Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Carbohydrate films on gold based on dimannoside thiols (DMT) were prepared, and a complementary surface chemical analysis was performed in detail by X-ray photoelectron spectroscopy (XPS), time-of-flight secondary ion mass spectrometry (ToF-SIMS), near-edge X-ray absorption fine structure (NEXAFS), FT-IR, and contact…
A series of Al and MgO-capped Co${}_{2}$FeAl${}_{0.5}$Si${}_{0.5}$ epitaxial thin films grown on MgO with various levels of L2${}_{1}$ ordering was obtained by in situ annealing. The films were studied by means of x-ray absorption spectroscopy, x-ray magnetic circular dichroism (XMCD), magneto-optical Kerr effect magn…
We prepared a series of new heteroleptic ruthenium(II) complexes, Ru(NCS)(2)LL' (3a-3e), where L is 4,4'-di(hydroxycarbonyl)-2,2'-bipyridine and L' is 4,4'-di(p-X-phenyl)-2,2'-pyridine (X = CN (a), F (b), H (c), OMe (d), and NMe(2) (e)), in an attempt to explore the structure-activity relationships in their photophysi…
GaN metal-semiconductor-metal (MSM) ultraviolet detectors were investigated by depositing different density of SiO2 nanoparticles (SNPs) on the GaN. It was shown that the dark current of the detectors with SNPs was more than one order of magnitude lower than that without SNPs and the peak responsivity was enhanced aft…
To maximize energy efficiency, gas turbine engines used in airplanes and for power generation operate at very high temperatures, even above the melting point of the metal alloys from which they are comprised. This feat is accomplished in part via the deposition of a multilayer, multicomponent thermal barrier coating (…
We report herein on the integration of novel transparent and conducting one-dimensional photonic crystals that consist of periodically alternating layers of spin-coated antimony-doped tin oxide nanoparticles and sputtered tin-doped indium oxide into organic light emitting diode (OLED) microcavities. The large refracti…
Diphenylacetylenes containing chiral menthyl groups [C 6 H 5 C≡C−C 6 H 4 OCOCH 2 OR* and C 6 H 5 C≡C−C 6 H 4 CO 2 R*, R* = (1 R,2 S,5 R )-(−)-menthyl] are synthesized and polymerized by WCl 6 −Ph 4 Sn catalyst. The structures and properties of the polymers are characterized and evaluated by IR, NMR, TGA, UV, CD, and P…
Using alkali metals as promoters is known to strongly influence the selectivity of catalytic reactions on Mo 2 C catalysts. To provide fundamental information about this observation, density functional theory calculations have been performed to study K and Rb adsorption of seven low-index α-Mo 2 C surfaces and the equ…
The dry thermal transformation of 2-line ferrihydrite to hematite was investigated using combinations of thermogravimetric (TG) and differential scanning calorimetric (DSC) analysis, along with in situ DSC and pair distribution function (PDF) analysis of X-ray total scattering data and in situ temperature controlled i…
Metal-rich metallaboranes: An exo-Fe(CO)3 moiety linked to a cubane core is the most prominent feature of complexes [(Cp*M)2(μ3-E)2B2H(μ-H){Fe(CO)2}2Fe(CO)3] (M=Mo, E=S, Se; M=Ru, E=CO; Cp*=η5-C5Me5), which are the first heterobimetallic cubane-type clusters with a boride unit (see structure).
Abstract The Mode I interlaminar fracture behavior of woven carbon fiber/epoxy composite laminates incorporating partially cured carbon nanotube/epoxy composite films has been investigated. Laminates with films containing carbon nanotubes (CNTs) in the as‐received state and functionalized with polyamidoamine were eval…
Thin film transistors (TFTs) with In and Ga-free multicomponent Zn–Sn–Zr–O (ZTZO) channel layers were fabricated using the cosputtering approach. The incorporation of ZrO2 into the Zn–Sn–O (ZTO) films increased the contact resistance, which led to the degradation of the transport properties. In contrast, the threshold…
The growth mechanism of self-induced InAs nanowires (NWs) grown on Si (111) by molecular beam epitaxy was investigated by in situ reflection high energy electron diffraction and ex situ scanning and transmission electron microscopy. Abrupt morphology transition and in-plane strain relaxation revealed that InAs NWs nuc…
Quantum chemistry studies of the oxidative stability of carbonate, sulfonate and sulfone-based solvents with and without BF4-, PF6- anions were performed using M05-2X Minnesota density functional and cc-pvTz basis set. Presence of BF4- and PF6- anions was found to significantly decrease oxidative stability of a number…
Using a mixture of Eudragit EPO and polyvinylpyrrolidone/vinyl acetate copolymer (PVP/VA) (Kollidon VA64) as carriers, a nimodipine solid dispersion (NM-SD) was prepared by hot-melt extrusion (HME) to achieve high dissolution. The dissolution profiles in 900 mL 0.1 mol/L HCl showed that the drug release of NM-SD reach…
A series of fluorenyl-substituted carbazole linear triads and starbursts were synthesized by the Suzuki and Sonogashira coupling reactions. In these compounds, a fluorene unit is connected to the 1,8; 2,7; or 3,6 positions of the central carbazole ring to form linear triads or linked to the 1,3,6,8 positions to form s…
From analysis of the in-plane resistivity ρ(ab)(T) of La(2-x)Sr(x)CuO(4), we show that normal state transport in overdoped cuprates can be delineated into two regimes in which the electrical resistivity varies approximately linearly with temperature. In the low-temperature limit, the T-linear resistivity extends over…
Using the measured capacitance-voltage curves of Ni Schottky contacts with different contact areas and the current-voltage characteristics for the circular and rectangular AlGaN/AlN/GaN heterostructure field-effect transistors (HFETs) at low drain-source voltage, we found that the polarization Coulomb field scattering…
A new family of fluorescent markers containing an Amino Naphthalenyl-2-Cyano-Acrylate (ANCA) motif has been synthesized and evaluated for its capability to associate with aggregated β-amyloid (Aβ) peptides. These fluorescent probes contain a nitrogen donor group that is connected via a naphthalene unit to an electron…
A method is proposed to determine the fraction of the tautomeric forms of the imidazole ring of histidine in proteins as a function of pH, provided that the observed and chemical shifts and the protein structure, or the fraction of H(+) form, are known. This method is based on the use of quantum chemical methods to co…