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Self-assembled monolayers (SAMs) of carboxylic acids: an overview

Sushilkumar A. Jadhav2011-03-21Open Chemistry

Abstract The field of self-assembled monolayers (SAMs) of organic compounds on different substrates is of importance because it provides a suitable and efficient method of surface modification. The formation of robust, stable monolayers from carboxylic acids on two and three dimensional surfaces of different substrate…

Quantum Dots Synthesis And PropertiesPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

High-quality reduced graphene oxide-nanocrystalline platinum hybrid materials prepared by simultaneous co-reduction of graphene oxide and chloroplatinic acid

Yinjie Wang、Jincheng Liu、Lei Liu 等 4 位作者2011-03-21Nanoscale Research Letters

Reduced graphene oxide-nanocrystalline platinum (RGO-Pt) hybrid materials were synthesized by simultaneous co-reduction of graphene oxide (GO) and chloroplatinic acid with sodium citrate in water at 80°C, of pH 7 and 10. The resultant RGO-Pt hybrid materials were characterized using transmission electron microscopy (T…

Graphene research and applicationsElectrochemical sensors and biosensorsGraphene and Nanomaterials Applications

Effect of channel thickness on density of states in amorphous InGaZnO thin film transistor

Sang Yeol Lee、Do Hyung Kim、Eugene Chong 等 5 位作者2011-03-21Applied Physics Letters

We report on the origin of threshold voltage shift with the thickness of amorphous InGaZnO channel layer deposited by rf magnetron sputter at room temperature, using density of states extracted from multi frequency method and falling rates of activation energy, which of trends are entirely consistent each other in res…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceElectrical and Thermal Properties of Materials

Superiority of Branched Side Chains in Spontaneous Nanowire Formation: Exemplified by Poly(3‐2‐methylbutylthiophene) for High‐Performance Solar Cells

Hsieh‐Chih Chen、I‐Che Wu、Jui‐Hsiang Hung 等 11 位作者2011-03-21Small

One-dimensional nanostructures containing heterojunctions by conjugated polymers, such as nanowires, are expected to greatly facilitate efficient charge transfer in bulk-heterojunction (BHJ) solar cells. Thus, a combined theoretical and experimental approach is pursued to explore spontaneous nanowire formation. A diss…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

XPS and ToF-SIMS Study of Electrode Processes on Sn−Ni Alloy Anodes for Li-Ion Batteries

Jun‐Tao Li、Jolanta Światowska、Vincent Maurice 等 7 位作者2011-03-21The Journal of Physical Chemistry C

The characterization of electrode processes induced by lithiation/delithiation of Sn−Ni alloy films electroplated on a copper substrate is presented. Galvanostatic discharge/charge measurements were combined with X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). XPS…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationExtraction and Separation Processes

Suppressed Compressibility at Large Scale in Jammed Packings of Size-Disperse Spheres

Ludovic Berthier、Pinaki Chaudhuri、Corentin Coulais 等 5 位作者2011-03-21Physical Review Letters

We analyze the large-scale structure and fluctuations of jammed packings of size-disperse spheres, produced in a granular experiment as well as numerically. While the structure factor of the packings reveals no unusual behavior for small wave vectors, the compressibility displays an anomalous linear dependence at low…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesComposite Material Mechanics

The SLC23 family of ascorbate transporters: ensuring that you get and keep your daily dose of vitamin C

James M. May2011-03-21British Journal of Pharmacology

The ascorbate transporters SVCT1 and SVCT2 are crucial for maintaining intracellular ascorbate concentrations in most cell types. Although the two transporter isoforms are highly homologous, they have different physiologic functions. The SVCT1 is located primarily in epithelial cells and has its greatest effect in rea…

Nanoparticles: synthesis and applicationsVitamin C and Antioxidants ResearchVitamin K Research Studies

UI4(1,4-dioxane)2, [UCl4(1,4-dioxane)]2, and UI3(1,4-dioxane)1.5: Stable and Versatile Starting Materials for Low- and High-Valent Uranium Chemistry

Marisa J. Monreal、Robert K. Thomson、Thibault Cantat 等 6 位作者2011-03-21Organometallics

The uranium(III) and uranium(IV) iodide complexes UI 3 (1,4-dioxane) 1.5 and UI 4 (1,4-dioxane) 2 have been easily prepared in high yield by reacting uranium turnings with a 1,4-dioxane solution of iodine under mild conditions. The two complexes exhibit outstanding thermal stability and are excellent precursors to a v…

Radioactive element chemistry and processingNuclear Materials and PropertiesNuclear materials and radiation effects

Low-voltage ZnO thin-film transistors based on Y2O3 and Al2O3 high-k dielectrics deposited by spray pyrolysis in air

George Adamopoulos、Stuart Thomas、Donal D. C. Bradley 等 5 位作者2011-03-21Applied Physics Letters

We report the application of ambient spray pyrolysis for the deposition of high-k polycrystalline Y2O3 and amorphous Al2O3 dielectrics and their use in low-voltage ZnO thin-film transistors. The films are studied by means of atomic force microscopy, UV-visible absorption spectroscopy, impedance spectroscopy, and field…

ZnO doping and propertiesSemiconductor materials and devicesThin-Film Transistor Technologies

Ultrafast carrier dynamics and saturable absorption of solution-processable few-layered graphene oxide

Xin Zhao、Zhibo Liu、Weibo Yan 等 7 位作者2011-03-21Applied Physics Letters

Ultrafast carrier dynamics and saturable absorption of few-layered graphene oxide, well-dispersed in organic solvent, are studied using femtosecond pump-probe and Z-scan techniques. The results demonstrate that few-layered graphene oxide has a fast energy relaxation of hot carriers and strong saturable absorption, whi…

Diamond and Carbon-based Materials ResearchAdvanced Fiber Laser TechnologiesNonlinear Optical Materials Studies

Methodological aspects of determining soil particle‐size distribution using the laser diffraction method

Magdalena Ryżak、Andrzej Bieganowski2011-03-21Journal of Plant Nutrition and Soil Science

Abstract This paper presents the influence of selected methodological aspects on the results of particle‐size distribution (PSD) as measured by the laser diffraction method (LDM). The investigations were carried out using the Mastersizer 2000 with Hydro MU attachment (Malvern Ltd., UK). It was found that for the inves…

Soil and Unsaturated FlowSoil Geostatistics and MappingClay minerals and soil interactions

Growth, geometry, and mechanics of a blooming lily

Haiyi Liang、L. Mahadevan2011-03-21Proceedings of the National Academy of Sciences

Despite the common use of the blooming metaphor, its floral inspiration remains poorly understood. Here we study the physical process of blooming in the asiatic lily Lilium casablanca. Our observations show that the edges of the petals wrinkle as the flower opens, suggesting that differential growth drives the deploym…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsPlant and Biological Electrophysiology Studies

Recent Advances in Conjugated Polymers for Light Emitting Devices

Mohamad Saleh AlSalhi、Javed Alam、Lawrence Arockiasamy Dass 等 4 位作者2011-03-21International Journal of Molecular Sciences

A recent advance in the field of light emitting polymers has been the discovery of electroluminescent conjugated polymers, that is, kind of fluorescent polymers that emit light when excited by the flow of an electric current. These new generation fluorescent materials may now challenge the domination by inorganic semi…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Search for Majorana Fermions in Multiband Semiconducting Nanowires

Roman M. Lutchyn、Tudor D. Stanescu、S. Das Sarma2011-03-21Physical Review Letters

We study multiband semiconducting nanowires proximity-coupled with an s-wave superconductor. We show that, when an odd number of subbands are occupied, the system realizes a nontrivial topological state supporting Majorana modes. We study the topological quantum phase transition in this system and calculate the phase…

Graphene research and applicationsTopological Materials and PhenomenaQuantum many-body systems

Biopolymer-Based Hydrogels for Cartilage Tissue Engineering

Biji Balakrishnan、Rinti Banerjee2011-03-21Chemical Reviews

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTBiopolymer-Based Hydrogels for Cartilage Tissue EngineeringBiji Balakrishnan and R. Banerjee*View Author Information Department of Biosciences & Bioengineering, Indian Institute of Technology, Bombay, Mumbai-400076, Maharashtra, IndiaTo whom correspondence should be addressed…

Osteoarthritis Treatment and MechanismsProteoglycans and glycosaminoglycans researchSilk-based biomaterials and applications

Optical Properties of Germanium Dots Self-Assembled on Porous TiO2 Templates

D. J. Lockwood、N. L. Rowell、Isabelle Berbézier 等 8 位作者2011-03-21ECS Transactions

Self-assembled Ge quantum dots were formed by in-situ thermal annealing of a thin amorphous Ge layer deposited by molecular beam epitaxy on a thin porous TiO2 layer grown on SiO2 on Si(001). For samples with dot diameters ranging from 10 to 35 nm, the dot photoluminescence (PL) appeared primarily as a wide near-infrar…

Glass properties and applicationsMesoporous Materials and CatalysisSilicon Nanostructures and Photoluminescence

Study of High-Frequency Artifacts in EIS Measurements of Ti and its Alloys in Simulated Body Fluid

Xuan Zhou、Pravansu Mohanty2011-03-21ECS Transactions

In electrochemical impedance spectroscopy which is commonly used to study the behavior of titanium and its alloy in simulated body fluid solution, high frequency artifacts are commonly observed. Two parameters that may augment the high frequency artifacts including the electrochemical cell design and the solution are…

Corrosion Behavior and InhibitionFuel Cells and Related MaterialsHydrogen embrittlement and corrosion behaviors in metals

Pd Assisted HF Etching of Si: Electrochemical Measurement

Masayuki Tashiro、Shinji Yae、Yuma Morii 等 5 位作者2011-03-21ECS Transactions

Metal-assisted HF etching of Si has attracted considerable attention as a new electroless method that can produce porous Si by immersing metal-modified Si in a HF solution without bias. Such etching generally uses not only metal-modified Si but also an oxidizing agent. Palladium exhibits high activity in assisted etch…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceAnodic Oxide Films and Nanostructures

Corrosion Inhibition of 304 Stainless Steel, Copper and Nickel Metals Using Mesoporous Silicate (MCM- 41) and 2, 5-Distyrylpyrazine Photopolymer

Mohamed B. Zakaria、Mohamed A. Elmorsi、El-Zeiny M. Ebied2011-03-21ECS Transactions

Mesoporous silicate (MCM-41) and 2, 5-distyrylpyrazine photo- polymer (poly-DSP) were used as corrosion protective coatings for 304 stainless steel, copper and nickel metals. Films on metal surfaces were prepared by dip-coating and vapor deposition (CVD, PVD) methods. Poly-DSP thin films formed by vapor deposition are…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilitySilicone and Siloxane Chemistry

Carbon nanotube field-effect transistors with molecular interface

Kan-Sheng Chen、Stephen McGill、Peng Xiong2011-03-21Applied Physics Letters

We report on a study of molecular modifications of the electronic characteristics of single-walled carbon nanotube (SWNT) field-effect transistors (FETs) through insertion of different organic self-assembled monolayers (SAMs) between the SWNT and an electrode. The changes induced by the molecular interface were elucid…

Carbon Nanotubes in CompositesMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications