rate dependence of the TL signal. As the heating rate varies the TL peaks shift to different temperatures and become affected by thermal quenching to diff…

Luminescence Properties of Advanced MaterialsAdvanced Thermoelectric Materials and DevicesTerahertz technology and applications

Oxidation of a Silicon Nitride‐Titanium Nitride Composite: Microstructural Investigations and Phenomenological Modeling

Frédéric Deschaux‐Beaume、Thierry Cutard、Nicole Fréty 等 4 位作者2002-07-01Journal of the American Ceramic Society

The high‐temperature oxidation of a silicon nitride‐titanium nitride (Si 3 N 4 –TiN) composite has been investigated via scanning electron microscopy and energy‐dispersive and wavelength‐dispersive spectrometry. At 1150°C, the oxidation of both the silicon nitride and titanium nitride phases takes place. Several oxida…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsMXene and MAX Phase Materials

Are filamentous mycolata important in foaming?

Russell J. Davenport、Thomas P. Curtis2002-07-01Water Science & Technology

In a previous study, we showed that there was a significant increase in mycolata numbers associated with foaming events at a wastewater treatment site possessing three activated sludge plants. In this paper, we demonstrate that branched filamentous mycolata were a minor proportion of the mycolata morphotypes present i…

Pickering emulsions and particle stabilization

New Concept for ZnTe-Based Homoepitaxial Light-Emitting Diodes Grown by Molecular Beam Epitaxy

Akio Ueta、D. Hommel2002-07-01physica status solidi (a)

ZnCdSeTe/ZnMgSeTe quasi-quaternary light-emitting devices emitting in the green–yellow wavelength region grown on ZnTe substrates are promising for efficient green light emitters. To solve the n-type conductivity problem in ZnTe-related materials, Cl-doped ZnMgSeTe quasi-quaternary layers which consisted of very thin…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Hydrogels based on pullulan derivatives crosslinked via a “living” free-radical process

V. Crescenzi、Mariella Dentini、Debora Bontempo 等 4 位作者2002-07-01Macromolecular Chemistry and Physics

Partially methacrylated pullulan was crosslinked by means of conventional and “living” radical polymerisations using, in the latter case, the reversible addition–fragmentation chain-transfer technique (RAFT). Several hydrogels were synthesised using methacrylated pullulan samples with different degrees of substitution…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and Properties

Microstructural Evolution in Liquid‐Phase‐Sintered SiC: Part III, Effect of Nitrogen‐Gas Sintering Atmosphere

Ángel L. Ortiz、Tania Bhatia、Nitin P. Padture 等 4 位作者2002-07-01Journal of the American Ceramic Society

Effects of N 2 sintering atmosphere and the starting SiC powder on the microstructural evolution of liquid‐phase‐sintered (LPS) SiC were studied. It was found that, for the β‐SiC starting powder case, there was complete suppression of the β→α phase transformation, which otherwise goes to completion in Ar atmosphere. I…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

The transition from elastic to plastic behaviour in an Al-Cu-Fe quasicrystal studied by cyclic nanoindentation

С. Н. Дуб、Н. В. Новиков、Yu.V. Milman2002-07-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Comparative mechanical tests of an Al-Cu-Fe quasicrystal and a tungsten (001) single crystal have been carried out using cyclic nanoindentation by a Berkovich indenter. The first loading-unloading cycle up to 30 mN formed the initial indent. On reloading of the indenter up to 50 mN, a transition from elastic to plasti…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsQuasicrystal Structures and Properties

Use of epilithic diatoms to evaluate water quality in the Karasu River of Turkey.

Hasan Gürbüz、Ersin Kıvrak2002-07-01PubMed

Epilithic diatom assemblages were used to evaluate water quality in the Karasu River basin (Turkey), which was polluted by industrial, agricultural and urban wastes. A total of 73 diatom taxa belonging to 22 genera were found from all seven sampling stations located in the River basin. The most pollution tolerant spec…

Diatoms and Algae ResearchWater Quality Monitoring and Analysis