Materials Literature
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An overview of the studies of vibronic transitions in the rare earth ions is given with special attention to the intraconfigurational transitions. First the general theory is shortly reviewed, later that of the rare-earth vibronic transitions. The vibronic spectroscopy of Gd3+ is extensively dealt with, because it is…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and UV-visible properties of soluble α-thiophene oligomers. Monomer to octamerJames M. Tour and Ruilian WuCite this: Macromolecules 1992, 25, 7, 1901–1907Publication Date (Print):March 1, 1992Publication History Published online1 May 2002Published inissue 1 March 1…
A cell suspension culture of tobacco (Nicotiana tabacum L.) was used as a model to study injury to cells during biolistic transformation. Lawns of cells were bombarded with tungsten particles that were coated with a plasmid containing the beta-glucuronidase and the neomycin phosphotransferase II genes. When a gunpowde…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSemicrystalline morphology of poly(aryl ether ether ketone)/poly(ether imide) blendsSteven D. Hudson, Don D. Davis, and Andrew J. LovingerCite this: Macromolecules 1992, 25, 6, 1759–1765Publication Date (Print):March 1, 1992Publication History Published online1 May 2002Publi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystallization of poly(butylene terephthalate) and its blends with polyarylateJ. Runt, D. M. Miley, X. Zhang, K. P. Gallagher, K. McFeaters, and J. FishburnCite this: Macromolecules 1992, 25, 7, 1929–1934Publication Date (Print):March 1, 1992Publication History Published on…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStudy of the crystal phase and crystallization rate of bacterial poly(3-hydroxybutyrate-co-3-hydroxyvalerate)Mariastella Scandola, Giuseppina Ceccorulli, Maria Pizzoli, and Massimo GazzanoCite this: Macromolecules 1992, 25, 5, 1405–1410Publication Date (Print):March 1, 1992P…
Dendrite growth velocities have been measured as a function of undercooling in droplets of dilute alloys of B in Ni undercooled by up to 306 K using an electromagnetic levitation technique. At a critical undercooling, depending strongly on the B concentration, a steep rise of the dendrite growth velocity is observed.…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMultiple ordered phases in a block copolymer meltK. Almdal, K. A. Koppi, F. S. Bates, and K. MortensenCite this: Macromolecules 1992, 25, 6, 1743–1751Publication Date (Print):March 1, 1992Publication History Published online1 May 2002Published inissue 1 March 1992https://pub…
Deuterium permeation studies for polycrystalline tungsten foil have been conducted to provide data for estimating tritium transport and trapping in tungsten-clad divertors proposed for advanced fusion-reactor concepts. Based on a detailed transmission electron microscopy (TEM) microstructural characterization of the s…
A mixed potential model (MPM) has been developed for calculating electrochemical potential (ECP) data for boiling water reactor (BWR) in-vessel components and recirculation piping using compositional data obtained from radiolysis water chemistry models. The calculated core component ECPs for the Duane-Arnold BWR are i…
The surface chemistry, oxidation, and disolution kinetics of titanium were measured to establish the mechanisms of passive dissolution in physiological environments. Titanium thin films were immersed in 8.0 mM ethylenediamine-tetraacetic acid in simulated interstitial electrolyte (EDTA/SIE) and maintained at 37 degree…
The upconversion properties of ${\mathrm{Er}}^{3+}$ ions were studied for the fluorophosphate glasses (45-x)${\mathrm{AlF}}_{3}$\ensuremath{\cdot}x${\mathrm{AlPO}}_{4}$\ensuremath{\cdot}${5\mathrm{E}\mathrm{r}\mathrm{F}}_{3}$\ensuremath{\cdot}${30\mathrm{C}\mathrm{a}\mathrm{F}}_{2}$\ensuremath{\cdot}${20\mathrm{B}\mat…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA kinetic investigation of the lanthanide DOTA chelates. Stability and rates of formation and of dissociation of a macrocyclic gadolinium(III) polyaza polycarboxylic MRI contrast agentXiangyun Wang, Tianzhu Jin, Vinciane Comblin, Antonio Lopez-Mut, Emile Merciny, and Jean F.…
Two series of site-directed mutations to the individual Ca(2+)-binding sites of Drosophila melanogaster calmodulin have been generated and studied. In each mutant, a conserved glutamic acid residue at position 12 in all of the Ca(2+)-binding loops has been mutated in one site. In one series the residue is changed to g…
Site-specific substitutions of arginine for lysine in the thermostable D-xylose isomerase (XI) from Actinoplanes missouriensis are shown to impart significant heat stability enhancement in the presence of sugar substrates most probably by interfering with nonenzymatic glycation. The same substitutions are also found t…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOligothiophene cation radical dimers. An alternative to bipolarons in oxidized polythiopheneMichael G. Hill, Kent R. Mann, Larry L. Miller, and Jean Francois PenneauCite this: J. Am. Chem. Soc. 1992, 114, 7, 2728–2730Publication Date (Print):March 1, 1992Publication History…
Light-scattering studies of the liquid-glass transition of ${\mathrm{Ca}}_{0.4}$${\mathrm{K}}_{0.6}$(${\mathrm{NO}}_{3}$${)}_{1.4}$ have been carried out from 305 to 23\ifmmode^\circ\else\textdegree\fi{}C. Composite spectra covering over four decades in frequency were obtained by combining data obtained with a Sanderc…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe role of analysis in the rate processesStuart W. ChurchillCite this: Ind. Eng. Chem. Res. 1992, 31, 3, 643–658Publication Date (Print):March 1, 1992Publication History Published online1 May 2002Published inissue 1 March 1992https://pubs.acs.org/doi/10.1021/ie00003a002http…
A cement-talc-chamotte refractory mixture was dosified by subjecting the same to thermal shock. To this end, specimens compacted to 350 Kg/cm2 through compression as well as specimens compacted manually were prepared. All the specimens were submitted to an initial working temperature of 1000ºC and then left to cool do…