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New Approach to Hyperbranched Polyesters: Self-Condensing Cyclic Ester Polymerization of Bis(hydroxymethyl)-Substituted ε-Caprolactone

M. Trollsås、Peter Löwenhielm、V. Y. Lee 等 6 位作者1999-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTNew Approach to Hyperbranched Polyesters: Self-Condensing Cyclic Ester Polymerization of Bis(hydroxymethyl)-Substituted ε-CaprolactoneM. Trollsås, P. Löwenhielm, V. Y. Lee, M. Möller, R. D. Miller, and J. L. HedrickView Author Infor…

RNA Interference and Gene DeliveryChemical Synthesis and AnalysisDendrimers and Hyperbranched Polymers

A 13 C‐NMR study of the interactions of soil organic matter with aluminium and allophane in podzols

Rhys Parfitt、Guodong Yuan、Benny K.G. Theng1999-12-01European Journal of Soil Science

Summary The stabilization of organic matter in soil by interaction with aluminium (Al) or allophane is important in maintaining soil quality, and in retarding the decomposition of soil organic matter. Complexation of Al by soil organic matter may also ameliorate Al toxicity. Here we use 13 C‐NMR spectroscopy to assess…

Soil Carbon and Nitrogen DynamicsHeavy metals in environmentClay minerals and soil interactions

An efficient low voltage, high frequency silicon CMOS light emitting device and electro-optical interface

Lukas W. Snyman、M. du Plessis、E. Seevinck 等 4 位作者1999-12-01IEEE Electron Device Letters

A silicon light emitting device was designed and realized utilizing a standard 2-μm industrial CMOS technology design and processing procedure. The device and its associated driving circuitry were integrated in a CMOS integrated circuit and can interface with a multimode optical fiber. The device delivers 8 nW of opti…

Semiconductor materials and devicesThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

Charge compensation and binding energy referencing in XPS analysis

James B. Metson1999-12-01Surface and Interface Analysis

Throughout the evolution of XPS, the ability to compensate for surface charging and accurately calibrate the binding energy scale, particularly with electrically inhomogeneous samples, has remained one of the most intractable problems. The last decade, however, has seen some quite significant advances in this area. Be…

X-ray Spectroscopy and Fluorescence AnalysisIron oxide chemistry and applicationsElectron and X-Ray Spectroscopy Techniques

Leakage current patterns on contaminated polymeric surfaces

M.A.R.M. Fernando、Stanislaw Gubanski1999-12-01IEEE Transactions on Dielectrics and Electrical Insulation

This paper presents measurements of low-level leakage current (LC) patterns on naturally aged insulators and artificially contaminated material samples as well as insulaton. A nonlinear behaviorof the LC has been observed. Possible causes for this behavior are discussed and its relations to surface hydrophobicity and…

High voltage insulation and dielectric phenomenaWater Systems and OptimizationPower Transformer Diagnostics and Insulation

Preparation of Transparent and Conductive Zinc Oxide Films by Optimization of the Two‐Step Electrolysis Technique

Masanobu Izaki1999-12-01Journal of The Electrochemical Society

The two‐step electrolysis technique was developed for the purpose of preparation of a transparent and conductive zinc oxide (ZnO) film by cathodic deposition from a simple zinc nitrate aqueous solution at ambient temperature. The structural, optical, and electrical characterizations were performed with an atomic force…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Interfacial characterisation of flax fibre-thermoplastic polymer composites by the pull-out test

Artemis Stamboulis、Caroline Baillie、E. Schulz1999-12-01Die Angewandte Makromolekulare Chemie

The interface between flax fibres and thermoplastic polymer matrices has been investigated. Two types of flax fibres have been used: dew retted and upgraded Duralin fibres. The latter fibres have been treated by a novel treatment process for improved moisture and rot sensitivity. The apparent shear strength of dew-ret…

Mechanical Behavior of CompositesStructural Behavior of Reinforced ConcreteNatural Fiber Reinforced Composites

Transport and magnetic properties of a ferromagnetic metal:Eu1−xRxTiO3

T. Katsufuji、Y. Tokura1999-12-01Physical review. B, Condensed matter

We report the transport and magnetic properties of a series of ferromagnetic metallic compounds, ${\mathrm{Eu}}_{1\ensuremath{-}x}{R}_{x}{\mathrm{TiO}}_{3},$ where the maximum ${T}_{C}$ is 8 K at $x=0.1.$ Magnetic interaction between Eu $4f$ spins mediated by itinerant Ti $3d$ electrons is essential for the ferromagne…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Layer-by-Layer Assembly of DNA Films and Their Interactions with Dyes

Jie Lang、Minghua Liu1999-12-01The Journal of Physical Chemistry B

Layer-by-layer assembly of DNA film was fabricated on quartz plates through alternative adsorption with poly(allylamine) in order to investigate the interaction of DNA film with dyes. The film was water-insoluble and can interact with many water-soluble dyes. It has been found that ethidium bromide (EB) and 5,10,15,20…

Advanced biosensing and bioanalysis techniquesPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Effect of thermal denaturation on water-collagen interactions: NMR relaxation and differential scanning calorimetry analysis

A. Rochdi、Loïc Foucat、Jean‐Pierre Renou1999-12-01Biopolymers

The dependence of the proton spin-lattice relaxation rate, and of the enthalpy and temperature of denaturation on water content, were studied by nmr and differential scanning calorimetry (DSC) in native and denatured collagen. Collagen was first heated at four different temperatures ranging from 40 to 70 degrees C. Th…

Protein Structure and DynamicsBone health and osteoporosis researchCollagen: Extraction and Characterization

Vicker's Microhardness Studies of L-arginine Hydrobromide Monohydrate Crystals (LAHBr)

Sudeshna Mukerji、T. Kar1999-12-01Crystal Research and Technology

Vicker's microhardness study of (100), (010) and (001) faces of a non-linear optical crystal, L-arginine hydrobromide monohydrate (LAHBr)have been reported.(100) plane is found to be the weakest plane. It has been observed that the microhardness decreases with increasing load for the three crystal planes. The microhar…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

RTV silicone rubber coatings for outdoor insulators

E.A. Cherney、R.S. Gorur1999-12-01IEEE Transactions on Dielectrics and Electrical Insulation

The paper presents a review of room temperature vulcanized (RTV) silicone rubber high voltage insulator coatings (HVIC). These coatings are designed to replace greasing and waterwashing of insulators. Present day coatings are the result of nearly thirty years of development and use. In all but a very few dirty environ…

High voltage insulation and dielectric phenomenaThermal Analysis in Power TransmissionPower Line Inspection Robots

A First-Principles Quantum Chemical Analysis of the Factors Controlling Ruffling Deformations of Porphyrins: Insights from the Molecular Structures and Potential Energy Surfaces of Silicon, Phosphorus, Germanium, and Arsenic Porphyrins and of a Peroxidase Compound I Model

Torgil R. Vangberg、Abhik Ghosh1999-12-01Journal of the American Chemical Society

Using nonlocal density functional theory calculations, we have examined several factors influencing ruffling deformations of porphyrin and porphyrazine complexes. Because a ruffling distortion is often a direct result of a small macrocycle core size, which, in turn, is brought about by complexation of a central ion wi…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Substituent-Induced Circular Dichroism in Phthalocyanines

Nagao Kobayashi、Ryuji Higashi、Bruno C. Titeca 等 5 位作者1999-12-01Journal of the American Chemical Society

Phthalocyanines with two and four optically active binaphthyl units have been synthesized and characterized by electronic absorption, CD, and MCD spectroscopy. The chiral substituents induce CD in the in-plane polarized Q and Soret bands of phthalocyanines: phthalocyanines having R and S binaphthyls show positive and…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic Compounds

Mineralogical and chemical characteristics of five nontronites and Fe-rich smectites

Heinrich M. Köster、U. Ehrlicher、H. Albert Gilg 等 6 位作者1999-12-01Clay Minerals

Abstract Five Fe–bearing dioctahedral smectites (three nontronites and two Fe-rich smectites) were purified using a variety of physical and chemical procedures. The structural formulae indicate one nontronite and one Fe-rich smectite to be montmorillonitic, whereas the other three smectites are beidellitic. Mössbauer…

Geological and Geochemical AnalysisClay minerals and soil interactionsIron oxide chemistry and applications

Mean stress effects on fatigue of NiTi

R. Murat Tabanli、N.K. Simha、B. T. Berg1999-12-01Materials Science and Engineering A

Fatigue properties of shape-memory alloys (SMA) play an important role in actuator and certain biomedical applications. Since a small cyclic stress can trigger martensitic transformation when the mean stress is close to a critical stress, it is crucial to understand the effect of mean stress. This paper examines mean…

Shape Memory Alloy Transformations

Cation-Exchange Capacity (CEC) of Zeolitic Volcaniclastic Materials: Applicability of the Ammonium Acetate Saturation (AMAS) Method

Konstantinos P. Kitsopoulos1999-12-01Clays and Clay Minerals

Abstract The ammonium acetate saturation (AMAS) method was used to study the cation-exchange capacity (CEC) of zeolitic volcaniclastic materials from Santorini and Polyegos Islands, Greece. The AMAS method was tested with respect to the time required to saturate the samples of zeolites with ammonium (NH 4 + ) ions, th…

Zeolite Catalysis and SynthesisClay minerals and soil interactionsChemical Synthesis and Characterization

New Transient Absorption Observed in the Spectrum of Colloidal CdSe Nanoparticles Pumped with High-Power Femtosecond Pulses

Clemens Burda、Stephan Link、T. C. Green 等 4 位作者1999-12-01The Journal of Physical Chemistry B

The power dependence of the transient absorption spectrum of CdSe nanoparticle colloids with size distribution of 4.0 ± 0.4 nm diameter is studied with femtosecond pump−probe techniques. At the lowest pump laser power, the absorption bleaching (negative spectrum) characteristic of the exciton spectrum is observed with…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Ethylammonium nitrate: a protein crystallization reagent

Jennifer A. Garlitz、Catherine A. Summers、Robert A. Flowers 等 4 位作者1999-12-01Acta Crystallographica Section D Biological Crystallography

Ethylammonium nitrate (EAN) is a liquid organic salt that has many potential applications in protein chemistry. Because this solvent has hydrophobic and ionic character as well as the ability to hydrogen bond, it is especially well suited for broad use in protein crystallography. For example, EAN may be used as an add…

Protein Structure and DynamicsEnzyme Structure and FunctionBiochemical and Molecular Research

Carburizing

G. PARRISH1999-12-01ASM International eBooks

Carburizing: Microstructures and Properties explains how to recognize and address problems associated with case carburizing treatments for steels. It examines the nature of internal oxidation, decarburization, free carbides, and retained austenite and their effect on fatigue and fracture strength, wear resistance, imp…

Microstructure and Mechanical Properties of SteelsSurface Treatment and Residual StressMetal Alloys Wear and Properties