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Apparent thermal contraction of single-walled carbon nanotubes

Guoxin Cao、Xi Chen、Jeffrey W. Kysar2005-12-01Physical Review B

The thermomechanical behavior of single-walled carbon nanotubes (SWCNTs) is governed by the competition between quasistatic thermal expansion and dynamic thermal vibration, while the vibration effect is more prominent and induces apparent contraction in both radial and axial directions. We perform extensive molecular-…

Carbon Nanotubes in CompositesFullerene Chemistry and ApplicationsBoron and Carbon Nanomaterials Research

Characterization, structural transitions and properties of a tightly crosslinked polythiourethane network for optical applications

Boris Jaffrennou、Nicolas Droger、Françoise Méchin 等 5 位作者2005-12-01e-Polymers

Abstract A new polythiourethane thermosetting system based on a diisocyanate and a trithiol was studied. After characterization of the reactive species, two critical temperatures, namely T g∞ (maximum glass transition temperature of the thermosetting system) and gel T g ( T g of the material at the gel point), were de…

Polymer composites and self-healingSynthesis and properties of polymersPhotopolymerization techniques and applications

Preparation of Arabinoxylan and its Sorption on Bacterial Cellulose During Cultivation

Heiko Winter、Abdellatif Barakat、Bernard Cathala 等 4 位作者2005-12-01Macromolecular Symposia

Abstract The sorption of arabinoxylan (AX) on bacterial cellulose was investigated by adding AX to the culture medium of Gluconacetobacter xylinus . The starting AX material was produced by alkaline extraction of oat spelts. To investigate the impact of varying AX quality, the residual lignin was reduced by ClO 2 blea…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesPolysaccharides and Plant Cell Walls

Conventional and Efficient Crosslinking of Natural Rubber: Effect of Heterogeneities on the Physical Properties

Luis A. González、A. Rodrı́guez、J. L. Valentín 等 5 位作者2005-12-01KGK. Kautschuk, Gummi, Kunststoffe

The scope of this article is to study the sulphur vulcanisation of natural rubber in the presence as accelerator of N cyclohexyl 2 benzothiazyl sulfenamide (CBS). Two series of compounds were prepared with conventional and efficient cured systems. Experimental results indicates that abstraction of allylic hydrogen and…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersTribology and Wear Analysis

Synthesis of Multiwalled Carbon Nanotubes through a Modified Wolff−Kishner Reduction Process

Wang、Bed Poudel、Deng Wang 等 4 位作者2005-12-01Journal of the American Chemical Society

We report the synthesis of highly crystallized multiwalled carbon nanotubes through a modified Wolff-Kishner reduction process at a low temperature of 180 degrees C without adding the conventional catalysts of Fe/Co/Ni into the reaction vessel. The as-synthesized carbon nanotubes are about 10-40 nm in diameter and sev…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

X-ray structural study of charge and anion orderings of TMTTF salts

Yasuyuki Nogami、Takayoshi Ito、Kaoru Yamamoto 等 10 位作者2005-12-01Journal de Physique IV (Proceedings)

High resolution X-ray structure analyses and electronic structure calculation revealed the condition for the charge ordering(CO) observed in the (TMTTF) 2 X (Fabre) salts. The phase diagram of the electronic states including 2k F and 4k F CO has been proposed associated with magnitudes of molecular dimerization and te…

Organic Electronics and PhotovoltaicsMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

A Theoretical Study of 31P NMR Chemical Shielding Models for Concentrated Phosphoric Acid Solution

D. B. Chesnut2005-12-01The Journal of Physical Chemistry A

Calculations on the hydrates, dimer, and trimer of phosphoric acid were carried out in an effort to obtain a viable model of the phosphorus NMR chemical shielding in 85% phosphoric acid solution. The theoretical approaches used the gauge-including-atomic-orbital (GIAO) 6-311+G(nd,p) basis set at both scaled density fu…

Advanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyThermal and Kinetic Analysis

Synthesis of Diamond-Like Carbon Films by Nanopulse Plasma Chemical Vapor Deposition in Open Air

Yoshimasa Kondo、Takao Saito、Tatsuya Terazawa 等 5 位作者2005-12-01Japanese Journal of Applied Physics

The deposition of diamond-like carbon (DLC) films at atmospheric pressure is a promising technique of achieving in-process coatings regardless of work size. In this study, we aimed at the synthesis of DLC films at atmospheric pressure by nanopulse chemical vapor deposition (CVD) using a unique power source system cons…

Carbon Nanotubes in CompositesMetal and Thin Film MechanicsDiamond and Carbon-based Materials Research

Diffraction efficiency and diffraction bandwidth of thermal-gradient and composition-gradient crystals

R. K. Smither、K. Abu Saleem、Mark A. Beno 等 6 位作者2005-12-01Review of Scientific Instruments

Measurements were made at the Advanced Photon Source at Argonne National Laboratory on the diffraction efficiency and diffraction bandwidth of a thermal-gradient crystal (Si) and a composition-gradient crystal (Si-Ge) to which a thermal gradient was applied. Gradient crystals are crystals in which the spacing between…

Advanced ceramic materials synthesisHigh-pressure geophysics and materialsCrystallography and Radiation Phenomena

A study of carbon steels in basic pitting environments

Mohamed Nadir Boucherit、D. Tebib2005-12-01Anti-Corrosion Methods and Materials

Purpose Aims to study the behaviour of four polycrystalline carbon steels in basic pitting solutions. Design/methodology/approach Electrochemical investigations were carried out on four steels: Fe.06C, Fe.18C, Fe.22C and Fe.43C. The analysis was made using an X‐ray fluorescence apparatus. The performance indicator was…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Enhancing calcium carbonate precipitation by heterogeneous nucleation during chemical softening

Kenneth L. Mercer、Yi‐Pin Lin、Philip C. Singer2005-12-01American Water Works Association

Heterogeneous nucleation refers to precipitation on the surface of nucleating agents such as seed crystals, whereas homogeneous nucleation is precipitation in the absence of available nucleating surfaces. Unlike homogeneous nucleation, heterogeneous nucleation lowers the free energy of crystallization in precipitative…

Calcium Carbonate Crystallization and InhibitionMine drainage and remediation techniquesPhosphorus and nutrient management

Crystal structures and textures of hot forged Ni48Mn30Ga22alloy investigated by neutron diffraction technique

Daoyong Cong、Yandong Wang、P. Zetterström 等 7 位作者2005-12-01Materials Science and Technology

A ferromagnetic shape memory alloy of Ni48Mn30Ga22 prepared by induction melting was successfully hot forged. Strong textures and a large anisotropy of in plane plastic flow were developed during the hot forging process. The crystal structures, both in austenitic and martensitic states, were investigated by means of n…

Shape Memory Alloy TransformationsMagnetic Properties and ApplicationsTitanium Alloys Microstructure and Properties

Tensile, flexural and impact properties of jute fibre-based thermosetting composites

O.A Khondker、U. S. Ishiaku、Akihito Nakai 等 4 位作者2005-12-01Plastics Rubber and Composites Macromolecular Engineering

The present study reports static and impact mechanical properties of jute fibre-based thermosetting composites using woven and flat braided jute fabrics. Tensile, three-point flexural and low-to-medium energy drop-weight impact tests were conducted and mechanical properties were evaluated to study their dependence upo…

Natural Fiber Reinforced CompositesAdditive Manufacturing and 3D Printing TechnologiesTextile materials and evaluations

Stacking disorder: the hexagonal polymorph of tris(bicyclo[2.1.1]hexeno)benzene and related examples

Hans‐Beat Bürgi、M. Hostettler、Henrik Birkedal 等 4 位作者2005-12-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract X-ray diffractograms of tris(bicyclo[2.1.1]hexeno)benzene, crystallized at the interface between a benzene solution and a layer of acetonitrile, show hexagonal symmetry and streaks of diffuse scattering along c *. The heavily faulted layer stacking is analyzed qualitatively and quantitatively in terms of a sy…

Glass properties and applicationsCrystallography and molecular interactionsX-ray Diffraction in Crystallography

AlPO 4 Coating on Alumina/Mullite Fibers as a Weak Interface in Fiber‐Reinforced Oxide Composites ‡

Yahua Bao、Patrick S. Nicholson2005-12-01Journal of the American Ceramic Society

A sol of amorphous aluminum orthophosphate (AlPO 4 ) nano particles (30–100 nm) was synthesized by co‐precipitation of Al 3+ and HPO 4 2− with urea at 95°C. A narrow particle size distribution was achieved when [Al 3+ ]≤0.1 M . The isoelectric point of the synthesized powder is pH∼4.7. Alumina/mullite fibers (Nextel™…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

Arrays of Electroplated Multilayered Co/Cu Nanowires with Controlled Magnetic Anisotropy

Kleber R. Pirota、M. Vázquez2005-12-01Advanced Engineering Materials

The controlled production of arrays of nanowires exhibiting outstanding characteristics is recently attracting much interest owing to their applications in a number of emerging technologies related with multifunctional biosensor applications, controlled optomagnetic response, magnetic storage, magnetotransport, or cat…

Semiconductor materials and devicesAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Three-dimensional numerical study of natural convection in vertical cylinders partially heated from the side

Dongjun Ma、Daniel Henry、H. Ben Hadid2005-12-01Physics of Fluids

Three-dimensional steady and oscillatory flows are simulated in a vertical cylinder partially heated from the side. The vertical wall is heated in a zone at midheight and is insulated above and below this middle zone, while both ends of the cylinder are cooled. The cylinder aspect ratio (A=height∕radius) ranges from 2…

Solidification and crystal growth phenomenaFluid Dynamics and Vibration AnalysisFluid Dynamics and Thin Films

Narrowband, polarization-independent free-space wave notch filter

T. Clausnitzer、Alexander Tishchenko、Ernst‐Bernhard Kley 等 7 位作者2005-12-01Journal of the Optical Society of America A

A two-dimensional-corrugated-slab-waveguide add/drop filter providing 100% resonant reflection at 1.55 microm wavelength for both TE and TM polarizations with identical FWHM is designed. The fabricated device exhibits a reflectivity spectrum of more than 95% peak reflection for both polarizations at 1.537 microm. The…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Efeito da adição de ácidos graxos em filmes à base de pectina

Juliana A. Batista、Patrícia S. Tanada-Palmu、Carlos Raimundo Ferreira Grosso2005-12-01Food Science and Technology

Os objetivos deste trabalho foram desenvolver filmes à base de pectina de baixo teor de esterificação, amidada, com adição dos ácidos graxos láurico (AL), palmítico (AP) e esteárico (AE) e caracterizá-los quanto às propriedades de permeabilidade ao vapor de água (PVA) e ao oxigênio, propriedades mecânicas (tensão de r…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesPineapple and bromelain studies

Poly(ethylene oxide) (PEO) XPS Reference Core Level and Energy Loss Spectra

Pierre Louette、Frederic Bodino、Jean‐Jacques Pireaux2005-12-01Surface Science Spectra

XPS measurements of poly(ethylene oxide) recorded with a SSX-100 spectrometer in standardized experimental conditions are presented: survey scan, high resolution core level spectra as well as the energy loss regions of carbon and oxygen peaks are analyzed. This is part of a contract work aiming to record spectra in th…

Advancements in Photolithography TechniquesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques