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The Influence of the Metal (Al, Cr, and Co) and the Substituents of the Porphyrin in Controlling the Reactions Involved in the Copolymerization of Propylene Oxide and Carbon Dioxide by Porphyrin Metal(III) Complexes. 1. Aluminum Chemistry

Chandrani Chatterjee、Malcolm H. Chisholm2011-04-15Inorganic Chemistry

The reactivities of aluminum(III) complexes LAlX, where L = 5,10,15,20-tetraphenylporphyrin (TPP), 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin (TFPP), and 2,3,7,8,12,13,17,18-octaethylporphyirn (OEP) and X = Cl or OEt, have been studied with respect to their ability to homopolymerize propylene oxide (PO) and copol…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisCO2 Reduction Techniques and Catalysts

Doxorubicin Delivery into Tumor Cells with Ultrasound and Microbubbles

Jean‐Michel Escoffre、Julien Piron、Anthony Novell 等 4 位作者2011-04-15Molecular Pharmaceutics

Doxorubicin is a potent chemotherapeutic whose severe side effects limit its application. Drug-targeted delivery with noninvasive techniques is required to increase the drug concentration locally and to reduce systemic side effects. Microbubble-assisted ultrasound has become a promising strategy for noninvasive local…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation PhenomenaPhotoacoustic and Ultrasonic Imaging

Epitaxial Growth of InGaN Nanowire Arrays for Light Emitting Diodes

Christopher Hahn、Zhaoyu Zhang、Anthony Fu 等 7 位作者2011-04-15ACS Nano

Significant synthetic challenges remain for the epitaxial growth of high-quality InGaN across the entire compositional range. One strategy to address these challenges has been to use the nanowire geometry because of its strain relieving properties. Here, we demonstrate the heteroepitaxial growth of In(x)Ga(1-x)N nanow…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Zinc(II) and PPi Selective Fluorescence OFF–ON–OFF Functionality of a Chemosensor in Physiological Conditions

I. Ravikumar、Pradyut Ghosh2011-04-15Inorganic Chemistry

A fluorescent chemosensor based on a quinoline derivative, L(2) (OFF state), selectively senses Zn(2+) by effective chelate-enhanced fluorescence (ON state), which further shows selectivity toward PPi over competing anions like Pi, AMP, and ATP via fluorescence quenching (OFF state) in a 100% aqueous HEPES buffer (pH…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Nitrile‐Substituted QA Derivatives: New Acceptor Materials for Solution‐Processable Organic Bulk Heterojunction Solar Cells

Tianlei Zhou、Tao Jia、Bonan Kang 等 6 位作者2011-04-15Advanced Energy Materials

Abstract The development of non‐fullerene‐based electron acceptors (especially organic molecules with sufficient absorption property within the solar spectrum region) for bulk‐heterojunction (BHJ) organic solar cells (OSCs) is an important issue for the achievement of high photoconversion efficiency. In this contribut…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

A Lyapunov Function-Based Robust Direct Torque Controller for a Switched Reluctance Motor Drive System

Sanjib Kumar Sahoo、Souvik Dasgupta、Sanjib Kumar Panda 等 4 位作者2011-04-15IEEE Transactions on Power Electronics

A novel Lyapunov function-based direct torque controller for minimization of torque ripples in a switched reluctance motor (SRM) drive system is reported in this paper. SRM magnetization characteristics are highly nonlinear, where torque is a complex and coupled function of the phase currents and rotor position. The d…

Electric Motor Design and AnalysisSensorless Control of Electric MotorsMagnetic Properties and Applications

Connection of Metallamacrocycles via Dynamic Covalent Chemistry: A Versatile Method for the Synthesis of Molecular Cages

Anton Granzhan、Clément Schouwey、T. Riis‐Johannessen 等 5 位作者2011-04-15Journal of the American Chemical Society

A modular approach for the synthesis of cage structures is described. Reactions of [(arene)RuCl(2)](2) [arene = p-cymene, 1,3,5-C(6)H(3)Me(3), 1,3,5-C(6)H(3)(i-Pr)(3)] with formyl-substituted 3-hydroxy-2-pyridone ligands provide trinuclear metallamacrocycles with pendant aldehyde groups. Subsequent condensation reacti…

Organometallic Complex Synthesis and CatalysisSupramolecular Chemistry and ComplexesMagnetism in coordination complexes

Dirac, Majorana, and Weyl fermions

Palash B. Pal2011-04-15American Journal of Physics

We discuss the Dirac, Majorana, and Weyl fermion fields. The definitions and motivations for introducing each kind of field is discussed, along with the connections between them. It is pointed out that these definitions have to do with the proper Lorentz group and not with any discrete symmetry. The action of discrete…

Topological Materials and PhenomenaCrystallography and Radiation PhenomenaChemical and Physical Properties of Materials

Trap-assisted and Langevin-type recombination in organic light-emitting diodes

Gert‐Jan A. H. Wetzelaer、Martijn Kuik、Herman T. Nicolai 等 4 位作者2011-04-15Physical Review B

Trapping of charges is known to play an important role in the charge transport of organic semiconductors, but the role of traps in the recombination process has not been addressed. Here we show that the ideality factor of the current of organic light-emitting diodes (OLEDs) in the diffusion-dominated regime has a temp…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Controlled Growth of Semiconducting Nanowire, Nanowall, and Hybrid Nanostructures on Graphene for Piezoelectric Nanogenerators

Brijesh Kumar、Keun Young Lee、Hyunkyu Park 等 6 位作者2011-04-15ACS Nano

Precise control of morphologies of one- or two-dimensional nanostructures during growth has not been easy, usually degrading device performance and therefore limiting applications to various advanced nanoscale electronics and optoelectronics. Graphene could be a platform to serve as a substrate for both morphology con…

Graphene research and applicationsZnO doping and propertiesAdvanced Sensor and Energy Harvesting Materials

Critical tensile and compressive strains for cracking of Al2O3 films grown by atomic layer deposition

Shih‐Hui Jen、Jacob A. Bertrand、Steven M. George2011-04-15Journal of Applied Physics

Al2O3 atomic layer deposition (ALD) is a model ALD system and Al2O3 ALD films are excellent gas diffusion barrier on polymers. However, little is known about the response of Al2O3 ALD films to strain and the potential film cracking that would restrict the utility of gas diffusion barrier films. To understand the mecha…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Highly Efficient Red Phosphorescent Dopants in Organic Light‐Emitting Devices

Do Han Kim、Nam Sung Cho、Hyoung‐Yun Oh 等 8 位作者2011-04-15Advanced Materials

Highly efficient red phosphorescent dopants in organic light-emitting devices have been explored by using a cyclometalated iridium complex with a fully methylated phenyl ring and a quinoline ring as well as a sterically crowded ancillary ligand. The red phosphorescent devices with these dopants give extremely high ext…

Catalytic Cross-Coupling ReactionsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Single‐Walled Carbon Nanotube Aerogel‐Based Elastic Conductors

Kyu Hun Kim、Mert Vural、Mohammad F. Islam2011-04-15Advanced Materials

Flexible conductors of various shapes and sizes with high electrical stability under large elastic stretching and bending are of significant importance in diverse fields ranging from microelectronics to biological implants. Stretchable conductors are fabricated by completely backfilling single-walled carbon nanotube a…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsAdvanced Materials and Mechanics

Combination of Titanium Oxide and a Conjugated Polyelectrolyte for High‐Performance Inverted‐Type Organic Optoelectronic Devices

Hyosung Choi、Ji Sun Park、Eunjae Jeong 等 9 位作者2011-04-15Advanced Materials

Interface engineering by combination of TiOx and a conjugated polyelectrolyte as an electron transport layer modifies the electrical contact between a metal electrode and an organic active layer with well-aligned frontier orbital energy levels for efficient charge transport. This results in remarkable improvements in…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Degradable Polyethylene: Fantasy or Reality

Prasun Kumar Roy、Minna Hakkarainen、I. K. Varma 等 4 位作者2011-04-15Environmental Science & Technology

Plastic waste disposal is one of the serious environmental issues being tackled by our society today. Polyethylene, particularly in packaging films, has received criticism as it tends to accumulate over a period of time, leaving behind an undesirable visual footprint. Degradable polyethylene, which would enter the eco…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionRecycling and Waste Management Techniques

Origin of Piezoelectricity in an Electrospun Poly(vinylidene fluoride‐trifluoroethylene) Nanofiber Web‐Based Nanogenerator and Nano‐Pressure Sensor

Dipankar Mandal、Sun Yoon、Kap Jin Kim2011-04-15Macromolecular Rapid Communications

A single stage electrospinning process can give rise to preferentially oriented induced dipoles in poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] nanofibers. The piezoelectricity of as-electrospun P(VDF-TrFE) nanofiber webs opens up new possibilities for their use as a flexible nanogenerators and nano-press…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Zeolitic Materials with Hierarchical Porous Structures

Sofia Lopez‐Orozco、Amer Inayat、Andreas Schwab 等 5 位作者2011-04-15Advanced Materials

During the past several years, different kinds of hierarchical structured zeolitic materials have been synthesized due to their highly attractive properties, such as superior mass/heat transfer characteristics, lower restriction of the diffusion of reactants in the mesopores, and low pressure drop. Our contribution pr…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisCatalysis and Hydrodesulfurization Studies

Evidence for Crystal-Face-Dependent TiO 2 Photocatalysis from Single-Molecule Imaging and Kinetic Analysis

Takashi Tachikawa、Soichiro Yamashita、Tetsuro Majima2011-04-15Journal of the American Chemical Society

According to the concept of active sites, the activity of heterogeneous catalysts correlates with the number of available catalytic sites and the binding affinity of the substrates. Herein, we report a single-molecule, single-particle fluorescence approach to elucidate the inherent photocatalytic activity of exposed s…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Large Topological Hall Effect in a Short-Period Helimagnet MnGe

Naoya Kanazawa、Y. Onose、T. Arima 等 9 位作者2011-04-15Physical Review Letters

We have observed an unconventional, likely topological, Hall effect over a wide temperature region in the magnetization process of a chiral-lattice helimagnet MnGe. The magnitude of the topological Hall resistivity is nearly temperature-independent below 70 K, which reflects the real-space fictitious magnetic field pr…

Magnetic properties of thin filmsMagnetic and transport properties of perovskites and related materialsTopological Materials and Phenomena

Effect of cow manure biochar on maize productivity under sandy soil condition

Kingsley Chinyere Uzoma、Mitsuhiro Inoue、H. Andry 等 6 位作者2011-04-15Soil Use and Management

Abstract In this study, we performed a greenhouse experiment to investigate the effect of cow manure biochar on maize yield, nutrient uptake and physico‐chemical properties of a dryland sandy soil. Biochar was derived from dry cow manure pyrolysed at 500 °C. Cow manure biochar was mixed with a sandy soil at the rate e…

Soil Carbon and Nitrogen DynamicsSoil and Unsaturated FlowClay minerals and soil interactions