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The development of chloride ion selective polypyrrole thin film on a layer-by-layer carbon nanotube working electrode

Yang Liu、Jerome Lynch2011-03-24Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

A chloride ion selective thin film sensor is proposed for measuring chloride ion concentration, which is an environmental parameter correlated to corrosion. In this work, electrochemical polymerization of Polypyrrole (PPy) doped with chloride ions was achieved on the top of a carbon nanotube (CNT) thin film as a worki…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Bulk Modulus of a Protein Active-Site Mimic

Bogdan M. Leu、J. Timothy Sage、N.J. Silvernail 等 7 位作者2011-03-24The Journal of Physical Chemistry B

Flexibility is an important property of porphyrins, both natural and synthetic. We applied two synchrotron-based techniques, nuclear resonance vibrational spectroscopy and inelastic X-ray scattering, to quantify this property by measuring the bulk modulus of a protein active-site mimic [chloro(octaethylporphyrinato)ir…

Porphyrin and Phthalocyanine ChemistryEnzyme Structure and FunctionCrystallography and Radiation Phenomena

Flash Cooling Protein Crystals: Estimate of Cryoprotectant Concentration Using Thermal Properties

Binal N. Shah、Unmesh Chinte、Stephen J. Tomanicek 等 5 位作者2011-03-24Crystal Growth & Design

X-ray diffraction from protein crystals is routinely measured at cryogenic temperatures, primarily to minimize radiation damage. Protein crystals and the surrounding mother liquor have high water content, which can lead to ice formation when samples are cooled to cryogenic temperatures. Cryoprotectants are added to th…

Material Dynamics and PropertiesEnzyme Structure and FunctionCrystallization and Solubility Studies

Design of a shape adaptive airfoil actuated by a Shape Memory Alloy strip for airplane tail

Rasoul Shirzadeh、Kamran Raissi Charmacani、Majid Tabesh2011-03-24Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Of the factors that mainly affect the efficiency of the wing during a special flow regime, the shape of its airfoil cross section is the most significant. Airfoils are generally designed for a specific flight condition and, therefore, are not fully optimized in all flight conditions. It is very desirable to have an ai…

Shape Memory Alloy TransformationsAeroelasticity and Vibration ControlTopology Optimization in Engineering

“Off‐on‐off” Fluorescence pH Switch of Three Trinuclear RuII Complexes Containing Imidazole Rings

Feixiang Cheng、Jishu Chen、Fan Wang 等 5 位作者2011-03-24Zeitschrift für anorganische und allgemeine Chemie

Abstract Three tripodal ligands H3L1–3 containing imidazole rings were synthesized by the reaction of 1,10‐phenanthroline‐5,6‐dione with 1,3,5‐tris[(3‐formylphenoxy)methyl]benzene, 1,3,5‐tris[(3‐formylphenoxy)methyl]‐2,4,6‐trimethylbenzene, and 2,2′,2"‐tris[(3‐formylphenoxy)ethyl]amine, respectively. Trinuclear RuII p…

Metal complexes synthesis and propertiesMolecular Sensors and Ion DetectionLanthanide and Transition Metal Complexes

Jahn–Teller effect and magnetic property in anisotropic triangular compound NaxMnO2

Sheng-De Ouyang、Dayong Liu、Liang‐Jian Zou 等 4 位作者2011-03-24Journal of Applied Physics

In this paper we investigate the Jahn–Teller distortion and magnetic property in parent and doped anisotropic triangular compound NaxMnO2. We first determine the Jahn–Teller distortion modes of the MnO6 octahedra by minimizing the potential energy. Then we demonstrate by the cluster self-consistent field method that t…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Modified Brinson model as an equivalent one-dimensional constitutive equation of SMA spring

Junghyun Ryu、Sung-Min Ahn、Je‐Sung Koh 等 5 位作者2011-03-24Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Shape Memory Alloy (SMA) spring has great potential as a component of compact actuating system. Trade-off between recovery force and deformation range due to phase transformation is possible through the control of spring design parameters such as spring diameter. Deformation behavior of SMA spring is complicated funct…

Shape Memory Alloy TransformationsSoft Robotics and Applications

A micropolar continuum model for large deformation caused by magnetic or electric fields

Ingo von Münch、Patrizio Neff、Werner Wagner2011-03-24Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

An appropriate continuum theory to predict the behavior of flexible magnetic or electrically polarized materials undergoing large deformations is explained. The formulation treats the angular momentum as an explicit complementary principle including net-couples from magnetic resp. electric fields. As a consequence non…

Thermoelastic and Magnetoelastic PhenomenaNonlocal and gradient elasticity in micro/nano structures

Overproduction, purification, crystallization and preliminary X-ray characterization of a novel carbohydrate-binding module of endoglucanase Cel5A fromEubacterium cellulosolvens

Ana S. Luís、Victor D. Alves、Maria João Romão 等 6 位作者2011-03-24Acta Crystallographica Section F Structural Biology and Crystallization Communications

The anaerobic cellulolytic rumen bacterium Eubacterium cellulosolvens produces a large array of cellulases and hemicellulases that are responsible for the hydrolysis of plant cell-wall polysaccharides. One of these enzymes, endoglucanase Cel5A, comprises two tandemly repeated novel carbohydrate-binding modules (CBMs)…

Enzyme Structure and FunctionEnzyme Production and CharacterizationMicrobial Metabolites in Food Biotechnology

Surface electromagnetic waves in 1D optically active photonic crystals

A. N. Furs2011-03-24Journal of Optics

Surface electromagnetic waves at the interface of a semi-infinite isotropic medium and a one-dimensional photonic crystal consisting of alternating optically active layers of a planar 3m, 4mm, or 6mm symmetry class are considered. The layers differ only in the sign of the antisymmetric magnetoelectric pseudotensor tha…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

A rational protocol for the successful crystallization of L -amino-acid oxidase fromBothrops atrox

Raquel Melo Alves、Patrícia R. Feliciano、Suely Vilela Sampaio 等 4 位作者2011-03-24Acta Crystallographica Section F Structural Biology and Crystallization Communications

Despite the valuable contributions of robotics and high-throughput approaches to protein crystallization, the role of an experienced crystallographer in the evaluation and rationalization of a crystallization process is still crucial to obtaining crystals suitable for X-ray diffraction measurements. In this work, the…

Protein Structure and DynamicsEnzyme Structure and FunctionVenomous Animal Envenomation and Studies

Theory of High Temperature Superconductivity: A Conventional Approach

Todor M. Mishonov、Evgeni S. Penev2011-03-24CERN Document Server (European Organization for Nuclear Research)

Tight-Binding Modeling of Layered Perovskites The Pairing Mechanism of Overdoped Cuprates Specific Heat and Penetration Depth Plasmons and the Cooper Pair Mass Thermodynamics of Gaussian Fluctuations and Paraconductivity Kinetics of Fluctuation Cooper Pairs Fluctuation Conductivity in Strong Electric Fields Linear-T E…

Physics of Superconductivity and MagnetismAdvanced Thermoelectric Materials and DevicesAdvanced Thermodynamics and Statistical Mechanics

Structural and magnetic characterizations of Mn2CrO4 and MnCr2O4 films on MgO(001) and SrTiO3(001) substrates by molecular beam epitaxy

Yu-Cing Jhuang、Kuang-Ming Kuo、G. Chern2011-03-24Journal of Applied Physics

In this report, we grow MnCr2O4 (124) films, and Mn2CrO4 (214) films, for comparison, on MgO and SrTiO3 (STO) substrates by oxygen-plasma-assisted molecular beam epitaxy and also carry out the measurements of the magnetization as a function of temperature (5–200 K) and external field (0–5 T) of these films. The result…

Magnetic properties of thin filmsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

A multi-block-spin approach for martensitic phase transformation based on statistical physics

Michael Fischlschweiger、Eduard Oberaigner、Thomas Antretter 等 4 位作者2011-03-24Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Current strategies in modeling shape memory alloy (SMA) behavior follow either the concept of classical irreversible thermodynamics or the methodology of phenomenological approaches at the micro as well as at the macro space scale. The objective of the present study is to show a new approach in modeling SMA's by using…

Microstructure and Mechanical Properties of SteelsShape Memory Alloy TransformationsMagnetic Properties and Applications

Effect of Metal Ion Concentration on the Property of Methotraexate/Layered Double Hydroxide Compounds

Chunxiao Jia、Shu-Ping Li、Hui Zhong2011-03-24Journal of Dispersion Science and Technology

A hybrid composite based on the intercalation of methotrexate (MTX) into the layered double hydroxides (LDHs) has been synthesized by the ion exchange technique. The influence of layer charges, altered by the molar ratio of Mg element to Al, on the property of MTX/LDH compounds has been studied. It was found that the…

Layered Double Hydroxides Synthesis and ApplicationsThermal Expansion and Ionic ConductivityMagnesium Oxide Properties and Applications

Cloning, overexpression, purification, crystallization and preliminary X-ray diffraction analysis of an inositol monophosphatase family protein (SAS2203) fromStaphylococcus aureusMSSA476

Sudipta Bhattacharyya、Debajyoti Dutta、Ananta K. Ghosh 等 4 位作者2011-03-24Acta Crystallographica Section F Structural Biology and Crystallization Communications

The gene product of the sas2203 ORF of Staphylococcus aureus MSSA476 encodes a 30 kDa molecular-weight protein with a high sequence resemblance (29% identity) to tetrameric inositol monophosphatase from Thermotoga maritima. The protein was cloned, expressed, purified to homogeneity and crystallized. Crystals appeared…

Enzyme Structure and FunctionEnzyme Production and CharacterizationBiochemical and Molecular Research

Depression Effects of Al on Oxidation of Diamond During Sintering of Diamond/Borosilicate Glass Composites

Xianghong Zhang、Yanhui Wang、Jianbing Zang 等 6 位作者2011-03-24International Journal of Applied Ceramic Technology

Oxidization of diamond in the sintering process of diamond/glass composites results in uncontrolled expansion with many irregular pores and low bending strength of the tools. In this paper, Al powder was used as oxygen getter due to its excellent affinity with oxygen. Its oxidization product, Al 2 O 3 , entered into g…

Diamond and Carbon-based Materials ResearchAdvanced materials and compositesTunneling and Rock Mechanics

Temperature compensation in piezoelectric energy harvesters using shape memory alloys

Mohamed Rhimi、Nizar Lajnef2011-03-24Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Harvested vibration energy is typically considered as an alternative power source for sensors' networks for health and usage monitoring in civil and mechanical structures. The longevity, and hence the efficacy, of these sensors is severely limited by the levels of generated power. Piezoelectric vibration harvesters ha…

Structural Health Monitoring TechniquesShape Memory Alloy TransformationsStructural Engineering and Vibration Analysis

Assessment of carbon fiber-reinforced polyphenylene sulfide by means of laser ultrasound

Michael Kalms、Christian Peters、Ronald Wierbos2011-03-24Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

From automobile industry to aerospace, thermoformed composites are more and more in use. Thermoplastics offer a number of attractive applications in commercial use like short production times, tailored solutions, recyclability and lower cost. The thermoforming process allows for producing carbon fiber-reinforced parts…

Material Properties and Applications

Synthesis of Fullerene [60] Polyvinyl Pyridine Composites in Supercritical Carbon Dioxide

M.G.H. Zaidi、Tithi Agarwal、Shahid Alam 等 4 位作者2011-03-24Fullerenes Nanotubes and Carbon Nanostructures

A synthetic route to prepare fullerene [60] polyvinyl pyridine composites (FPVPC) in supercritical carbon dioxide (scCO2) is presented. The synthetic route involve 2, 2'-azobisisobutyronitrile (AIBN) initiated free radical polymerization of vinyl pyridine (VPY) in presence of fullerene [60] (C60) under various conditi…

Carbon Nanotubes in CompositesPhase Equilibria and ThermodynamicsPolymer Foaming and Composites